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trifloxystrobin
benzeneacetic acid, a-(methoxyimino)-2-[[[[(1E)-1-[3-(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]-, methyl ester, (aZ)-

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CAS Number: 141517-21-7Picture of molecule3D/inchi
Other(deleted CASRN):221007-60-9
FDA UNII: F625Z36B2D
Nikkaji Web:J2.223.913I
MDL:MFCD09953763
XlogP3-AA:4.90 (est)
Molecular Weight:408.37743960
Formula:C20 H19 F3 N2 O4
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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US Patents:Search
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PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 72.90 °C. @ 760.00 mm Hg (est)
Boiling Point: 470.35 °C. @ 760.00 mm Hg (est)
Vapor Pressure:2.500000 mmHg @ 25.00 °C. (est)
Flash Point: 461.00 °F. TCC ( 238.30 °C. ) (est)
logP (o/w): 5.112 (est)
Soluble in:
 water, 0.39 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
trifloxystrobin 98%
Glentham Life Sciences
Trifloxystrobin
Santa Cruz Biotechnology
For experimental / research use only.
Trifloxystrobin
Sigma-Aldrich
For experimental / research use only.
Trifloxystrobin PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for trifloxystrobin usage levels up to:
 not for fragrance use.
 
Recommendation for trifloxystrobin flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the modification of the existing MRL for trifloxystrobin in beans with pods
View page or View pdf

Reasoned opinion on the modification of the existing MRLs for trifloxystrobin in horseradish, parsley root and purslane
View page or View pdf

Reasoned Opinion on the review of the existing maximum residue levels (MRLs) for trifloxystrobin according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Reasoned opinion on the modification of the existing MRL for trifloxystrobin in cane fruit
View page or View pdf

Modification of the existing maximum residue level (MRL) for trifloxystrobin in celeriacs
View page or View pdf

Peer review of the pesticide risk assessment of the active substance trifloxystrobin
View page or View pdf

Modification of the existing maximum residue levels for trifloxystrobin in various crops
View page or View pdf

Modification of the existing maximum residue level for trifloxystrobin in broccoli
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :9578570
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
methyl(2Z)-2-methoxyimino-2-[2-[[(E)-1-[3-(trifluoromethyl)phenyl]ethylideneamino]oxymethyl]phenyl]acetate
Chemidplus:0141517217
 
References:
 methyl(2Z)-2-methoxyimino-2-[2-[[(E)-1-[3-(trifluoromethyl)phenyl]ethylideneamino]oxymethyl]phenyl]acetate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):9578570
Pubchem (sid):135187180
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEMBL:View
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
•trade names: flint; tega; compass; twist; zatao. mixtures: stratego (+propiconazole); agora (+cyproconazole); eclair (+cymoxanil); rombus (+propiconazole); sphere (+cyproconazole). •emulsifiable concentrate, water dispersable granules. •a water dispersible granular formulation for the three end-use products (flint, compass and stratego) contain 50% active ingredient.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 benzeneacetic acid, a-(methoxyimino)-2-[[[[(1E)-1-[3-(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]-, methyl ester, (aZ)-
 methyl (2Z)-(methoxyimino)(2-{[({(1E)-1-[3-(trifluoromethyl)phenyl]ethylidene}amino)oxy]methyl}phenyl)acetate
 methyl 2-[2-({(1E)-2-[3-(trifluoromethyl)phenyl]-1-azaprop-1-enyloxy}methyl)phenyl](2Z)-3-methoxy-3-azaprop-2-enoate
 methyl-(2Z)-(methoxyimino)(2-{[({(1E)-1-[3-(trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)acetate
 methyl(2Z)-2-methoxyimino-2-[2-[[(E)-1-[3-(trifluoromethyl)phenyl]ethylideneamino]oxymethyl]phenyl]acetate
 

Articles:

