Category:herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless odorless gas (est) |
Assay: | 95.00 to 100.00
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Food Chemicals Codex Listed: | No |
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-guinea pig LD50 100 mg/kg Dow Chemical Company Reports.
oral-rat LD50 100 mg/kg "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 3, Pg. 15, 1976/1977.
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
inhalation-mouse LCLo 1200 ppm/1H LUNGS, THORAX, OR RESPIRATION: CYANOSIS
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 34, Pg. 581, 1973.
inhalation-rabbit LCLo 5000 ppm/1H LUNGS, THORAX, OR RESPIRATION: CYANOSIS
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 34, Pg. 581, 1973.
inhalation-rat LC50 991 ppm/4H LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
LUNGS, THORAX, OR RESPIRATION: CYANOSIS Fundamental and Applied Toxicology. Vol. 7, Pg. 664, 1986.
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Safety in Use Information:
Category: | herbicides / pesticides |
Recommendation for sulfuryl fluoride usage levels up to: | | not for fragrance use.
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Recommendation for sulfuryl fluoride flavor usage levels up to: |
| not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
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Modification of the existing MRLs for sulfuryl fluoride and fluoride ion in chestnuts View page or View pdf
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Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level View page or View pdf
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Outcome of the consultation on confirmatory data used in risk assessment for sulfuryl fluoride View page or View pdf
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Review of the existing maximum residue levels for sulfuryl fluoride according to Article 12 of Regulation (EC) No 396/2005 View page or View pdf
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EPI System: View |
NIOSH International Chemical Safety Cards:search |
NIOSH Pocket Guide:search |
AIDS Citations:Search |
Cancer Citations:Search |
Toxicology Citations:Search |
EPA Substance Registry Services (TSCA):2699-79-8 |
EPA ACToR:Toxicology Data |
EPA Substance Registry Services (SRS):Registry |
Laboratory Chemical Safety Summary :17607 |
National Institute of Allergy and Infectious Diseases:Data |
sulfuryl difluoride |
Chemidplus:0002699798 |
EPA/NOAA CAMEO:hazardous materials |
RTECS:2699-79-8 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| EPA pesticide chemical code 078003 | | fluoro de sulfurilo | | fluorure de sulfuryle | | HSDB 828 | | sulfonyl fluoride | | sulfur difluoride dioxide | | sulfuric oxyfluoride | | sulfuryl difluoride | | sulfuryl fluoride [UN2191] [Poison gas] | | sulphuryl difluoride | | sulphuryl fluoride | | sulphuryl fluoride [ISO] | | vikane |
Articles:
PubMed:Controlling pests in dry-cured ham: A review. |
PubMed:Evaluation of Structural Treatment Efficacy against Tribolium castaneum and Tribolium confusum (Coleoptera: Tenebrionidae) Using Meta-Analysis of Multiple Studies Conducted in Food Facilities. |
PubMed:Exposure of Brown Recluse and Brown Widow Spiders (Araneae: Sicariidae, Theridiidae) to a Commercial Sulfuryl Fluoride Fumigation. |
PubMed:Evaluation of methyl bromide alternatives efficacy against soil-borne pathogens, nematodes and soil microbial community. |
PubMed:Evaluation of sorbent materials for the sampling and analysis of phosphine, sulfuryl fluoride and methyl bromide in air. |
PubMed:Susceptibility to sulfuryl fluoride and lack of cross-resistance to phosphine in developmental stages of the red flour beetle, Tribolium castaneum (Coleoptera: Tenebrionidae). |
PubMed:Fumigation of bed bugs (Hemiptera: Cimicidae): effective application rates for sulfuryl fluoride. |
PubMed:Sulfur(VI) fluoride exchange (SuFEx): another good reaction for click chemistry. |
PubMed:A chemical "hub" for absolute quantification of a targeted protein: orthogonal integration of elemental and molecular mass spectrometry. |
PubMed:Sulfonyl fluorides as alternative to sulfonyl chlorides in parallel synthesis of aliphatic sulfonamides. |
PubMed:Ascertaining the suitability of aryl sulfonyl fluorides for [18F]radiochemistry applications: a systematic investigation using microfluidics. |
PubMed:Decomposition treatment of SO2F2 using packed bed DBD plasma followed by chemical absorption. |
PubMed:Production, partial purification and characterization of protease from a phytopathogenic fungi Alternaria solani (Ell. and Mart.) Sorauer. |
PubMed:Broad-spectrum antimalarial activity of peptido sulfonyl fluorides, a new class of proteasome inhibitors. |
PubMed:Chemical proteomics with sulfonyl fluoride probes reveals selective labeling of functional tyrosines in glutathione transferases. |
