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CAS Number: 55219-65-3

SMILES : c1cc(CL)ccc1OC(n2ncnc2)C(O)C(C)(C)C

CHEM : Triadimenol

MOL FOR: C14 H18 CL1 N3 O2

MOL WT : 295.77

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 2.95

Log Kow (Exper. database match) = 2.90

Exper. Ref: BAKER,EA ET AL. (1992)

Log Kow (Exper. database match) = 3.28

Exper. Ref: TOMLIN,C (1997)

Log Kow (Exper. database match) = 3.08

Exper. Ref: TOMLIN,C (1997)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 386.72 (Adapted Stein & Brown method)

Melting Pt (deg C): 152.51 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 3.28E-008 (Modified Grain method)

VP (Pa, 25 deg C) : 4.37E-006 (Modified Grain method)

MP (exp database): 138.2 deg C

VP (exp database): 4.50E-09 mm Hg (6.00E-007 Pa) at 20 deg C

Subcooled liquid VP: 5.93E-008 mm Hg (20 deg C, exp database VP )

: 7.9E-006 Pa (20 deg C, exp database VP )

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 98.5

log Kow used: 3.08 (expkow database)

no-melting pt equation used

Water Sol (Exper. database match) = 120 mg/L (20 deg C)

Exper. Ref: MERCK INDEX (1996)

Water Sol (Exper. database match) = 33 mg/L (20 deg C)

Exper. Ref: TOMLIN,C (1997)

Water Sol (Exper. database match) = 62 mg/L (20 deg C)

Exper. Ref: TOMLIN,C (1997)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1991.2 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Triazoles (Non-Fused)

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.58E-011 atm-m3/mole (1.60E-006 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 1.28E-12 atm-m3/mole (1.30E-007 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.296E-010 atm-m3/mole (1.313E-005 Pa-m3/mole)

VP: 3.28E-008 mm Hg (source: MPBPVP)

WS: 98.5 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.08 (exp database)

Log Kaw used: -10.281 (exp database)

Log Koa (KOAWIN v1.10 estimate): 13.361

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.5310

Biowin2 (Non-Linear Model) : 0.1731

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.2287 (months )

Biowin4 (Primary Survey Model) : 3.3088 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.2116

Biowin6 (MITI Non-Linear Model): 0.0509

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.7326

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 7.91E-006 Pa (5.93E-008 mm Hg)

Log Koa (Koawin est ): 13.361

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.379

Octanol/air (Koa) model: 5.64

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.932

Mackay model : 0.968

Octanol/air (Koa) model: 0.998

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 31.8488 E-12 cm3/molecule-sec

Half-Life = 0.336 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 4.030 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.95 (Junge-Pankow, Mackay avg)

0.998 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 193.2 L/kg (MCI method)

Log Koc: 2.286 (MCI method)

Koc : 221.9 L/kg (Kow method)

Log Koc: 2.346 (Kow method)

Experimental Log Koc: 2.7 (database)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.444 (BCF = 27.77 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.4455 days (HL = 2.789 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.063 (BCF = 115.6)

Log BAF Arnot-Gobas method (upper trophic) = 2.063 (BAF = 115.7)

log Kow used: 3.08 (expkow database)

Volatilization from Water:

Henry LC: 1.28E-012 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 7.866E+008 hours (3.278E+007 days)

Half-Life from Model Lake : 8.582E+009 hours (3.576E+008 days)

Removal In Wastewater Treatment:

Total removal: 6.43 percent

Total biodegradation: 0.13 percent

Total sludge adsorption: 6.30 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 1.75e-005 8.06 1000

Water 12.9 1.44e+003 1000

Soil 87 2.88e+003 1000

Sediment 0.156 1.3e+004 0

Persistence Time: 2.5e+003 hr

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