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CAS Number: 250-84-0

SMILES : c1csc2c1ccs2

CHEM : thieno[2,3-b]thiophene

MOL FOR: C6 H4 S2

MOL WT : 140.22

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 2.81

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 249.36 (Adapted Stein & Brown method)

Melting Pt (deg C): 55.88 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.0142 (Modified Grain method)

VP (Pa, 25 deg C) : 1.9 (Modified Grain method)

Subcooled liquid VP: 0.0275 mm Hg (25 deg C, Mod-Grain method)

: 3.66 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 333.3

log Kow used: 2.81 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 265.51 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.55E-004 atm-m3/mole (1.57E+001 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 7.860E-006 atm-m3/mole (7.965E-001 Pa-m3/mole)

VP: 0.0142 mm Hg (source: MPBPVP)

WS: 333 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.81 (KowWin est)

Log Kaw used: -2.198 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 5.008

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.6808

Biowin2 (Non-Linear Model) : 0.7345

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.8893 (weeks )

Biowin4 (Primary Survey Model) : 3.6454 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3279

Biowin6 (MITI Non-Linear Model): 0.2608

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.4544

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

LOG BioHC Half-Life (days) : 1.0149

BioHC Half-Life (days) : 10.3483

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 3.67 Pa (0.0275 mm Hg)

Log Koa (Koawin est ): 5.008

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 8.18E-007

Octanol/air (Koa) model: 2.5E-008

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 2.96E-005

Mackay model : 6.55E-005

Octanol/air (Koa) model: 2E-006

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 21.6000 E-12 cm3/molecule-sec

Half-Life = 0.495 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 5.942 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

4.75E-005 (Junge-Pankow, Mackay avg)

2E-006 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 465 L/kg (MCI method)

Log Koc: 2.667 (MCI method)

Koc : 274.4 L/kg (Kow method)

Log Koc: 2.438 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 1.521 (BCF = 33.16 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.6818 days (HL = 0.208 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.571 (BCF = 37.25)

Log BAF Arnot-Gobas method (upper trophic) = 1.571 (BAF = 37.25)

log Kow used: 2.81 (estimated)

Volatilization from Water:

Henry LC: 0.000155 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 5.681 hours

Half-Life from Model Lake : 161.3 hours (6.719 days)

Removal In Wastewater Treatment:

Total removal: 11.11 percent

Total biodegradation: 0.11 percent

Total sludge adsorption: 4.07 percent

Total to Air: 6.93 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 1.53 11.9 1000

Water 21.1 360 1000

Soil 76.9 720 1000

Sediment 0.392 3.24e+003 0

Persistence Time: 415 hr

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