PubMed:Optimization of dispersive liquid-liquid microextraction based on the solidification of floating organic droplets using an orthogonal array design and its application for the determination of fungicide concentrations in environmental water samples.
PubMed:Persistence and dissipation kinetics of trifloxystrobin and tebuconazole in onion and soil.
PubMed:Potential toxic effect of trifloxystrobin on cellular microstructure, mRNA expression and antioxidant enzymes in Chlorella vulgaris.
PubMed:Simultaneous determination of trifloxystrobin and trifloxystrobin acid residue in rice and soil by a modified Quick, Easy, Cheap, Effective, Rugged, and Safe method using ultra high performance liquid chromatography with tandem mass spectrometry.
PubMed:Heteroplasmy of the cytochrome b gene in Venturia inaequalis and its involvement in quantitative and practical resistance to trifloxystrobin.
PubMed:Determination of strobilurin fungicides in cotton seed by combination of acetonitrile extraction and dispersive liquid-liquid microextraction coupled with gas chromatography.
PubMed:Immunoassays for trifloxystrobin analysis. Part I. Rational design of regioisomeric haptens and production of monoclonal antibodies.
PubMed:Effect of trifloxystrobin on hatching, survival, and gene expression of endocrine biomarkers in early life stages of medaka (Oryzias latipes).
PubMed:Bioefficacy, residue dynamics and safety assessment of the combination fungicide trifloxystrobin 25% + tebuconazole 50%-75 WG in managing early blight of tomato (Lycopersicon esculentum Mill.).
PubMed:Toxic effects of three strobilurins (trifloxystrobin, azoxystrobin and kresoxim-methyl) on mRNA expression and antioxidant enzymes in grass carp (Ctenopharyngodon idella) juveniles.
PubMed:Isolation and characterisation of azoxystrobin degrading bacteria from soil.
PubMed:Emerging pesticide metabolites in groundwater and surface water as determined by the application of a multimethod for 150 pesticide metabolites.
PubMed:[Determination of seven strobilurin fungicide residues in Chinese herbs by liquid chromatography-tandem mass spectrometry coupled with solid phase extraction].
PubMed:Comparative study on disappearance trends of captan and trifloxystrobin residues on fruit and apple tree leaves using internal normalisation method.
PubMed:Acute toxicity of pyraclostrobin and trifloxystrobin to Hyalella azteca.
PubMed:Ultrasound-assisted surfactant-enhanced emulsification microextraction with solidification of floating organic droplet followed by high performance liquid chromatography for the determination of strobilurin fungicides in fruit juice samples.
PubMed:Dissipation kinetics of trifloxystrobin and tebuconazole on apple (Malus domestica) and soil--a multi location study from north western Himalayan region.
PubMed:Simultaneous detection and degradation patterns of kresoxim-methyl and trifloxystrobin residues in citrus fruits by HPLC combined with QuEChERS.
PubMed:FcStuA from Fusarium culmorum controls wheat foot and root rot in a toxin dispensable manner.
PubMed:The Landau Stream Mesocosm Facility: pesticide mitigation in vegetated flow-through streams.
PubMed:Metabolism of strobilurins by wheat cell suspension cultures.
PubMed:Monitoring pesticide residues in greenhouse tomato by combining acetonitrile-based extraction with dispersive liquid-liquid microextraction followed by gas-chromatography-mass spectrometry.
PubMed:Dissipation kinetics of trifloxystrobin and tebuconazole on wheat leaves and their harvest time residues in wheat grains and soil.
PubMed:Identification of the G143A mutation associated with QoI resistance in Cercospora beticola field isolates from Michigan, United States.
PubMed:A quantitative solid-state Raman spectroscopic method for control of fungicides.
PubMed:Occurrence and distribution study of residues from pesticides applied under controlled conditions in the field during rice processing.
PubMed:Genetic analysis and molecular characterisation of laboratory and field mutants of Botryotinia fuckeliana (Botrytis cinerea) resistant to QoI fungicides.
PubMed:Toxicity of the fungicide trifloxystrobin on tadpoles and its effect on fish-tadpole interaction.
PubMed:Influence of pesticides on yeasts colonizing leaves.
PubMed:Dissipation kinetics of trifloxystrobin and tebuconazole on chili and soil.
PubMed:Environmental fate of fungicides in surface waters of a horticultural-production catchment in southeastern Australia.
PubMed:Meta-analysis of yield response of hybrid field corn to foliar fungicides in the U.S. Corn Belt.
PubMed:Determination of tebuconazole, trifloxystrobin and its metabolite in fruit and vegetables by a Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method using gas chromatography with a nitrogen-phosphorus detector and ion trap mass spectrometry.
PubMed:Reducing the impact of pesticides on biological control in Australian vineyards: pesticide mortality and fecundity effects on an indicator species, the predatory mite Euseius victoriensis (Acari: Phytoseiidae).
PubMed:Sensitivity to strobilurin fungicides of Italian Venturia inaequalis populations with different origin and scab control.
PubMed:Evaluation of comprehensive two-dimensional gas chromatography with micro-electron capture detection for the analysis of seven pesticides in sediment samples.
PubMed:Efficacy of fungicides with various modes of action in controlling the early stages of an Erysiphe necator-induced epidemic.
PubMed:Behaviour of trifloxystrobin and tebuconazole on grapes under semi-arid tropical climatic conditions.
PubMed:Stir bar sorptive extraction coupled to liquid chromatography for the analysis of strobilurin fungicides in fruit samples.
PubMed:Melanization of appressoria is critical for the pathogenicity of Diplocarpon rosae.
