EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes

vinyl acetate
acetic acid, vinyl ester

Supplier Sponsors

Name:ethenyl acetate
CAS Number: 108-05-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:203-545-4
FDA UNII: L9MK238N77
Nikkaji Web:J2.860F
Beilstein Number:4290704
MDL:MFCD00008713
XlogP3:0.70 (est)
Molecular Weight:86.09022000
Formula:C4 H6 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:food-contact surface of paper and paperboard
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
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Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
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Pubchem Patents:Search
PubMed:Search
NCBI:Search
DG SANTE Food Contact Materials:acetic acid, vinyl ester
FDA Mainterm (SATF):108-05-4 ; VINYL ACETATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart I--Multipurpose Additives
Sec. 172.892 Food starch-modified.


FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS
Subpart B--Substances for Use Only as Components of Adhesives
Sec. 175.105 Adhesives.


FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS
Subpart C--Substances for Use as Components of Coatings
Sec. 175.320 Resinous and polymeric coatings for polyolefin films.


FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS
Subpart C--Substances for Use as Components of Coatings
Sec. 175.350 Vinyl acetate/crotonic acid copolymer.


FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS
Subpart B--Substances for Use Only as Components of Paper and Paperboard
Sec. 176.170 Components of paper and paperboard in contact with aqueous and fatty foods.


FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS
Subpart B--Substances for Use Only as Components of Paper and Paperboard
Sec. 176.170 Components of paper and paperboard in contact with aqueous and fatty foods.


FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS
Subpart B--Substances for Use Only as Components of Paper and Paperboard
Sec. 176.180 Components of paper and paperboard in contact with dry food.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Surfaces
Sec. 177.1330 Ionomeric resins.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact
Sec. 177.1350 Ethylene-vinyl acetate copolymers.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Surfaces
Sec. 177.1360 Ethylene-vinyl acetate-vinyl alcohol copolymers.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact
Sec. 177.1390 Laminate structures for use at temperatures of 250 deg. F and above.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart C--Substances for Use Only as Components of Articles Intended for Repeated Use
Sec. 177.2250 Filters, microporous polymeric.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart C--Substances for Use Only as Components of Articles Intended for Repeated Use
Sec. 177.2260 Filters, resin-bonded.


FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS
Subpart C--Substances for Use Only as Components of Articles Intended for Repeated Use
Sec. 177.2800 Textiles and textile fibers.
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.93200 to 0.93500 @ 20.00 °C.
Pounds per Gallon - (est).: 7.764 to 7.789
Refractive Index:1.39200 to 1.39900 @ 20.00 °C.
Melting Point: 72.00 to 73.00 °C. @ 760.00 mm Hg
Boiling Point: 72.50 °C. @ 760.00 mm Hg
Vapor Pressure:118.484001 mmHg @ 25.00 °C. (est)
Flash Point: 20.00 °F. TCC ( -6.67 °C. )
logP (o/w): 0.730
Soluble in:
 water, 20000 mg/L @ 20 °C (exp)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: film formers
 
Suppliers:
Dow Chemical
DOW Vinyl Acetate Monomer
ECSA Chemicals
VINYL ACETATE
ECSA TRADE THE MOST UPDATED FINANCIAL PUBLICATION ON THE WORLD OF CHEMISTRY
EMD Millipore
For experimental / research use only.
Vinyl Acetate
sds
LyondellBasell Industries
Vinyl Acetate Monomer
Penta International
VINYL ACETATE STABILIZED
Sigma-Aldrich: Aldrich
For experimental / research use only.
Vinyl acetate, contains 3-20 ppm hydroquinone as inhibitor, ≥99%
sds
Silver Fern Chemical
Vinyl Acetate Monomer (VAM)
Odor: characteristic
Use: Vinyl acetate monomer is chemical building block used for a wide variety of industrial and consumer products, particularly polyvinyl acetate. It is used to produce paints, adhesives, coatings, and polyester fiber-fill insulation textiles. Other end products include adhesives, insulation for magnetic wires, and safety glass.
TCI AMERICA
For experimental / research use only.
Vinyl Acetate Monomer (stabilized with HQ) >99.0%(GC)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 2900 mg/kg
National Technical Information Service. Vol. OTS0521596

intraperitoneal-guinea pig LDLo 500 mg/kg
LIVER: FATTY LIVER DEGERATION
American Industrial Hygiene Association Journal. Vol. 35, Pg. 21, 1974.

oral-mouse LD50 1600 mg/kg
National Technical Information Service. Vol. OTS0521596

Dermal Toxicity:
skin-rabbit LD50 2335 mg/kg
E.I. Dupont de Nemours and Company, Technical Sheet. Vol. ES-3574, Pg. 1975

Inhalation Toxicity:
inhalation-rat LC50 11400 mg/m3/4H
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(11), Pg. 57, 1981.

inhalation-guinea pig LC50 6200 ppm/4H
National Technical Information Service. Vol. OTS0521596

inhalation-mouse LC50 1550 ppm/4H
E.I. Dupont de Nemours and Company, Technical Sheet. Vol. ES-3574, Pg. 1975

inhalation-rabbit LC50 2500 ppm/4H
"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 5, Pg. 621, 1986.
 
Safety in Use Information:
Category:
food-contact surface of paper and paperboard
Recommendation for vinyl acetate usage levels up to:
 not for fragrance use.
 
