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CAS Number: 3949-36-8

SMILES : O=C1C(=Cc2c(cccc2)O1)C(=O)C

CHEM : 2H-1-Benzopyran-2-one, 3-acetyl-

MOL FOR: C11 H8 O3

MOL WT : 188.18

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 0.79

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 342.94 (Adapted Stein & Brown method)

Melting Pt (deg C): 98.66 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 3.73E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00497 (Modified Grain method)

Subcooled liquid VP: 0.000194 mm Hg (25 deg C, Mod-Grain method)

: 0.0259 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 1.061e+004

log Kow used: 0.79 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 544.57 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Acrylates

Vinyl/Allyl Ketones

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.94E-009 atm-m3/mole (2.98E-004 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 8.705E-010 atm-m3/mole (8.820E-005 Pa-m3/mole)

VP: 3.73E-005 mm Hg (source: MPBPVP)

WS: 1.06E+004 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 0.79 (KowWin est)

Log Kaw used: -6.920 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 7.710

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8390

Biowin2 (Non-Linear Model) : 0.9813

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.9010 (weeks )

Biowin4 (Primary Survey Model) : 3.7830 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.6532

Biowin6 (MITI Non-Linear Model): 0.7112

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.0812

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.0259 Pa (0.000194 mm Hg)

Log Koa (Koawin est ): 7.710

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000116

Octanol/air (Koa) model: 1.26E-005

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.00417

Mackay model : 0.00919

Octanol/air (Koa) model: 0.00101

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 29.3661 E-12 cm3/molecule-sec

Half-Life = 0.364 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 4.371 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 5.670000 E-17 cm3/molecule-sec

Half-Life = 0.202 Days (at 7E11 mol/cm3)

Half-Life = 4.851 Hrs

Fraction sorbed to airborne particulates (phi):

0.00668 (Junge-Pankow, Mackay avg)

0.00101 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 45.38 L/kg (MCI method)

Log Koc: 1.657 (MCI method)

Koc : 31.05 L/kg (Kow method)

Log Koc: 1.492 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -1.2381 days (HL = 0.05779 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.129 (BCF = 1.345)

Log BAF Arnot-Gobas method (upper trophic) = 0.129 (BAF = 1.345)

log Kow used: 0.79 (estimated)

Volatilization from Water:

Henry LC: 2.94E-009 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 2.732E+005 hours (1.138E+004 days)

Half-Life from Model Lake : 2.98E+006 hours (1.242E+005 days)

Removal In Wastewater Treatment:

Total removal: 1.87 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.78 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0483 3.12 1000

Water 23.6 360 1000

Soil 76.3 720 1000

Sediment 0.0873 3.24e+003 0

Persistence Time: 651 hr

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