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CAS Number: 1689-84-5

SMILES : Oc1c(Br)cc(C(#N))cc1Br

CHEM : Bromoxynil

MOL FOR: C7 H3 Br2 N1 O1

MOL WT : 276.92

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.39

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 328.67 (Adapted Stein & Brown method)

Melting Pt (deg C): 119.50 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.31E-006 (Modified Grain method)

VP (Pa, 25 deg C) : 0.000308 (Modified Grain method)

MP (exp database): 190 deg C

VP (exp database): 4.72E-08 mm Hg (6.29E-006 Pa) at 20 deg C

Subcooled liquid VP: 2.02E-006 mm Hg (20 deg C, exp database VP )

: 0.00027 Pa (20 deg C, exp database VP )

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 43.87

log Kow used: 3.39 (estimated)

no-melting pt equation used

Water Sol (Exper. database match) = 130 mg/L (25 deg C)

Exper. Ref: WORTHING,CR & WALKER,SB (1987)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1148.4 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Phenols

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 8.60E-010 atm-m3/mole (8.71E-005 Pa-m3/mole)

Group Method: 9.52E-010 atm-m3/mole (9.64E-005 Pa-m3/mole)

Exper Database: 1.32E-10 atm-m3/mole (1.34E-005 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.919E-008 atm-m3/mole (1.944E-003 Pa-m3/mole)

VP: 2.31E-006 mm Hg (source: MPBPVP)

WS: 43.9 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.39 (KowWin est)

Log Kaw used: -8.268 (exp database)

Log Koa (KOAWIN v1.10 estimate): 11.658

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8178

Biowin2 (Non-Linear Model) : 0.7813

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.2892 (weeks-months)

Biowin4 (Primary Survey Model) : 3.1157 (weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3742

Biowin6 (MITI Non-Linear Model): 0.1822

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.7259

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.000269 Pa (2.02E-006 mm Hg)

Log Koa (Koawin est ): 11.658

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.0111

Octanol/air (Koa) model: 0.112

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.287

Mackay model : 0.471

Octanol/air (Koa) model: 0.899

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 0.2096 E-12 cm3/molecule-sec

Half-Life = 51.023 Days (12-hr day; 1.5E6 OH/cm3)

Ozone Reaction:

No Ozone Reaction Estimation

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.379 (Junge-Pankow, Mackay avg)

0.899 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 330.1 L/kg (MCI method)

Log Koc: 2.519 (MCI method)

Koc : 2287 L/kg (Kow method)

Log Koc: 3.359 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.904 (BCF = 80.14 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.6260 days (HL = 0.2366 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.856 (BCF = 71.7)

Log BAF Arnot-Gobas method (upper trophic) = 1.856 (BAF = 71.7)

log Kow used: 3.39 (estimated)

Volatilization from Water:

Henry LC: 1.32E-010 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 7.381E+006 hours (3.075E+005 days)

Half-Life from Model Lake : 8.052E+007 hours (3.355E+006 days)

Removal In Wastewater Treatment:

Total removal: 10.76 percent

Total biodegradation: 0.17 percent

Total sludge adsorption: 10.60 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.00107 1.22e+003 1000

Water 13.2 900 1000

Soil 86.5 1.8e+003 1000

Sediment 0.245 8.1e+003 0

Persistence Time: 1.76e+003 hr

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