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CAS Number: 56-36-0

SMILES : CCCC[Sn](CCCC)(CCCC)OC(=O)(C)

CHEM : Tributyl tin acetate

MOL FOR: C14 H30 O2 Sn1

MOL WT : 349.10

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.24

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 315.00 (Adapted Stein & Brown method)

Melting Pt (deg C): 72.12 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.000235 (Modified Grain method)

VP (Pa, 25 deg C) : 0.0313 (Modified Grain method)

MP (exp database): 84.7 deg C

VP (exp database): 2.70E-03 mm Hg (3.60E-001 Pa) at 20 deg C

Subcooled liquid VP: 0.0105 mm Hg (20 deg C, exp database VP )

: 1.4 Pa (20 deg C, exp database VP )

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 10.78

log Kow used: 3.24 (estimated)

no-melting pt equation used

Water Sol (Exper. database match) = 65 mg/L ( deg C)

Exper. Ref: BLUNDEN,SJ ET AL. (1984)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1.7769 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

SHOULD NOT BE PROFILED

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 5.81E-002 atm-m3/mole (5.88E+003 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 1.91E-05 atm-m3/mole (1.94E+000 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.001E-005 atm-m3/mole (1.015E+000 Pa-m3/mole)

VP: 0.000235 mm Hg (source: MPBPVP)

WS: 10.8 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.24 (KowWin est)

Log Kaw used: -3.107 (exp database)

Log Koa (KOAWIN v1.10 estimate): 6.347

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.9066

Biowin2 (Non-Linear Model) : 0.9729

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.3227 (days-weeks )

Biowin4 (Primary Survey Model) : 4.1513 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.2523

Biowin6 (MITI Non-Linear Model): 0.0000

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.2015

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 1.4 Pa (0.0105 mm Hg)

Log Koa (Koawin est ): 6.347

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 2.14E-006

Octanol/air (Koa) model: 5.46E-007

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 7.74E-005

Mackay model : 0.000171

Octanol/air (Koa) model: 4.37E-005

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 42.6942 E-12 cm3/molecule-sec

Half-Life = 0.251 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 3.006 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.000124 (Junge-Pankow, Mackay avg)

4.37E-005 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1648 L/kg (MCI method)

Log Koc: 3.217 (MCI method)

Koc : 307.6 L/kg (Kow method)

Log Koc: 2.488 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 3.203 (BCF = 1596 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.1368 days (HL = 0.7299 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.057 (BCF = 114.1)

Log BAF Arnot-Gobas method (upper trophic) = 2.057 (BAF = 114.2)

log Kow used: 3.24 (estimated)

Volatilization from Water:

Henry LC: 1.91E-005 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 59.18 hours (2.466 days)

Half-Life from Model Lake : 802.3 hours (33.43 days)

Removal In Wastewater Treatment:

Total removal: 9.26 percent

Total biodegradation: 0.14 percent

Total sludge adsorption: 8.14 percent

Total to Air: 0.98 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.989 6.01 1000

Water 26.6 208 1000

Soil 71.4 416 1000

Sediment 0.978 1.87e+003 0

Persistence Time: 279 hr

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