EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

asulam
methyl ((4-aminophenyl)sulfonyl)carbamate

Supplier Sponsors

CAS Number: 3337-71-1Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:222-077-1
FDA UNII: 0Y5ASM7P5S
Nikkaji Web:J3.401K
Beilstein Number:2697523
MDL:MFCD00055534
XlogP3:-0.30 (est)
Molecular Weight:230.24350000
Formula:C8 H10 N2 O4 S
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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US Patents:Search
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PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 144.00 °C. @ 760.00 mm Hg
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
logP (o/w): -0.270
Soluble in:
 water, 5000 mg/L @ 22 °C (exp)
 water, 2527 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
asulam
Santa Cruz Biotechnology
For experimental / research use only.
Asulam
Sigma-Aldrich
For experimental / research use only.
Asulam PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-chicken LD50 > 2000 mg/kg
Pesticide Manual. Vol. 9, Pg. 39, 1991.

oral-dog LD50 > 5000 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 15, Pg. 497, 1990.

oral-mouse LD50 > 5000 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 15, Pg. 497, 1990.

unreported-mouse LD50 5000 mg/kg
"Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 204, 1971.

oral-quail LD50 > 2000 mg/kg
Pesticide Manual. Vol. 9, Pg. 39, 1991.

oral-rabbit LD50 > 2000 mg/kg
"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A021, Pg. 1983

oral-rat LD50 2000 mg/kg
"Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 90, 1977.

Dermal Toxicity:
skin-rat LD50 > 10000 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 15, Pg. 497, 1990.

Inhalation Toxicity:
inhalation-rat LC50 > 18900 mg/m3
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 15, Pg. 497, 1990.
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for asulam usage levels up to:
 not for fragrance use.
 
Recommendation for asulam flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the review of the existing maximum residue levels (MRLs) for asulam according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Protocol for the evaluation of data concerning the necessity of the application of herbicide active substances to control a serious danger to plant health which cannot be contained by other available means, including non-chemical methods
View page or View pdf

Peer review of the pesticide risk assessment of the active substance asulam (variant evaluated asulam-sodium)
View page or View pdf

EPI System: View
EPA-Iris:IRIS
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :18752
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
methyl N-(4-aminophenyl)sulfonylcarbamate
Chemidplus:0003337711
 
References:
 methyl N-(4-aminophenyl)sulfonylcarbamate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):18752
Pubchem (sid):134981856
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18350
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 asulox 40
 asulox F
 carbamic acid, ((4-aminophenyl)sulfonyl)-, methyl ester (9CI)
 carbamic acid, [(4-aminophenyl)sulfonyl]-, methyl ester
 carbamic acid, N-[(4-aminophenyl)sulfonyl]-, methyl ester
 carbamic acid, sulfanilyl-, methyl ester (7CI)(8CI)
 methyl ((4-aminophenyl)sulfonyl)carbamate
 methyl [(4-aminophenyl)sulfonyl]carbamate
 methyl 4-aminobenzenesulfonyl carbamate
 methyl 4-aminobenzenesulphonyl carbamate
 methyl 4-aminobenzenesulphonylcarbamate
 methyl 4-aminophenylsulphonyl carbamate
 methyl 4-aminophenylsulphonylcarbamate
 methyl N-(4-aminobenzenesulfonyl)carbamate
 methyl N-(4-aminophenyl)sulfonylcarbamate
 methyl N-(4-aminophenylsulfonyl)carbamate
 methyl sulfanilyl carbamate
 methyl sulfanilylcarbamate
 methyl sulphanilylcarbamate
 

Articles:

