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CAS Number: 925-16-6

SMILES : O=C(OCC=C)CCC(=O)OCC=C

CHEM : Butanedioic acid, di-2-propenyl ester

MOL FOR: C10 H14 O4

MOL WT : 198.22

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 2.10

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 223.34 (Adapted Stein & Brown method)

Melting Pt (deg C): -51.41 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.11 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 14.7 (Mean VP of Antoine & Grain methods)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 724.1

log Kow used: 2.10 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 729.16 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Esters

Vinyl/Allyl Esters

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 9.56E-007 atm-m3/mole (9.68E-002 Pa-m3/mole)

Group Method: 1.23E-007 atm-m3/mole (1.24E-002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 3.962E-005 atm-m3/mole (4.015E+000 Pa-m3/mole)

VP: 0.11 mm Hg (source: MPBPVP)

WS: 724 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.10 (KowWin est)

Log Kaw used: -4.408 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 6.508

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.0015

Biowin2 (Non-Linear Model) : 0.9998

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.0415 (weeks )

Biowin4 (Primary Survey Model) : 4.0197 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 1.0447

Biowin6 (MITI Non-Linear Model): 0.9730

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.8426

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 13.7 Pa (0.103 mm Hg)

Log Koa (Koawin est ): 6.508

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 2.18E-007

Octanol/air (Koa) model: 7.91E-007

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 7.89E-006

Mackay model : 1.75E-005

Octanol/air (Koa) model: 6.33E-005

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 56.3011 E-12 cm3/molecule-sec

Half-Life = 0.190 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.280 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 2.400000 E-17 cm3/molecule-sec

Half-Life = 0.477 Days (at 7E11 mol/cm3)

Half-Life = 11.460 Hrs

Fraction sorbed to airborne particulates (phi):

1.27E-005 (Junge-Pankow, Mackay avg)

6.33E-005 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 31.59 L/kg (MCI method)

Log Koc: 1.500 (MCI method)

Koc : 90.26 L/kg (Kow method)

Log Koc: 1.955 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 2.562E-001 L/mol-sec

Kb Half-Life at pH 8: 31.315 days

Kb Half-Life at pH 7: 313.150 days

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.050 (BCF = 11.23 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -2.2323 days (HL = 0.005858 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.444 (BCF = 2.779)

Log BAF Arnot-Gobas method (upper trophic) = 0.444 (BAF = 2.779)

log Kow used: 2.10 (estimated)

Volatilization from Water:

Henry LC: 1.23E-007 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 6703 hours (279.3 days)

Half-Life from Model Lake : 7.324E+004 hours (3052 days)

Removal In Wastewater Treatment:

Total removal: 2.35 percent

Total biodegradation: 0.10 percent

Total sludge adsorption: 2.25 percent

Total to Air: 0.01 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.325 3.26 1000

Water 32 360 1000

Soil 67.5 720 1000

Sediment 0.101 3.24e+003 0

Persistence Time: 433 hr

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