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CAS Num: 024634-61-5

SMILES : KOC(=O)C=CC=CC

CHEM : 2,4-Hexadienoic acid, potassium salt, (E,E)-

MOL FOR: C6 H7 O2 K1

MOL WT : 150.22

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Water Solubility (mg/L): ------

Vapor Pressure (mm Hg) : ------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = -2.19

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.43):

Boiling Pt (deg C): 445.91 (Adapted Stein & Brown method)

Melting Pt (deg C): 173.92 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.78E-008 (Modified Grain method)

VP (Pa, 25 deg C) : 2.37E-006 (Modified Grain method)

MP (exp database): >270 dec deg C

Subcooled liquid VP: 6.21E-007 mm Hg (25 deg C, Mod-Grain method)

: 8.28E-005 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 1e+006

log Kow used: -2.19 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 16673 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : Incomplete

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 3.518E-015 atm-m3/mole (3.565E-010 Pa-m3/mole)

VP: 1.78E-008 mm Hg (source: MPBPVP)

WS: 1E+006 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Can Not Estimate (can not calculate HenryLC)

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8753

Biowin2 (Non-Linear Model) : 0.9802

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.6143 (days-weeks )

Biowin4 (Primary Survey Model) : 4.3406 (hours-days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5849

Biowin6 (MITI Non-Linear Model): 0.6357

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.3315

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 8.28E-005 Pa (6.21E-007 mm Hg)

Log Koa (): not available

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.0362

Octanol/air (Koa) model: not available

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.567

Mackay model : 0.743

Octanol/air (Koa) model: not available

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 49.8360 E-12 cm3/molecule-sec

Half-Life = 0.215 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.575 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 5.265000 E-17 cm3/molecule-sec

Half-Life = 0.218 Days (at 7E11 mol/cm3)

Half-Life = 5.224 Hrs

Fraction sorbed to airborne particulates (phi):

0.655 (Junge-Pankow, Mackay avg)

not available (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 8.715 L/kg (MCI method)

Log Koc: 0.940 (MCI method)

Koc : 0.08798 L/kg (Kow method)

Log Koc: -1.056 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.8389 days (HL = 0.1449 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.445 (BCF = 2.784)

Log BAF Arnot-Gobas method (upper trophic) = 0.445 (BAF = 2.784)

log Kow used: 1.33 (expkow database)

Volatilization from Water:

Henry LC: 3.52E-015 atm-m3/mole (calculated from VP/WS)

Half-Life from Model River: 2.04E+011 hours (8.498E+009 days)

Half-Life from Model Lake : 2.225E+012 hours (9.271E+010 days)

Removal In Wastewater Treatment:

Total removal: 1.85 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.75 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 3.15e-007 2.59 1000

Water 28.6 208 1000

Soil 71.3 416 1000

Sediment 0.0589 1.87e+003 0

Persistence Time: 412 hr

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