PubMed:Efficacy of sulfuryl fluoride against the pinewood nematode, Bursaphelenchus xylophilus (Nematoda: Aphelenchidae), in Pinus pinaster boards. |
PubMed:Evaluation of sulfuryl fluoride as a soil fumigant in China. |
PubMed:Tribolium castaneum (Coleoptera: Tenebrionidae) associated with rice mills: fumigation efficacy and population rebound. |
PubMed:Sulfonyl fluoride analogues as activity-based probes for serine proteases. |
PubMed:Sulfonyl fluoride-based prosthetic compounds as potential 18F labelling agents. |
PubMed:Effectiveness of sulfuryl fluoride for control of different life stages of stored-product psocids (Psocoptera). |
PubMed:Europium-labeled activity-based probe through click chemistry: absolute serine protease quantification using (153)Eu isotope dilution ICP/MS. |
PubMed:Polyisoprenylation potentiates the inhibition of polyisoprenylated methylated protein methyl esterase and the cell degenerative effects of sulfonyl fluorides. |
PubMed:Synthesis and biological evaluation of novel irreversible serine protease inhibitors using amino acid based sulfonyl fluorides as an electrophilic trap. |
PubMed:Anomeric effects in sulfonyl compounds: an experimental and computational study of fluorosulfonyl azide, FSO(2)N(3), and trifluoromethylsulfonyl azide, CF(3)SO(2)N(3). |
PubMed:Sulfuryl fluoride as a quarantine treatment for emerald ash borer (Coleoptera: Buprestidae) in ash logs. |
PubMed:Environmental and health risks of sulfuryl fluoride, a fumigant replacement for methyl bromide. |
PubMed:Sulfuryl fluoride as a quarantine treatment for Chlorophorus annularis (Coleoptera: Cerambycidae) in Chinese bamboo poles. |
PubMed:Sulfuryl fluoride fumigation effects on the safety, volatile composition, and sensory quality of dry cured ham. |
PubMed:Reactive and nonreactive quenching of O(1D) by the potent greenhouse gases SO2F2, NF3, and SF5CF3. |
PubMed:Atmospheric chemistry of sulfuryl fluoride: reaction with OH radicals, Cl atoms and O3, atmospheric lifetime, IR spectrum, and global warming potential. |
PubMed:Experimental and theoretical study of the atmospheric chemistry and global warming potential of SO2F2. |
PubMed:Systemic fluoride poisoning and death from inhalational exposure to sulfuryl fluoride. |
PubMed:Sorption of sulfuryl fluoride by food commodities. |
PubMed:[Determination of sulfuryl fluoride and ethylene oxide in aerosol pesticide by GC]. |
PubMed:Evaluation of microwave irradiation for analysis of carbonyl sulfide, carbon disulfide, cyanogen, ethyl formate, methyl bromide, sulfuryl fluoride, propylene oxide, and phosphine in hay. |
PubMed:Lipid chain selectivity by outer membrane phospholipase A. |
PubMed:Sulfuryl fluoride as a quarantine treatment for Anoplophora glabripennis (Coleoptera: Cerambycidae) in regulated wood packing material. |
PubMed:A convenient preparation of heteroaryl sulfonamides and sulfonyl fluorides from heteroaryl thiols. |
PubMed:A scaled quantum mechanical force field for the sulfuryl halides II. The SO(2)XF (X=Cl, Br) halides. |
PubMed:Rapid uptake, metabolism, and elimination of inhaled sulfuryl fluoride fumigant by rats. |
PubMed:Convenient synthesis of fluorinated nucleosides with perfluoroalkanesulfonyl fluorides. |
PubMed:Alternatives to methyl bromide treatments for stored-product and quarantine insects. |
PubMed:Inhibition of lipoprotein lipase by alkanesulfonyl fluorides. |
PubMed:Centrifugal Distortion Analysis of a Near-Spherical Top, SO(2)F(2): The First Determination of All Six Quartic Centrifugal Distortion Constants for an Asymmetric Top. |
PubMed:Health effects associated with sulfuryl fluoride and methyl bromide exposure among structural fumigation workers. |
PubMed:Agreement between company-recorded and self-reported estimates of duration and frequency of occupational fumigant exposure. |
PubMed:Sulfonyl fluorides and the promotion of diisopropyl fluorophosphate neuropathy. |
PubMed:Residues of methyl bromide and sulfuryl fluoride in manufacturer-packaged household foods following fumigation. |
PubMed:Fluoride residues in frozen foods fumigated with sulfuryl fluoride. |
PubMed:The effects of inhalation exposure to sulfuryl fluoride on fetal development in rats and rabbits. |
PubMed:Inhalation toxicity of sulfuryl fluoride in rats and rabbits. |
PubMed:Subchronic neurotoxicity in rats of the structural fumigant, sulfuryl fluoride. |
PubMed:Desorption of residual sulfuryl fluoride from structural and household commodities by headspace analysis using gas chromatography. |
PubMed:Leads from the MMWR. Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia. |
PubMed:Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia. |
PubMed:Incapacitation and treatment of rats exposed to a lethal dose of sulfuryl fluoride. |
PubMed:Suicide by exposure to sulfuryl fluoride. |
PubMed:Neurobehavioral evaluation of soil and structural fumigators using methyl bromide and sulfuryl fluoride. |
PubMed:Carpet beetle dermatitis. |
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