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CAS Number: 539-80-0

SMILES : O=C1C=CC=CC=C1

CHEM : 2,4,6-CYCLOHEPTATRIEN-1-ONE

MOL FOR: C7 H6 O1

MOL WT : 106.13

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.26

Log Kow (Exper. database match) = 0.26

Exper. Ref: BIOBYTE (1995)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 186.45 (Adapted Stein & Brown method)

Melting Pt (deg C): -15.35 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.98 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 131 (Mean VP of Antoine & Grain methods)

MP (exp database): -7 deg C

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 6.717e+004

log Kow used: 0.26 (expkow database)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1576.8 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Vinyl/Allyl Ketones

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 8.71E-006 atm-m3/mole (8.82E-001 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 2.037E-006 atm-m3/mole (2.064E-001 Pa-m3/mole)

VP: 0.98 mm Hg (source: MPBPVP)

WS: 6.72E+004 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 0.26 (exp database)

Log Kaw used: -3.448 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 3.708

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7039

Biowin2 (Non-Linear Model) : 0.7405

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.9422 (weeks )

Biowin4 (Primary Survey Model) : 3.6724 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5513

Biowin6 (MITI Non-Linear Model): 0.6146

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.0031

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 119 Pa (0.895 mm Hg)

Log Koa (Koawin est ): 3.708

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 2.51E-008

Octanol/air (Koa) model: 1.25E-009

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 9.08E-007

Mackay model : 2.01E-006

Octanol/air (Koa) model: 1E-007

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 51.8330 E-12 cm3/molecule-sec

Half-Life = 0.206 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.476 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 0.985000 E-17 cm3/molecule-sec

Half-Life = 1.163 Days (at 7E11 mol/cm3)

Half-Life = 27.923 Hrs

Fraction sorbed to airborne particulates (phi):

1.46E-006 (Junge-Pankow, Mackay avg)

1E-007 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 31.67 L/kg (MCI method)

Log Koc: 1.501 (MCI method)

Koc : 18.39 L/kg (Kow method)

Log Koc: 1.265 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -1.3163 days (HL = 0.04827 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.009 (BCF = 1.02)

Log BAF Arnot-Gobas method (upper trophic) = 0.009 (BAF = 1.02)

log Kow used: 0.26 (expkow database)

Volatilization from Water:

Henry LC: 8.71E-006 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 70.3 hours (2.929 days)

Half-Life from Model Lake : 853.3 hours (35.55 days)

Removal In Wastewater Treatment:

Total removal: 2.33 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.75 percent

Total to Air: 0.49 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.527 4.21 1000

Water 33.3 360 1000

Soil 66.1 720 1000

Sediment 0.105 3.24e+003 0

Persistence Time: 395 hr

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