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CAS Number: 116-14-3

SMILES : FC(F)=C(F)F

CHEM : Ethene, tetrafluoro-

MOL FOR: C2 F4

MOL WT : 100.02

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.21

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): -31.60 (Adapted Stein & Brown method)

Melting Pt (deg C): -161.81 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.42E+004 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 1.9E+006 (Mean VP of Antoine & Grain methods)

MP (exp database): -142.5 deg C

BP (exp database): -75.9 deg C

VP (exp database): 2.45E+04 mm Hg (3.27E+006 Pa) at 25 deg C

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 1.074e+004

log Kow used: 1.21 (estimated)

no-melting pt equation used

Water Sol (Exper. database match) = 159 mg/L (25 deg C)

Exper. Ref: HORVATH,AL (1982)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 19790 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 8.28E-001 atm-m3/mole (8.39E+004 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 6.29E-01 atm-m3/mole (6.37E+004 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 9.313E-003 atm-m3/mole (9.436E+002 Pa-m3/mole)

VP: 1.42E+004 mm Hg (source: MPBPVP)

WS: 1.07E+004 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 1.21 (KowWin est)

Log Kaw used: 1.410 (exp database)

Log Koa (KOAWIN v1.10 estimate): -0.200

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.6999

Biowin2 (Non-Linear Model) : 0.8304

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.9781 (weeks )

Biowin4 (Primary Survey Model) : 3.7034 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.4841

Biowin6 (MITI Non-Linear Model): 0.0000

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.8361

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 3.27E+006 Pa (2.45E+004 mm Hg)

Log Koa (Koawin est ): -0.200

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 9.18E-013

Octanol/air (Koa) model: 1.55E-013

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 3.32E-011

Mackay model : 7.35E-011

Octanol/air (Koa) model: 1.24E-011

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 0.2139 E-12 cm3/molecule-sec

Half-Life = 49.998 Days (12-hr day; 1.5E6 OH/cm3)

Ozone Reaction:

OVERALL Ozone Rate Constant = 0.004480 E-17 cm3/molecule-sec

Half-Life = 255.803 Days (at 7E11 mol/cm3)

Fraction sorbed to airborne particulates (phi):

5.33E-011 (Junge-Pankow, Mackay avg)

1.24E-011 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 94.94 L/kg (MCI method)

Log Koc: 1.977 (MCI method)

Koc : 11.21 L/kg (Kow method)

Log Koc: 1.050 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.468 (BCF = 2.939 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.3169 days (HL = 0.4821 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.406 (BCF = 2.545)

Log BAF Arnot-Gobas method (upper trophic) = 0.406 (BAF = 2.545)

log Kow used: 1.21 (estimated)

Volatilization from Water:

Henry LC: 0.629 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 1.021 hours

Half-Life from Model Lake : 95 hours (3.958 days)

Removal In Wastewater Treatment (recommended maximum 95%):

Total removal: 99.59 percent

Total biodegradation: 0.02 percent

Total sludge adsorption: 0.29 percent

Total to Air: 99.28 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 54.7 856 1000

Water 44.3 360 1000

Soil 0.726 720 1000

Sediment 0.251 3.24e+003 0

Persistence Time: 139 hr

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