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CAS Number: 42874-03-3

SMILES : CLc1cc(C(F)(F)F)ccc1Oc2cc(OCC)c(N(=O)(=O))cc2

CHEM : Oxyfluorfen

MOL FOR: C15 H11 CL1 F3 N1 O4

MOL WT : 361.71

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 5.21

Log Kow (Exper. database match) = 4.73

Exper. Ref: NANDIHALLI,UB ET AL. (1993)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 395.75 (Adapted Stein & Brown method)

Melting Pt (deg C): 156.08 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.3E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00306 (Modified Grain method)

MP (exp database): 84 deg C

BP (exp database): 358.2 deg C

VP (exp database): 2.00E-07 mm Hg (2.67E-005 Pa) at 25 deg C

Subcooled liquid VP: 7.67E-007 mm Hg (25 deg C, exp database VP )

: 0.000102 Pa (25 deg C, exp database VP )

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 0.1958

log Kow used: 4.73 (expkow database)

no-melting pt equation used

Water Sol (Exper. database match) = 0.116 mg/L (25 deg C)

Exper. Ref: TOMLIN,C (1994)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 0.010126 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.35E-007 atm-m3/mole (2.38E-002 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 8.20E-07 atm-m3/mole (8.31E-002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 5.591E-005 atm-m3/mole (5.665E+000 Pa-m3/mole)

VP: 2.3E-005 mm Hg (source: MPBPVP)

WS: 0.196 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 4.73 (exp database)

Log Kaw used: -4.475 (exp database)

Log Koa (KOAWIN v1.10 estimate): 9.205

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : -0.1687

Biowin2 (Non-Linear Model) : 0.0004

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 1.3945 (recalcitrant)

Biowin4 (Primary Survey Model) : 2.9320 (weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : -0.0036

Biowin6 (MITI Non-Linear Model): 0.0000

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.0504

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.000102 Pa (7.67E-007 mm Hg)

Log Koa (Koawin est ): 9.205

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.0293

Octanol/air (Koa) model: 0.000394

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.514

Mackay model : 0.701

Octanol/air (Koa) model: 0.0305

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 11.5297 E-12 cm3/molecule-sec

Half-Life = 0.928 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 11.132 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.608 (Junge-Pankow, Mackay avg)

0.0305 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 3.99E+004 L/kg (MCI method)

Log Koc: 4.601 (MCI method)

Koc : 7453 L/kg (Kow method)

Log Koc: 3.872 (Kow method)

Experimental Log Koc: 5 (database)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.788 (BCF = 613.6 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.8580 days (HL = 7.211 days)

Log BCF Arnot-Gobas method (upper trophic) = 3.271 (BCF = 1868)

Log BAF Arnot-Gobas method (upper trophic) = 3.320 (BAF = 2088)

log Kow used: 4.73 (expkow database)

Volatilization from Water:

Henry LC: 8.2E-007 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 1360 hours (56.66 days)

Half-Life from Model Lake : 1.499E+004 hours (624.8 days)

Removal In Wastewater Treatment:

Total removal: 67.35 percent

Total biodegradation: 0.60 percent

Total sludge adsorption: 66.73 percent

Total to Air: 0.01 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.127 22.3 1000

Water 4.31 4.32e+003 1000

Soil 75.1 8.64e+003 1000

Sediment 20.4 3.89e+004 0

Persistence Time: 5.87e+003 hr

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