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CAS Number: 2384-86-3

SMILES : C(#CCCCCC)CCC

CHEM : 4-DECYNE

MOL FOR: C10 H18

MOL WT : 138.26

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 4.54

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 179.90 (Adapted Stein & Brown method)

Melting Pt (deg C): 13.39 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.52 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 202 (Mean VP of Antoine & Grain methods)

MP (exp database): -73 deg C

BP (exp database): 177 deg C

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 3.301

log Kow used: 4.54 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 9.1072 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 5.89E-002 atm-m3/mole (5.96E+003 Pa-m3/mole)

Group Method: 7.73E-002 atm-m3/mole (7.84E+003 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 8.377E-002 atm-m3/mole (8.488E+003 Pa-m3/mole)

VP: 1.52 mm Hg (source: MPBPVP)

WS: 3.3 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 4.54 (KowWin est)

Log Kaw used: 0.382 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 4.158

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7902

Biowin2 (Non-Linear Model) : 0.9473

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.1920 (weeks )

Biowin4 (Primary Survey Model) : 3.9173 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5982

Biowin6 (MITI Non-Linear Model): 0.7596

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.5152

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

LOG BioHC Half-Life (days) : 0.6944

BioHC Half-Life (days) : 4.9477

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 185 Pa (1.39 mm Hg)

Log Koa (Koawin est ): 4.158

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 1.62E-008

Octanol/air (Koa) model: 3.53E-009

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 5.85E-007

Mackay model : 1.29E-006

Octanol/air (Koa) model: 2.83E-007

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 34.7559 E-12 cm3/molecule-sec

Half-Life = 0.308 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 3.693 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 0.003000 E-17 cm3/molecule-sec

Half-Life = 382.000 Days (at 7E11 mol/cm3)

Fraction sorbed to airborne particulates (phi):

9.4E-007 (Junge-Pankow, Mackay avg)

2.83E-007 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1451 L/kg (MCI method)

Log Koc: 3.162 (MCI method)

Koc : 8707 L/kg (Kow method)

Log Koc: 3.940 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.661 (BCF = 457.6 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.1723 days (HL = 1.487 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.724 (BCF = 529.4)

Log BAF Arnot-Gobas method (upper trophic) = 2.726 (BAF = 531.5)

log Kow used: 4.54 (estimated)

Volatilization from Water:

Henry LC: 0.0773 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 1.209 hours

Half-Life from Model Lake : 111.8 hours (4.658 days)

Removal In Wastewater Treatment (recommended maximum 95%):

Total removal: 97.67 percent

Total biodegradation: 0.13 percent

Total sludge adsorption: 35.99 percent

Total to Air: 61.54 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 7.12 7.38 1000

Water 58 360 1000

Soil 32.1 720 1000

Sediment 2.84 3.24e+003 0

Persistence Time: 106 hr

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