PubMed:Toxicity of fungicides with different modes of action to Cladobotryum dendroides and Agaricus bisporus.
PubMed:Influence of several fungicides on the antioxidant activity of red wines (var. Monastrell).
PubMed:Field leaching of pesticides at five test sites in Hawaii: study description and results.
PubMed:Persistence of trifloxystrobin and tebuconazole on grape leaves, grape berries and soil.
PubMed:Multiresidue determination of 11 new fungicides in grapes and wines by liquid-liquid extraction/clean-up and programmable temperature vaporization injection with analyte protectants/gas chromatography/ion trap mass spectrometry.
PubMed:To what extent are soil amendments useful to control Verticillium wilt?
PubMed:[In vitro activity of different fungicides on the growth in Mycosphaerella fijiensis var. difformis Stover and Dickson, Cladosporium musae Morelet and Deightoniella torulosa (Syd.) Ellis, isolated parasites of the banana phyllosphere in the Ivory Coast].
PubMed:Residue-free wines: fate of some quinone outside inhibitor (QoI) fungicides in the winemaking process.
PubMed:Method development and validation for strobilurin fungicides in baby foods by solid-phase microextraction gas chromatography-mass spectrometry.
PubMed:Control of strobilurin fungicides in wheat using direct analysis in real time accurate time-of-flight and desorption electrospray ionization linear ion trap mass spectrometry.
PubMed:Combinations of Fungicides with Phylloplane Yeasts for Improved Control of Botrytis cinerea on Geranium Seedlings.
PubMed:Field Resistance to Strobilurin (Q(o)I) Fungicides in Pyricularia grisea Caused by Mutations in the Mitochondrial Cytochrome b Gene.
PubMed:Synthesis and fungicidal activities of novel bis(trifluoromethyl)phenyl-based strobilurins.
PubMed:Analysis of pesticides in dried hops by liquid chromatography-tandem mass spectrometry.
PubMed:Synthesis and fungicidal activities of novel indene-substituted oxime ether strobilurins.
PubMed:Effect of the use of recent commercial fungicides [under good and critical agricultural practices] on the aroma composition of Monastrell red wines.
PubMed:Influence of fungicides on grape yeast content and its evolution in the fermentation.
PubMed:Removal of pesticides from white wine by the use of fining agents and filtration.
PubMed:Hapten synthesis and monoclonal antibody-based immunoassay development for detection of the fungicide trifloxystrobin.
PubMed:The drug transporter MgMfs1 can modulate sensitivity of field strains of the fungal wheat pathogen Mycosphaerella graminicola to the strobilurin fungicide trifloxystrobin.
PubMed:Determination of trifloxystrobin and its metabolites in Hawaii soils by ASE-LC-MS/MS.
PubMed:Field resistance to QoI fungicides in Podosphaera fusca is not supported by typical mutations in the mitochondrial cytochrome b gene.
PubMed:Removal of famoxadone, fluquinconazole and trifloxystrobin residues in red wines: effects of clarification and filtration processes.
PubMed:Validation and global uncertainty of a liquid chromatographic with diode array detection method for the screening of azoxystrobin, kresoxim-methyl, trifloxystrobin, famoxadone, pyraclostrobin and fenamidone in grapes and wine.
PubMed:Spectral elucidation of the acid metabolites of the four geometric isomers of trifloxystrobin.
PubMed:Safe apples for baby-food production: survey of pesticide treatment regimes leaving minimum residues.
PubMed:The evaluation of trifloxystrobin in protection of Calendula officinalis (Pot marigold) against Erysiphe cichoracearum DC.
PubMed:Environmental fate of trifloxystrobin in soils of different geographical origins and photolytic degradation in water.
PubMed:Rapid gas chromatographic method for the determination of famoxadone, trifloxystrobin and fenhexamid residues in tomato, grape and wine samples.
PubMed:Residues of the quinone outside inhibitor fungicide trifloxystrobin after postharvest dip treatments to control Penicillium spp. on citrus fruit.
PubMed:Residue evaluation of famoxadone and trifloxystrobin in cultivated mushrooms.
PubMed:The biological evaluation of Zato 50 WG in protection of carrot against Alternaria blight.
PubMed:Sensitivity of Venturia inaequalisto strobilurin fungicides in Italy.
PubMed:Investigating the role of ABC transporters in multifungicide insensitivity in Phytophthora infestans.
PubMed:Photoisomerization kinetics of trifloxystrobin.
PubMed:Screening of grapes and wine for azoxystrobin, kresoxim-methyl and trifloxystrobin fungicides by HPLC with diode array detection.
PubMed:Signum, a new fungicide with interesting properties in resistance management of fungal diseases in strawberries.
PubMed:Effects of fungicide residues on the survival, fecundity, and predation of the mites Tetranychus urticae (Acari: Tetranychidae) and Galendromus occidentalis (Acari: Phytoseiidae).
PubMed:First detection of resistance to QoI fungicides in Mycosphaerella graminicola on winter wheat in Belgium.
PubMed:Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables.
PubMed:Impact of strobilurins on physiology and yield formation of wheat.
PubMed:Impact of alternative respiration and target-site mutations on responses of germinating conidia of Magnaporthe grisea to Qo-inhibiting fungicides.
PubMed:Sensitivity of Venturia inaequalis to trifloxystrobin.
PubMed:Method validation for strobilurin fungicides in cereals and fruit.
PubMed:Sensitivity of mitochondrial respiration to different inhibitors in Venturia inaequalis.
PubMed:The ABC transporter BcatrB from Botrytis cinerea is a determinant of the activity of the phenylpyrrole fungicide fludioxonil.
 
Notes:
trifloxystrobin is the (e,e)-isomer; has antimicrobial activity against plant pathogens; strobilurin analogue.
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