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CAS Number: 101200-48-0

SMILES : COC(=O)c1ccccc1S(=O)(=O)NC(=O)N(C)c2nc(OC)nc(C)n2

CHEM : Tribenuron-methyl

MOL FOR: C15 H17 N5 O6 S1

MOL WT : 395.39

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 2.55

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 572.17 (Adapted Stein & Brown method)

Melting Pt (deg C): 246.31 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.63E-011 (Modified Grain method)

VP (Pa, 25 deg C) : 3.5E-009 (Modified Grain method)

MP (exp database): 141 deg C

VP (exp database): 3.90E-10 mm Hg (5.20E-008 Pa) at 25 deg C

Subcooled liquid VP: 5.47E-009 mm Hg (25 deg C, exp database VP )

: 7.3E-007 Pa (25 deg C, exp database VP )

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 21.72

log Kow used: 2.55 (estimated)

no-melting pt equation used

Water Sol (Exper. database match) = 50 mg/L (25 deg C)

Exper. Ref: TOMLIN,C (2003); pH 5

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 30.626 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Esters

Triazines, Aromatic

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.54E-012 atm-m3/mole (1.56E-007 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 1.02E-13 atm-m3/mole (1.03E-008 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 6.300E-013 atm-m3/mole (6.383E-008 Pa-m3/mole)

VP: 2.63E-011 mm Hg (source: MPBPVP)

WS: 21.7 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.55 (KowWin est)

Log Kaw used: -11.380 (exp database)

Log Koa (KOAWIN v1.10 estimate): 13.930

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.9296

Biowin2 (Non-Linear Model) : 0.1937

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.0868 (months )

Biowin4 (Primary Survey Model) : 3.4573 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.2672

Biowin6 (MITI Non-Linear Model): 0.0000

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.1155

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 7.29E-007 Pa (5.47E-009 mm Hg)

Log Koa (Koawin est ): 13.930

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 4.11

Octanol/air (Koa) model: 20.9

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.993

Mackay model : 0.997

Octanol/air (Koa) model: 0.999

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 2.9579 E-12 cm3/molecule-sec

Half-Life = 3.616 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 43.392 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.995 (Junge-Pankow, Mackay avg)

0.999 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 94.69 L/kg (MCI method)

Log Koc: 1.976 (MCI method)

Koc : 204.1 L/kg (Kow method)

Log Koc: 2.310 (Kow method)

Experimental Log Koc: 1.72 (database)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 3.998E-002 L/mol-sec

Kb Half-Life at pH 8: 200.670 days

Kb Half-Life at pH 7: 5.494 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.833 (BCF = 6.8 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -2.4004 days (HL = 0.003978 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.574 (BCF = 3.746)

Log BAF Arnot-Gobas method (upper trophic) = 0.574 (BAF = 3.746)

log Kow used: 2.55 (estimated)

Volatilization from Water:

Henry LC: 1.02E-013 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 1.141E+010 hours (4.756E+008 days)

Half-Life from Model Lake : 1.245E+011 hours (5.188E+009 days)

Removal In Wastewater Treatment:

Total removal: 3.25 percent

Total biodegradation: 0.10 percent

Total sludge adsorption: 3.14 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.000138 86.8 1000

Water 16.5 1.44e+003 1000

Soil 83.4 2.88e+003 1000

Sediment 0.111 1.3e+004 0

Persistence Time: 2.25e+003 hr

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