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pyraclostrobin
carbamic acid, (2-(((1-(4-chlorophenyl)-1H-pyrazol-3-yl)oxy)methyl)phenyl)methoxy-, methyl ester

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Name:methyl N-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-N-methoxycarbamate
CAS Number: 175013-18-0Picture of molecule3D/inchi
FDA UNII: DJW8M9OX1H
Nikkaji Web:J1.571.715G
MDL:MFCD03792774
XlogP3-AA:4.10 (est)
Molecular Weight:387.82226000
Formula:C19 H18 Cl N3 O4
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:white or light beige crystalline solid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 501.10 °C. @ 760.00 mm Hg (est)
Flash Point: 494.00 °F. TCC ( 256.80 °C. ) (est)
logP (o/w): 4.250 (est)
Soluble in:
 water, 1.425 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Pyraclostrobine
Santa Cruz Biotechnology
For experimental / research use only.
Pyraclostrobin
Sigma-Aldrich
For experimental / research use only.
Pyraclostrobin PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for pyraclostrobin usage levels up to:
 not for fragrance use.
 
Recommendation for pyraclostrobin flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the modification of the existing MRLs for pyraclostrobin in swedes and turnips
View page or View pdf

Modification of the existing maximum residue level for pyraclostrobin in beet leaves (chards)
View page or View pdf

Modification of the existing maximum residue levels for pyraclostrobin in various crops
View page or View pdf

Evaluation of confirmatory data following the Article 12 MRL review for pyraclostrobin
View page or View pdf

Setting of an import tolerance for pyraclostrobin in rice
View page or View pdf

Modification of the existing maximum residue levels and setting of import tolerances for pyraclostrobin in various crops
View page or View pdf

Modification of the existing maximum residue levels for pyraclostrobin in soyabean
View page or View pdf

Modification of the existing maximum residue level for pyraclostrobin in sweet corn
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6422843
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
methyl N-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-N-methoxycarbamate
Chemidplus:0175013180
RTECS:EZ3441000 for cas# 175013-18-0
 
References:
 methyl N-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-N-methoxycarbamate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):6422843
Pubchem (sid):135246466
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18561
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 cabrio
 carbamic acid, (2-(((1-(4-chlorophenyl)-1H-pyrazol-3-yl)oxy)methyl)phenyl)methoxy-, methyl ester
 methyl N-(2-(1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl)phenyl)-(N-methoxy)carbamate
 methyl N-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-N-methoxycarbamate
 

Articles:

