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CAS Number: 13422-51-0

SMILES : N4=C5C(=C6N=C(C(C6(CC(=O)N)C)CCC(=O)N)C=C7N=C(C(C7(CCC(=O)N)C)C)C(=C8

NC(C4(C(C5CCC(=O)N)(CC(=O)N)C)C)C(C8CCC(=O)NCC(OP(=O)(OC1C(C(n2c3c(cc

(c(c3)C)C)nc2)OC1CO)O)O)C)(CC(=O)N)C)C)C

CHEM : HYDROXOCOBALAMIN

MOL FOR: C62 H90 N13 O14 P1

MOL WT : 1272.46

Vapor Pressure (mm Hg) : ------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Physical Property Inputs:

------------------------------ EPI SUMMARY (v3.20) --------------------------

Water Solubility (mg/L): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 5.28

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 480.00 (Adapted Stein & Brown method)

Melting Pt (deg C): 90.27 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.06E-011 (Modified Grain method)

VP (Pa, 25 deg C) : 2.74E-009 (Modified Grain method)

Subcooled liquid VP: 8.76E-011 mm Hg (25 deg C, Mod-Grain method)

: 1.17E-008 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 1.336e-007

log Kow used: 5.28 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 8.5016 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Aliphatic Amines

Imidazoles

Amides

Vinyl/Allyl Amines

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : Incomplete

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 2.582E-004 atm-m3/mole (2.616E+001 Pa-m3/mole)

VP: 2.06E-011 mm Hg (source: MPBPVP)

WS: 1.34E-007 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Can Not Estimate (can not calculate HenryLC)

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.9264

Biowin2 (Non-Linear Model) : 0.0226

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): -0.8669 (recalcitrant)

Biowin4 (Primary Survey Model) : 2.8381 (weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : -0.6707

Biowin6 (MITI Non-Linear Model): 0.0000

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -5.9171

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 1.17E-008 Pa (8.76E-011 mm Hg)

Log Koa (): not available

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 257

Octanol/air (Koa) model: not available

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1

Mackay model : 1

Octanol/air (Koa) model: not available

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 346.4150 E-12 cm3/molecule-sec

Half-Life = 0.031 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 22.231 Min

Ozone Reaction:

OVERALL Ozone Rate Constant = 8.706249 E-17 cm3/molecule-sec

Half-Life = 0.132 Days (at 7E11 mol/cm3)

Half-Life = 3.159 Hrs

Fraction sorbed to airborne particulates (phi):

1 (Junge-Pankow, Mackay avg)

not available (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1E+010 L/kg (MCI method)

Log Koc: 13.194 (MCI method)

Koc : 1075 L/kg (Kow method)

Log Koc: 3.031 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 0.698 (BCF = 4.984 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -4.1198 days (HL = 7.589e-005 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.089 (BCF = 12.27)

Log BAF Arnot-Gobas method (upper trophic) = 1.089 (BAF = 12.27)

log Kow used: 5.28 (estimated)

Volatilization from Water:

Henry LC: 0.000258 atm-m3/mole (calculated from VP/WS)

Half-Life from Model River: 11.73 hours

Half-Life from Model Lake : 427.1 hours (17.79 days)

Removal In Wastewater Treatment:

Total removal: 85.16 percent

Total biodegradation: 0.71 percent

Total sludge adsorption: 83.28 percent

Total to Air: 1.17 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.00257 0.6 1000

Water 0.696 4.32e+003 1000

Soil 39.1 8.64e+003 1000

Sediment 60.2 3.89e+004 0

Persistence Time: 1.08e+004 hr

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