PubMed:Ipso-hydroxylation and subsequent fragmentation: a novel microbial strategy to eliminate sulfonamide antibiotics.
PubMed:Combined theoretical and experimental study of the photophysics of asulam.
PubMed:Reversed phase liquid chromatography trace analysis of pesticides in soil by on-column sample pumping large volume injection and UV detection.
PubMed:Automated determination of asulam by enhanced chemiluminescence using luminol/peroxidase system.
PubMed:In-capillary microextraction using monolithic polymers: application to preconcentration of carbamate pesticides prior to their separation by MEKC.
PubMed:Crops with target-site herbicide resistance for Orobanche and Striga control.
PubMed:Electrocatalytic behaviour of carbon paste electrode modified with iron(II) phthalocyanine (FePc) nanoparticles towards the detection of amitrole.
PubMed:Herbicide Effects on Sugarcane Growth, Pythium Root Rot, and Pythium arrhenomanes.
PubMed:Determination of asulam by fast stopped-flow chemiluminescence inhibition of luminol/peroxidase.
PubMed:Comparative study of multi walled carbon nanotubes-based electrodes in micellar media and their application to micellar electrokinetic capillary chromatography.
PubMed:The effectiveness of asulam for bracken (Pteridium aquilinum) control in the United Kingdom: a meta-analysis.
PubMed:The effectiveness of management interventions used to control ragwort species.
PubMed:Fluorescence determination of the pesticide asulam by flow injection analysis.
PubMed:Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection.
PubMed:Aquatic risk assessment of a realistic exposure to pesticides used in bulb crops: a microcosm study.
PubMed:Contamination of honey by the herbicide asulam and its antibacterial active metabolite sulfanilamide.
PubMed:Dose-response relationships between herbicides with different modes of action and growth of Lemna paucicostata: an improved ecotoxicological method.
PubMed:The effects of a pesticide mixture on aquatic ecosystems differing in trophic status: responses of the macrophyte Myriophyllum spicatum and the periphytic algal community.
PubMed:Effect of natural organic matter on powdered activated carbon adsorption of trace contaminants: characteristics and mechanism of competitive adsorption.
PubMed:Exposure to Asulox inhibits the growth of mosses.
PubMed:Soil photolysis of herbicides in a moisture- and temperature-controlled environment.
PubMed:Capillary zone electrophoresis in wide bore capillary tubes with fiber-coupled diode array detection.
PubMed:Identification of a novel mannose-capped lipoarabinomannan from Amycolatopsis sulphurea.
PubMed:The first monoclonal antibody-based, matrix-resistant immunoassay for the carbamate herbicide asulam, in water.
PubMed:Iron (III) aquacomplexes as effective photocatalysts for the degradation of pesticides in homogeneous aqueous solutions.
PubMed:Pesticide adsorption by granular activated carbon adsorbers. 2. Effects of pesticide and natural organic matter characteristics on pesticide breakthrough curves.
PubMed:Pesticide adsorption by granular activated carbon adsorbers. 1. Effect of natural organic matter preloading on removal rates and model simplification.
PubMed:In vitro pesticide degradation in turfgrass soil incubated under open and sealed conditions.
PubMed:Determination of carbamate herbicide asulam in peaches following fluorescamine fluorigenic labelling.
PubMed:[The toxicity of herbicide Asulam].
PubMed:Assessment of the effects of herbicide spray drift on a range of plant species of conservation interest.
PubMed:Metabolism of the carbamate herbicide, asulam, in the rat.
PubMed:An h.p.l.c. method for the quantitative determination of asulam, acetylasulam and sulphanilamide in peaches.
PubMed:Identification and determination of asulam and related degradation products in soil.
PubMed:Direct analysis of the wild oat herbicide, asulam, in wheat samples by reversed-phase liquid chromatography at selected ultraviolet wavelengths.
PubMed:Effects of asulam on some microbial activities of three soils.
PubMed:Sensitive gas-liquid chromatographic method for asulam residues in peaches.
PubMed:The microbial degradation of a sulphanilamide-based herbicide (Asulam) [proceedings].
PubMed:A soil Flavobacterium sp. that degrades sulphanilamide and asulam.
PubMed:[Determination of asulam in air by the thin-layer chromatography method].
PubMed:Some patterns of herbicide and growth regulator intake, persistence, and distribution in sugarcane.
PubMed:Effect of asulam in wildlife specie residues and toxicity in bobwhite quail after prolonged exposure.
PubMed:Effect of asulam in wildlife species acute toxicity to birds and fish.
 
Notes:
wild oat herbicide used in prairie regions for control of wild oats in cereal grains such as wheat.
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