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CAS Number: 95-56-7

SMILES : Oc(c(ccc1)Br)c1

CHEM : Phenol, 2-bromo-

MOL FOR: C6 H5 Br1 O1

MOL WT : 173.01

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 2.40

Log Kow (Exper. database match) = 2.35

Exper. Ref: HANSCH,C ET AL. (1995)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 223.04 (Adapted Stein & Brown method)

Melting Pt (deg C): 38.43 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.254 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 33.8 (Mean VP of Antoine & Grain methods)

MP (exp database): 5.6 deg C

BP (exp database): 194.5 deg C

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 2227

log Kow used: 2.35 (expkow database)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 14308 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Phenols

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.23E-007 atm-m3/mole (2.26E-002 Pa-m3/mole)

Group Method: 2.74E-007 atm-m3/mole (2.78E-002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 2.596E-005 atm-m3/mole (2.631E+000 Pa-m3/mole)

VP: 0.254 mm Hg (source: MPBPVP)

WS: 2.23E+003 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.35 (exp database)

Log Kaw used: -5.040 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 7.390

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.6707

Biowin2 (Non-Linear Model) : 0.4459

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.7372 (weeks-months)

Biowin4 (Primary Survey Model) : 3.4843 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.4613

Biowin6 (MITI Non-Linear Model): 0.5005

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.5351

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 30.5 Pa (0.229 mm Hg)

Log Koa (Koawin est ): 7.390

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 9.83E-008

Octanol/air (Koa) model: 6.03E-006

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 3.55E-006

Mackay model : 7.86E-006

Octanol/air (Koa) model: 0.000482

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 9.6921 E-12 cm3/molecule-sec

Half-Life = 1.104 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 13.243 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

5.7E-006 (Junge-Pankow, Mackay avg)

0.000482 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 306.5 L/kg (MCI method)

Log Koc: 2.486 (MCI method)

Koc : 246.5 L/kg (Kow method)

Log Koc: 2.392 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.218 (BCF = 16.5 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.6971 days (HL = 0.2009 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.339 (BCF = 21.85)

Log BAF Arnot-Gobas method (upper trophic) = 1.339 (BAF = 21.85)

log Kow used: 2.35 (expkow database)

Volatilization from Water:

Henry LC: 2.74E-007 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 2812 hours (117.2 days)

Half-Life from Model Lake : 3.079E+004 hours (1283 days)

Removal In Wastewater Treatment:

Total removal: 2.75 percent

Total biodegradation: 0.10 percent

Total sludge adsorption: 2.63 percent

Total to Air: 0.02 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.632 26.5 1000

Water 18.2 900 1000

Soil 80.9 1.8e+003 1000

Sediment 0.314 8.1e+003 0

Persistence Time: 1.16e+003 hr

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