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CAS Number: 34256-82-1

SMILES : Cc1cccc(CC)c1N(C(=O)CCL)COCC

CHEM : Acetochlor

MOL FOR: C14 H20 CL1 N1 O2

MOL WT : 269.77

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.37

Log Kow (Exper. database match) = 3.03

Exper. Ref: TOMLIN,C (1994)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 378.17 (Adapted Stein & Brown method)

Melting Pt (deg C): 128.45 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.8E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00374 (Modified Grain method)

MP (exp database): < 0 deg C

BP (exp database): 162 @ 7 mm Hg deg C

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 47.36

log Kow used: 3.03 (expkow database)

no-melting pt equation used

Water Sol (Exper. database match) = 223 mg/L (25 deg C)

Exper. Ref: SHIU,WY ET AL. (1990)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 444.62 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Haloacetamides

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.23E-008 atm-m3/mole (2.26E-003 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 2.099E-007 atm-m3/mole (2.126E-002 Pa-m3/mole)

VP: 2.8E-005 mm Hg (source: MPBPVP)

WS: 47.4 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.03 (exp database)

Log Kaw used: -6.040 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 9.070

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.4799

Biowin2 (Non-Linear Model) : 0.0946

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.2172 (months )

Biowin4 (Primary Survey Model) : 3.4165 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.1982

Biowin6 (MITI Non-Linear Model): 0.0372

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.8647

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.00373 Pa (2.8E-005 mm Hg)

Log Koa (Koawin est ): 9.070

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000804

Octanol/air (Koa) model: 0.000288

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.0282

Mackay model : 0.0604

Octanol/air (Koa) model: 0.0226

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 49.5801 E-12 cm3/molecule-sec

Half-Life = 0.216 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.589 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.0443 (Junge-Pankow, Mackay avg)

0.0226 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 298.4 L/kg (MCI method)

Log Koc: 2.475 (MCI method)

Koc : 290.6 L/kg (Kow method)

Log Koc: 2.463 (Kow method)

Experimental Log Koc: 2.32 (database)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.666 (BCF = 46.37 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.6887 days (HL = 0.2048 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.681 (BCF = 47.99)

Log BAF Arnot-Gobas method (upper trophic) = 1.681 (BAF = 47.99)

log Kow used: 3.03 (expkow database)

Volatilization from Water:

Henry LC: 2.23E-008 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 4.312E+004 hours (1797 days)

Half-Life from Model Lake : 4.706E+005 hours (1.961E+004 days)

Removal In Wastewater Treatment:

Total removal: 5.95 percent

Total biodegradation: 0.13 percent

Total sludge adsorption: 5.83 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0667 5.18 1000

Water 13.9 1.44e+003 1000

Soil 85.8 2.88e+003 1000

Sediment 0.253 1.3e+004 0

Persistence Time: 1.97e+003 hr

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