EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

tert-butyl methacrylate
methacrylic acid, tert-butyl ester

Supplier Sponsors

CAS Number: 585-07-9Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:209-548-7
FDA UNII: F9029V5818
Nikkaji Web:J47.811C
Beilstein Number:1746394
MDL:MFCD00048245
XlogP3:2.50 (est)
Molecular Weight:142.19798000
Formula:C8 H14 O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:film forming agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
DG SANTE Food Contact Materials:methacrylic acid, tert-butyl ester
FDA Mainterm (IAUFC):585-07-9 ; TERT-BUTYL METHACRYLATE
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 156.94 °C. @ 760.00 mm Hg (est)
Vapor Pressure:6.170000 mmHg @ 25.00 °C. (est)
Flash Point: 106.00 °F. TCC ( 41.10 °C. ) (est)
logP (o/w): 2.540
Soluble in:
 water, 1000 mg/L @ 25 °C (exp)
 water, 555.3 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: film formers
 
Suppliers:
BASF
TBMA
BOC Sciences
For experimental / research use only.
tertiary-Butyl Methacrylate 95%
Kowa Amerian Corporation
t-BMA
Odor: characteristic
Use: t-BMA acts as a reactive monomer in order to produce other monomers/substances. t-BMA forms homopolymers and copolymers. tert-Butyl Methacrylate (t-BMA) is also a very useful feedstock for chemical syntheses, because it readily undergoes addition reactions with a wide variety of organic and inorganic compounds.
Santa Cruz Biotechnology
For experimental / research use only.
tert-Butyl Methacrylate ≥97%
Sigma-Aldrich: Aldrich
For experimental / research use only.
tert-Butyl Methacrylate 98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor
sds
TCI AMERICA
For experimental / research use only.
tert-Butyl Methacrylate Monomer (stabilized with MEHQ) >98.0%(GC)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-mouse LD50 8549 mg/kg
Toxicology Letters. Vol. 11, Pg. 125, 1982.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
film forming agents
Recommendation for tert-butyl methacrylate usage levels up to:
 not for fragrance use.
 
Recommendation for tert-butyl methacrylate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):585-07-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :11448
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
tert-butyl 2-methylprop-2-enoate
Chemidplus:0000585079
EPA/NOAA CAMEO:hazardous materials
RTECS:OZ3675500 for cas# 585-07-9
 
References:
 tert-butyl 2-methylprop-2-enoate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):11448
Pubchem (sid):134978658
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.14.2050
ChemSpider:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
tert-butyl 2-methylprop-2-enoate
t-butyl methacrylate
1,1-dimethylethyl 2-methyl-2-propenoate
 methacrylic acid t-butyl ester
 methacrylic acid tert-butyl ester
 methacrylic acid, tert-butyl ester
2-methyl-2-propanyl methacrylate
2-methyl-2-propenoic acid 1,1-dimethyl ethyl ester
2-methyl-2-propenoic acid 1,1-dimethylethyl ester
2-propenoic acid, 2-methyl-, 1,1-dimethylethyl ester
 

Articles:

PubMed:Thermodynamics of copolymer solutions: how the pair interactions contribute to the overall effect.
PubMed:Micro and macrorheology at fluid-fluid interfaces.
PubMed:Polycationic nanoparticles for siRNA delivery: comparing ARGET ATRP and UV-initiated formulations.
PubMed:Application of High-Resolution MALDI-TOFMS with a Spiral Ion Trajectory for the Structural Characterization of Free Radical Polymerized Methacrylate Ester Copolymers.
PubMed:Amphiphilic block copolymer modified magnetic nanoparticles for microwave-assisted extraction of polycyclic aromatic hydrocarbons in environmental water.
PubMed:Counterion-mediated hierarchical self-assembly of an ABC miktoarm star terpolymer.
PubMed:Phase transitions of n-hexadecane in nanoencapsulated binary solutions of n-hexadecane and 1-octanol.
PubMed:Dye-loaded porous nanocapsules immobilized in a permeable polyvinyl alcohol matrix: a versatile optical sensor platform.
PubMed:Correlations between Chemical Compositions and Retention Times of Methacrylate Random Copolymers Using LC-ESI-MS.
PubMed:Formation of polyampholyte brushes via controlled radical polymerization and their assembly in solution.
PubMed:Scanning thermal lithography of tailored tert-butyl ester protected carboxylic acid functionalized (meth)acrylate polymer platforms.
PubMed:Temperature- and pH-triggered reversible transfer of doubly responsive hairy particles between water and a hydrophobic ionic liquid.
PubMed:Core-crosslinked compartmentalized cylinders.
PubMed:Going beyond the surface: revealing complex block copolymer morphologies with 3D scanning force microscopy.
PubMed:Self-assembly of poly(4-methylstyrene)-g-poly(methacrylic acid) graft copolymer in selective solvents for grafts: scattering and molecular dynamics simulation study.
PubMed:Thermosensitive aqueous gels with tunable sol-gel transition temperatures from thermo- and pH-responsive hydrophilic ABA triblock copolymer.
PubMed:An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins.
PubMed:Amphoteric core-shell microgels: contraphilic two-compartment colloidal particles.
PubMed:Protein-functionalized hairy diamond nanoparticles.
PubMed:Alignment of tellurium nanorods via a magnetization-alignment-demagnetization ("MAD") process assisted by an external magnetic field.
PubMed:Undulated multicompartment cylinders by the controlled and directed stacking of polymer micelles with a compartmentalized corona.
PubMed:pH-responsive supramolecular self-assembly of well-defined zwitterionic ABC miktoarm star terpolymers.
PubMed:Structured and gradient polymer brushes from biphenylthiol self-assembled monolayers by self-initiated photografting and photopolymerization (SIPGP).
PubMed:Integral geometry analysis of fluorescence micrographs for quantitative relative comparison of protein adsorption onto polymer surfaces.
PubMed:Joint theoretical experimental investigation of the electron spin resonance spectra of nitroxyl radicals: application to intermediates in in situ nitroxide mediated polymerization (in situ NMP) of vinyl monomers.
PubMed:Staleya guttiformis attachment on poly(tert-butylmethacrylate) polymeric surfaces.
PubMed:A comparative study between the adsorption and covalent binding of human immunoglobulin and lysozyme on surface-modified poly(tert-butyl methacrylate).
PubMed:Vibrio fischeri and Escherichia coli adhesion tendencies towards photolithographically modified nanosmooth poly (tert-butyl methacrylate) polymer surfaces.
PubMed:Surface hydrophobicity modulates the operation of actomyosin-based dynamic nanodevices.
PubMed:Mesoscale simulations of the behavior of charged polymer brushes under normal compression and lateral shear forces.
PubMed:Polymer brushes in nanopores surrounded by silicon-supported tris(trimethylsiloxy)silyl monolayers.
PubMed:Towards nanoporous membranes based on ABC triblock terpolymers.
PubMed:Janus discs.
PubMed:An optical thermometer based on the delayed fluorescence of C70.
PubMed:One-pot synthesis of pegylated ultrasmall iron-oxide nanoparticles and their in vivo evaluation as magnetic resonance imaging contrast agents.
PubMed:Effects of temperature and chemical modification on polymer Langmuir films.
PubMed:ATP level variations in heterotrophic bacteria during attachment on hydrophilic and hydrophobic surfaces.
PubMed:Synthesis, isolation via self-assembly, and single-molecule observation of a [60]fullerene-end-capped isotactic poly(methyl methacrylate).
PubMed:Solvent-induced large compound vesicle of [60]fullerene containing poly(tert-butyl methacrylate).
PubMed:pH-sensitive unimolecular polymeric micelles: synthesis of a novel drug carrier.
PubMed:Detection of coccoid forms of Sulfitobacter mediterraneus using atomic force microscopy.
PubMed:Carbohydrate/monomer complexes in aqueous polymerizations: methylated-beta-cyclodextrin mediated aqueous polymerization of hydrophobic methacrylic monomers.
PubMed:Protein profiled features patterned via confocal microscopy.
PubMed:Actin motion on microlithographically functionalized myosin surfaces and tracks.
PubMed:Ultrathin films of a polyelectrolyte with layered architecture
 
Notes:
None found
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