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CAS Number: 72939-63-0

SMILES : O=C(OCC=C)C#CCCCCCC

CHEM : 2-Nonynoic acid, 2-propenyl ester

MOL FOR: C12 H18 O2

MOL WT : 194.28

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.94

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 258.98 (Adapted Stein & Brown method)

Melting Pt (deg C): 57.87 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.0083 (Modified Grain method)

VP (Pa, 25 deg C) : 1.11 (Modified Grain method)

Subcooled liquid VP: 0.0167 mm Hg (25 deg C, Mod-Grain method)

: 2.23 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 20.15

log Kow used: 3.94 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 14.476 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Esters

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.76E-004 atm-m3/mole (1.78E+001 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.053E-004 atm-m3/mole (1.067E+001 Pa-m3/mole)

VP: 0.0083 mm Hg (source: MPBPVP)

WS: 20.1 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.94 (KowWin est)

Log Kaw used: -2.143 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 6.083

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.9377

Biowin2 (Non-Linear Model) : 0.9979

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.2084 (weeks )

Biowin4 (Primary Survey Model) : 4.0655 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.7934

Biowin6 (MITI Non-Linear Model): 0.8855

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.5460

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 2.23 Pa (0.0167 mm Hg)

Log Koa (Koawin est ): 6.083

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 1.35E-006

Octanol/air (Koa) model: 2.97E-007

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 4.87E-005

Mackay model : 0.000108

Octanol/air (Koa) model: 2.38E-005

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 43.9485 E-12 cm3/molecule-sec

Half-Life = 0.243 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.921 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 1.203000 E-17 cm3/molecule-sec

Half-Life = 0.953 Days (at 7E11 mol/cm3)

Half-Life = 22.863 Hrs

Fraction sorbed to airborne particulates (phi):

7.82E-005 (Junge-Pankow, Mackay avg)

2.38E-005 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 711 L/kg (MCI method)

Log Koc: 2.852 (MCI method)

Koc : 1094 L/kg (Kow method)

Log Koc: 3.039 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 1.366E+000 L/mol-sec

Kb Half-Life at pH 8: 5.872 days

Kb Half-Life at pH 7: 58.719 days

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.267 (BCF = 185.1 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.8636 days (HL = 0.1369 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.742 (BCF = 55.25)

Log BAF Arnot-Gobas method (upper trophic) = 1.742 (BAF = 55.25)

log Kow used: 3.94 (estimated)

Volatilization from Water:

Henry LC: 0.000176 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 6.059 hours

Half-Life from Model Lake : 183 hours (7.624 days)

Removal In Wastewater Treatment:

Total removal: 32.32 percent

Total biodegradation: 0.28 percent

Total sludge adsorption: 26.26 percent

Total to Air: 5.77 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.658 4.65 1000

Water 20.4 360 1000

Soil 78.4 720 1000

Sediment 0.539 3.24e+003 0

Persistence Time: 417 hr

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