PubMed:Independent Emergence of Resistance to Seven Chemical Classes of Fungicides in Botrytis cinerea.
PubMed:Comparison of different cleanup procedures for oil crops based on the development of a trace analytical method for the determination of pyraclostrobin and epoxiconazole.
PubMed:[Comparative hygienic assessment of potential risk to workers under application of fungicides of different classes].
PubMed:Essential oils from Schinus species of northwest Argentina: Composition and antifungal activity.
PubMed:Foliar application of pyraclostrobin fungicide enhances the growth, rhizobial-nodule formation and nitrogenase activity in soybean (var. JS-335).
PubMed:Effect of paste processing on residue levels of imidacloprid, pyraclostrobin, azoxystrobin and fipronil in winter jujube.
PubMed:[Professional risk assessment for modern pesticides during their application in the horticulture].
PubMed:Fungicide resistance of Botrytis cinerea in tomato greenhouses in the Canary Islands and effectiveness of non-chemical treatments against gray mold.
PubMed:Suppression of hop looper (Lepidoptera: Noctuidae) by the fungicide pyraclostrobin.
PubMed:Inhibitory effects of respiration inhibitors on aflatoxin production.
PubMed:Pyraclostrobin wash-off from sugarcane leaves and aerobic dissipation in agricultural soil.
PubMed:Behavior of pyrimethanil, pyraclostrobin, boscalid, cypermethrin and chlorpyrifos residues on raspberry fruit and leaves of Laszka variety.
PubMed:Effect of a fungicide and spray adjuvant on queen-rearing success in honey bees (Hymenoptera: Apidae).
PubMed:Influence of new generation fungicides on Saccharomyces cerevisiae growth, grape must fermentation and aroma biosynthesis.
PubMed:Post-infection activities of fungicides against Cercospora arachidicola of peanut (Arachis hypogaea).
PubMed:Influence of biochar amendments on the sorption-desorption of aminocyclopyrachlor, bentazone and pyraclostrobin pesticides to an agricultural soil.
PubMed:Isolation and characterisation of azoxystrobin degrading bacteria from soil.
PubMed:Adsorption-desorption and leaching of pyraclostrobin in Indian soils.
PubMed:Accumulation of pesticides in Pacific chorus frogs (Pseudacris regilla) from California's Sierra Nevada Mountains, USA.
PubMed:Targeting the mitochondrial respiratory chain of Cryptococcus through antifungal chemosensitization: a model for control of non-fermentative pathogens.
PubMed:Effect of phenylpyrrole-resistance on fitness parameters and ochratoxin production in Aspergillus carbonarius.
PubMed:Effect of moisture, organic matter, microbial population and fortification level on dissipation of pyraclostrobin in soils.
PubMed:Environmental fate of fungicides and other current-use pesticides in a central California estuary.
PubMed:[Determination of seven strobilurin fungicide residues in Chinese herbs by liquid chromatography-tandem mass spectrometry coupled with solid phase extraction].
PubMed:Alteration of the content of primary and secondary metabolites in strawberry fruit by Colletotrichum nymphaeae infection.
PubMed:Acute toxicity of pyraclostrobin and trifloxystrobin to Hyalella azteca.
PubMed:Ultrasound-assisted surfactant-enhanced emulsification microextraction with solidification of floating organic droplet followed by high performance liquid chromatography for the determination of strobilurin fungicides in fruit juice samples.
PubMed:Pesticide leaching from two Swedish topsoils of contrasting texture amended with biochar.
PubMed:Molecular characterization, fitness and mycotoxin production of benzimidazole-resistant isolates of Penicillium expansum.
PubMed:Determination of strobilurin fungicide residues in fruits and vegetables by micellar electrokinetic capillary chromatography with sweeping.
PubMed:The usefulness of fungicide mixtures and alternation for delaying the selection for resistance in populations of Mycosphaerella graminicola on winter wheat: a modeling analysis.
PubMed:Occurrence and persistence of fungicides in bed sediments and suspended solids from three targeted use areas in the United States.
PubMed:Synergism of antifungal activity between mitochondrial respiration inhibitors and kojic acid.
PubMed:Quantifying the non-fungicidal effects of foliar applications of fluxapyroxad (Xemium) on stomatal conductance, water use efficiency and yield in winter wheat.
PubMed:Comparison of four extraction methods for the determination of fungicide residues in grapes through gas chromatography-mass spectrometry.
PubMed:Optimization and validation of a simple and fast method for the determination of fungicides in must and wine samples by SPE and GC/MS.
PubMed:Simultaneous determination of five pyrazole fungicides in cereals, vegetables and fruits using liquid chromatography/tandem mass spectrometry.
PubMed:Direct surface plasmon resonance immunosensing of pyraclostrobin residues in untreated fruit juices.
PubMed:Identifying the cause of sediment toxicity in agricultural sediments: the role of pyrethroids and nine seldom-measured hydrophobic pesticides.
PubMed:Identification of the G143A mutation associated with QoI resistance in Cercospora beticola field isolates from Michigan, United States.
PubMed:Micronuclei, nucleoplasmic bridges, and nuclear buds induced in human lymphocytes by the fungicide signum and its active ingredients (boscalid and pyraclostrobin).
PubMed:Occurrence of boscalid and other selected fungicides in surface water and groundwater in three targeted use areas in the United States.
PubMed:Dissipation of pyraclostrobin and its metabolite BF-500-3 in maize under field conditions.
PubMed:Biological activity of the succinate dehydrogenase inhibitor fluopyram against Botrytis cinerea and fungal baseline sensitivity.
PubMed:Pre-harvest treatments with fungicides and post-harvest dips in sodium bicarbonate to control postharvest decay in stone fruit.
PubMed:Residue dynamics of pyraclostrobin in peanut and field soil by QuEChERS and LC-MS/MS.
