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CAS Number: 32064-70-3

SMILES : O=C(C)C(=CCC)CCCC

CHEM : 2-HEPTANONE, 3-PROPYLIDENE-

MOL FOR: C10 H18 O1

MOL WT : 154.25

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.33

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 205.48 (Adapted Stein & Brown method)

Melting Pt (deg C): -16.75 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.398 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 53.1 (Mean VP of Antoine & Grain methods)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 103.6

log Kow used: 3.33 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 50.899 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Vinyl/Allyl Ketones

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.99E-004 atm-m3/mole (2.02E+001 Pa-m3/mole)

Group Method: 4.88E-004 atm-m3/mole (4.95E+001 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 7.797E-004 atm-m3/mole (7.900E+001 Pa-m3/mole)

VP: 0.398 mm Hg (source: MPBPVP)

WS: 104 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.33 (KowWin est)

Log Kaw used: -2.090 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 5.420

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7894

Biowin2 (Non-Linear Model) : 0.9011

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.1341 (weeks )

Biowin4 (Primary Survey Model) : 3.8720 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5761

Biowin6 (MITI Non-Linear Model): 0.6706

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.0818

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 48.9 Pa (0.367 mm Hg)

Log Koa (Koawin est ): 5.420

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 6.13E-008

Octanol/air (Koa) model: 6.46E-008

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 2.21E-006

Mackay model : 4.9E-006

Octanol/air (Koa) model: 5.17E-006

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 83.2912 E-12 cm3/molecule-sec

Half-Life = 0.128 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 1.541 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 19.963125 E-17 cm3/molecule-sec

Half-Life = 0.057 Days (at 7E11 mol/cm3)

Half-Life = 1.378 Hrs

Fraction sorbed to airborne particulates (phi):

3.56E-006 (Junge-Pankow, Mackay avg)

5.17E-006 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 155.3 L/kg (MCI method)

Log Koc: 2.191 (MCI method)

Koc : 917.5 L/kg (Kow method)

Log Koc: 2.963 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.866 (BCF = 73.41 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.1234 days (HL = 0.7526 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.120 (BCF = 131.9)

Log BAF Arnot-Gobas method (upper trophic) = 2.120 (BAF = 132)

log Kow used: 3.33 (estimated)

Volatilization from Water:

Henry LC: 0.000488 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 2.757 hours

Half-Life from Model Lake : 134.2 hours (5.593 days)

Removal In Wastewater Treatment:

Total removal: 25.13 percent

Total biodegradation: 0.14 percent

Total sludge adsorption: 8.72 percent

Total to Air: 16.27 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.262 0.952 1000

Water 25.6 360 1000

Soil 73.9 720 1000

Sediment 0.203 3.24e+003 0

Persistence Time: 295 hr

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