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CAS Num: 000079-01-6

SMILES : C(=CCL)(CL)CL

CHEM : Ethene, trichloro-

MOL FOR: C2 H1 CL3

MOL WT : 131.39

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Water Solubility (mg/L): ------

Vapor Pressure (mm Hg) : ------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 2.47

Log Kow (Exper. database match) = 2.42

Exper. Ref: HANSCH,C ET AL. (1995)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.43):

Boiling Pt (deg C): 84.79 (Adapted Stein & Brown method)

Melting Pt (deg C): -77.15 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 72.5 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 9.66E+003 (Mean VP of Antoine & Grain methods)

MP (exp database): -84.7 deg C

BP (exp database): 87.2 deg C

VP (exp database): 6.90E+01 mm Hg (9.20E+003 Pa) at 25 deg C

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 778.7

log Kow used: 2.42 (expkow database)

no-melting pt equation used

Water Sol (Exper. database match) = 1280 mg/L (25 deg C)

Exper. Ref: HORVATH,AL ET AL. (1999)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 755.94 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Vinyl/Allyl Halides

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.30E-002 atm-m3/mole (2.33E+003 Pa-m3/mole)

Group Method: 1.86E-002 atm-m3/mole (1.88E+003 Pa-m3/mole)

Exper Database: 9.85E-03 atm-m3/mole (9.98E+002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.610E-002 atm-m3/mole (1.631E+003 Pa-m3/mole)

VP: 72.5 mm Hg (source: MPBPVP)

WS: 779 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.42 (exp database)

Log Kaw used: -0.395 (exp database)

Log Koa (KOAWIN v1.10 estimate): 2.815

Log Koa (experimental database): 2.990

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.3508

Biowin2 (Non-Linear Model) : 0.0119

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.3893 (weeks-months)

Biowin4 (Primary Survey Model) : 3.3563 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3307

Biowin6 (MITI Non-Linear Model): 0.0408

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.7186

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 9.2E+003 Pa (69 mm Hg)

Log Koa (Exp database): 2.990

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 3.26E-010

Octanol/air (Koa) model: 2.4E-010

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1.18E-008

Mackay model : 2.61E-008

Octanol/air (Koa) model: 1.92E-008

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 0.8048 E-12 cm3/molecule-sec

Half-Life = 13.291 Days (12-hr day; 1.5E6 OH/cm3)

Ozone Reaction:

OVERALL Ozone Rate Constant = 0.000512 E-17 cm3/molecule-sec

Half-Life = 2239.432 Days (at 7E11 mol/cm3)

Fraction sorbed to airborne particulates (phi):

1.89E-008 (Junge-Pankow, Mackay avg)

1.92E-008 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 60.7 L/kg (MCI method)

Log Koc: 1.783 (MCI method)

Koc : 125.9 L/kg (Kow method)

Log Koc: 2.100 (Kow method)

Experimental Log Koc: 2 (database)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 1.264 (BCF = 18.35 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.0509 days (HL = 1.124 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.375 (BCF = 23.7)

Log BAF Arnot-Gobas method (upper trophic) = 1.375 (BAF = 23.7)

log Kow used: 2.42 (expkow database)

Volatilization from Water:

Henry LC: 0.00985 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 1.238 hours

Half-Life from Model Lake : 109.6 hours (4.567 days)

Removal In Wastewater Treatment:

Total removal: 79.58 percent

Total biodegradation: 0.04 percent

Total sludge adsorption: 1.26 percent

Total to Air: 78.28 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 35.4 109 1000

Water 54.2 900 1000

Soil 10.1 1.8e+003 1000

Sediment 0.261 8.1e+003 0

Persistence Time: 147 hr

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