PubMed:Molecular characterization of pyraclostrobin resistance and structural diversity of the cytochrome b gene in Botrytis cinerea from apple.
PubMed:Snails as indicators of pesticide drift, deposit, transfer and effects in the vineyard.
PubMed:Impact of vineyard pesticides on a beneficial arthropod, Typhlodromus pyri (Acari: Phytoseiidae), in laboratory bioassays.
PubMed:Influence of fenamidone, indoxacarb, pyraclostrobin, and deltamethrin on the population of natural yeast microflora during winemaking of two sardinian grape cultivars.
PubMed:Evaluation of the incidence of the G143A mutation and cytb intron presence in the cytochrome bc-1 gene conferring QoI resistance in Botrytis cinerea populations from several hosts.
PubMed:Stability and fitness of pyraclostrobin- and boscalid-resistant phenotypes in field isolates of Botrytis cinerea from apple.
PubMed:Meta-analysis of yield response of hybrid field corn to foliar fungicides in the U.S. Corn Belt.
PubMed:Glove accumulation of pesticide residues for strawberry harvester exposure assessment.
PubMed:Development of immunoaffinity columns for pyraclostrobin extraction from fruit juices and analysis by liquid chromatography with UV detection.
PubMed:Effect of anilinopyrimidine resistance on aflatoxin production and fitness parameters in Aspergillus parasiticus Speare.
PubMed:Reducing the impact of pesticides on biological control in Australian vineyards: pesticide mortality and fecundity effects on an indicator species, the predatory mite Euseius victoriensis (Acari: Phytoseiidae).
PubMed:Synthesis of site-heterologous haptens for high-affinity anti-pyraclostrobin antibody generation.
PubMed:Toxicity of sediment-associated pesticides to Chironomus dilutus and Hyalella azteca.
PubMed:Multiple resistance of Botrytis cinerea from kiwifruit to SDHIs, QoIs and fungicides of other chemical groups.
PubMed:Response surface optimization for determination of pesticide residues in grapes using MSPD and GC-MS: assessment of global uncertainty.
PubMed:Biodegradation of epoxyconazole and piraclostrobin fungicides by Klebsiella sp. from soil.
PubMed:Minor crops for export: a case study of boscalid, pyraclostrobin, lufenuron and lambda-cyhalothrin residue levels on green beans and spring onions in Egypt.
PubMed:Stir bar sorptive extraction coupled to liquid chromatography for the analysis of strobilurin fungicides in fruit samples.
PubMed:Temperature, moisture, and fungicide effects in managing Rhizoctonia root and crown rot of sugar beet.
PubMed:Development, validation and application of a methodology based on solid-phase micro extraction followed by gas chromatography coupled to mass spectrometry (SPME/GC-MS) for the determination of pesticide residues in mangoes.
PubMed:Subnanomolar inhibitor of cytochrome bc1 complex designed by optimizing interaction with conformationally flexible residues.
PubMed:Development of a sample preparation method for the analysis of current-use pesticides in sediment using gas chromatography.
PubMed:Description of Cryptosporiopsis kienholzii and species profiles of Neofabraea in major pome fruit growing districts in the Pacific Northwest USA.
PubMed:Multiresidue determination of 11 new fungicides in grapes and wines by liquid-liquid extraction/clean-up and programmable temperature vaporization injection with analyte protectants/gas chromatography/ion trap mass spectrometry.
PubMed:Residue-free wines: fate of some quinone outside inhibitor (QoI) fungicides in the winemaking process.
PubMed:Toxicity of soybean rust fungicides to freshwater algae and Daphnia magna.
PubMed:Method development and validation for strobilurin fungicides in baby foods by solid-phase microextraction gas chromatography-mass spectrometry.
PubMed:Control of strobilurin fungicides in wheat using direct analysis in real time accurate time-of-flight and desorption electrospray ionization linear ion trap mass spectrometry.
PubMed:Characterization of mutations in the iron-sulphur subunit of succinate dehydrogenase correlating with Boscalid resistance in Alternaria alternata from California pistachio.
PubMed:Toxicity of six novel fungicides and sulphur to Galendromus occidentalis (Acari: Phytoseiidae).
PubMed:Production and characterization of monoclonal antibodies specific to the strobilurin pesticide pyraclostrobin.
PubMed:Pesticides selectivity list to beneficial arthropods in four field vegetable crops.
PubMed:Screening preharvest/postharvest strategies to prevent fruit rot decay.
PubMed:Acute pesticide poisoning associated with pyraclostrobin fungicide--Iowa, 2007.
PubMed:Acute and chronic toxicity of technical-grade pesticides to glochidia and juveniles of freshwater mussels (Unionidae).
PubMed:Validation and global uncertainty of a liquid chromatographic with diode array detection method for the screening of azoxystrobin, kresoxim-methyl, trifloxystrobin, famoxadone, pyraclostrobin and fenamidone in grapes and wine.
PubMed:[Susceptibility of Trichogramma pretiosum Riley (Hymenoptera: Trichogrammatidae) adults to fungicides used to control apple diseases].
PubMed:Cuticular uptake of xenobiotics into living plants. Part 2: influence of the xenobiotic dose on the uptake of bentazone, epoxiconazole and pyraclostrobin, applied in the presence of various surfactants, into Chenopodium album, Sinapis alba and Triticum aestivum leaves.
PubMed:Signum, a new fungicide for control of leaf diseases in outdoor vegetables.
PubMed:Re-examination of inhibitor resistance conferred by Qo-site mutations in cytochrome b using yeast as a model system.
PubMed:Signum, a new fungicide with interesting properties in resistance management of fungal diseases in strawberries.
PubMed:Modeling the Qo site of crop pathogens in Saccharomyces cerevisiae cytochrome b.
PubMed:A strobilurin fungicide enhances the resistance of tobacco against tobacco mosaic virus and Pseudomonas syringae pv tabaci.
 
Notes:
headline is used as a fungicide.
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