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CAS Number: 477-30-5

SMILES : C1Cc2cc(OC)c(OC)c(OC)c2C3=CC=C(OC)C(=O)C=C3C1NC

CHEM : Demecolcine

MOL FOR: C21 H25 N1 O5

MOL WT : 371.44

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 2.38

Log Kow (Exper. database match) = 1.37

Exper. Ref: HANSCH,C ET AL. (1995)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 476.32 (Adapted Stein & Brown method)

Melting Pt (deg C): 201.54 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.48E-009 (Modified Grain method)

VP (Pa, 25 deg C) : 1.98E-007 (Modified Grain method)

Subcooled liquid VP: 1.08E-007 mm Hg (25 deg C, Mod-Grain method)

: 1.44E-005 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 3161

log Kow used: 1.37 (expkow database)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 82.01 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Aliphatic Amines

Vinyl/Allyl Ketones

Vinyl/Allyl Ethers

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.21E-014 atm-m3/mole (1.23E-009 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 2.288E-013 atm-m3/mole (2.319E-008 Pa-m3/mole)

VP: 1.48E-009 mm Hg (source: MPBPVP)

WS: 3.16E+003 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 1.37 (exp database)

Log Kaw used: -12.306 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 13.676

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8344

Biowin2 (Non-Linear Model) : 0.9075

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.1224 (months )

Biowin4 (Primary Survey Model) : 3.4860 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3506

Biowin6 (MITI Non-Linear Model): 0.0293

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.0179

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 1.44E-005 Pa (1.08E-007 mm Hg)

Log Koa (Koawin est ): 13.676

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.208

Octanol/air (Koa) model: 11.6

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.883

Mackay model : 0.943

Octanol/air (Koa) model: 0.999

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 403.2953 E-12 cm3/molecule-sec

Half-Life = 0.027 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 19.095 Min

Ozone Reaction:

OVERALL Ozone Rate Constant = 64.055000 E-17 cm3/molecule-sec

Half-Life = 0.018 Days (at 7E11 mol/cm3)

Half-Life = 25.763 Min

Fraction sorbed to airborne particulates (phi):

0.913 (Junge-Pankow, Mackay avg)

0.999 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 4342 L/kg (MCI method)

Log Koc: 3.638 (MCI method)

Koc : 71.8 L/kg (Kow method)

Log Koc: 1.856 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.571 (BCF = 3.723 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.2646 days (HL = 0.5438 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.514 (BCF = 3.266)

Log BAF Arnot-Gobas method (upper trophic) = 0.514 (BAF = 3.266)

log Kow used: 1.37 (expkow database)

Volatilization from Water:

Henry LC: 1.21E-014 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 9.326E+010 hours (3.886E+009 days)

Half-Life from Model Lake : 1.017E+012 hours (4.239E+010 days)

Removal In Wastewater Treatment:

Total removal: 1.94 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.85 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 6.71e-007 0.256 1000

Water 8.46 1.44e+003 1000

Soil 88.8 2.88e+003 1000

Sediment 2.7 1.3e+004 0

Persistence Time: 2.93e+003 hr

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