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CAS Number:

SMILES : CC=C=C(C)C(=O)(O)

CHEM :

MOL FOR: C6 H8 O2

MOL WT : 112.13

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.78

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 209.99 (Adapted Stein & Brown method)

Melting Pt (deg C): 20.62 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.218 (Mean VP of Antoine & Grain methods)

VP (Pa, 25 deg C) : 29.1 (Mean VP of Antoine & Grain methods)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 7945

log Kow used: 1.78 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 10647 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Neutral Organics-acid

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 7.09E-007 atm-m3/mole (7.19E-002 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 4.048E-006 atm-m3/mole (4.102E-001 Pa-m3/mole)

VP: 0.218 mm Hg (source: MPBPVP)

WS: 7.95E+003 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 1.78 (KowWin est)

Log Kaw used: -4.538 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 6.318

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7669

Biowin2 (Non-Linear Model) : 0.8869

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.3160 (days-weeks )

Biowin4 (Primary Survey Model) : 4.0715 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5667

Biowin6 (MITI Non-Linear Model): 0.6202

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.7902

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 26.8 Pa (0.201 mm Hg)

Log Koa (Koawin est ): 6.318

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 1.12E-007

Octanol/air (Koa) model: 5.11E-007

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 4.04E-006

Mackay model : 8.96E-006

Octanol/air (Koa) model: 4.08E-005

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 30.5420 E-12 cm3/molecule-sec

Half-Life = 0.350 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 4.202 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 0.633750 E-17 cm3/molecule-sec

Half-Life = 1.808 Days (at 7E11 mol/cm3)

Half-Life = 43.399 Hrs

Fraction sorbed to airborne particulates (phi):

6.5E-006 (Junge-Pankow, Mackay avg)

4.08E-005 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 4.796 L/kg (MCI method)

Log Koc: 0.681 (MCI method)

Koc : 13.81 L/kg (Kow method)

Log Koc: 1.140 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.3067 days (HL = 0.4935 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.840 (BCF = 6.919)

Log BAF Arnot-Gobas method (upper trophic) = 0.840 (BAF = 6.919)

log Kow used: 1.78 (estimated)

Volatilization from Water:

Henry LC: 7.09E-007 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 875.5 hours (36.48 days)

Half-Life from Model Lake : 9640 hours (401.7 days)

Removal In Wastewater Treatment:

Total removal: 2.13 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.99 percent

Total to Air: 0.04 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 1.27 7.04 1000

Water 39.8 208 1000

Soil 58.9 416 1000

Sediment 0.0761 1.87e+003 0

Persistence Time: 245 hr

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