Recommendation for vinyl acetate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA-Iris:IRIS
NIOSH International Chemical Safety Cards:search
NIOSH Pocket Guide:search
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
Carcinogenic Potency Database:Search
EPA GENetic TOXicology:Search
EPA Substance Registry Services (TSCA):108-05-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7904
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1301
WGK Germany:2
ethenyl acetate
Chemidplus:0000108054
EPA/NOAA CAMEO:hazardous materials
RTECS:108-05-4
 
References:
 ethenyl acetate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:108-05-4
Pubchem (cid):7904
Pubchem (sid):134972749
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
FDA Indirect Additives used in Food Contact Substances:View
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C19309
HMDB (The Human Metabolome Database):Search
FooDB:FDB003232
Export Tariff Code:2915.32.0000
FDA Listing of Food Additive Status:View
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
•various commercial grades of vinyl acetate are available in usa, which differ only in the amt of inhibitor added: 3-5 mgl (ppm) hydroquinone are present when use is expected within 2 mo of delivery; 14-17 mgl (ppm) hydroquinone for up to 4 mo of storage; & 200-300 mgl (ppm) diphenylamine when indefinite storage is anticipated. •grades or purity: grade a (diphenylamine-inhibited): 99.8%; grade h (hydroquinone-inhibited): 99.8%
 
Potential Blenders and core components note
None Found
 
Potential Uses:
 film formers
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 acetic acid ethenyl ester
 acetic acid ethylene ether
 acetic acid vinyl ester
 acetic acid vinyl ester monomer
 acetic acid, ethenyl ester
 acetic acid, ethylene ether
 acetic acid, vinyl ester
 acetoxyethene
 acetoxyethylene
1-acetoxyethylene
 DOW vinyl acetate monomer
 ethanoic acid, ethenyl ester
 ethenyl acetate
 ethenyl ethanoate
 vinyl acetate monomer
 vinyl acetate stabilized
 vinyl acetate, inhibited [UN1301] [Flammable liquid]
 vinyl ethanoate
 vinylacetate
 

Articles:

PubMed:Molecular imprinting method for fabricating novel glucose sensor: Polyvinyl acetate electrode reinforced by MnO2/CuO loaded on graphene oxide nanoparticles.
PubMed:Assessment of starch-based wood adhesive quality by confocal Raman microscopic detection of reaction homogeneity.
PubMed:Ultrasound assisted lipase catalyzed synthesis of cinnamyl acetate via transesterification reaction in a solvent free medium.
PubMed:Application of plastic polymers in remediating wine with elevated alkyl-methoxypyrazine levels.
PubMed:Highly efficient and regioselective synthesis of dihydromyricetin esters by immobilized lipase.
PubMed:Chemoenzymatic synthesis of 1,3-dioleoyl-2-palmitoylglycerol.
PubMed:Selective oxygenation of alkynes: a direct approach to diketones and vinyl acetate.
PubMed:Physicochemical, morphological, thermal and IR spectral changes in the properties of waxy rice starch modified with vinyl acetate.
PubMed:Effect of different new packaging materials on biscuit quality during accelerated storage.
PubMed:Enzymatic acylation of flavonoid glycosides by a carbohydrate esterase of family 16.
PubMed:Structure-property relationships of reactively compatibilized PHB/EVA/starch blends.
PubMed:An efficient enzymatic modification of cordycepin in ionic liquids under ultrasonic irradiation.
PubMed:Effect of packaging material on enological parameters and volatile compounds of dry white wine.
PubMed:Biosynthesis of sucrose-6-acetate catalyzed by surfactant-coated Candida rugosa lipase immobilized on sol-gel supports.
PubMed:Enzymes involved in vinyl acetate decomposition by Pseudomonas fluorescens PCM 2123 strain.
PubMed:Aroma-active components of yeast extract pastes with a basic and characteristic meaty flavour.
PubMed:Solvent-Free Synthesis of Flavour Esters through Immobilized Lipase Mediated Transesterification.
PubMed:Immobilization and Biochemical Properties of the Enantioselective Recombinant NStcI Esterase of Aspergillus nidulans.
PubMed:Highly efficient and regioselective acylation of pharmacologically interesting cordycepin catalyzed by lipase in the eco-friendly solvent 2-methyltetrahydrofuran.
PubMed:Rapid synthesis of cellulose esters by transesterification of cellulose with vinyl esters under the catalysis of NaOH or KOH in DMSO.
PubMed:Identification and quantification of odorous compounds from adhesives used in food packaging materials by headspace solid phase extraction and headspace solid phase microextraction coupled to gas chromatography-olfactometry-mass spectrometry.
PubMed:Release kinetics of tocopherol and quercetin from binary antioxidant controlled-release packaging films.
PubMed:Enzymatic synthesis of rose aromatic ester (2-phenylethyl acetate) by lipase.
PubMed:Incorporation of nisin in poly (ethylene-co-vinyl acetate) films by melt processing: a study on the antimicrobial properties.
PubMed:Release of naturally derived antimicrobial agents from LDPE films.
PubMed:Control of biofilm formation by poly-ethylene-co-vinyl acetate films incorporating nisin.
PubMed:Regioselective lipase-catalyzed synthesis of 3-o-acyl derivatives of resveratrol and study of their antioxidant properties.
PubMed:Transdermal delivery of fentanyl from matrix and reservoir systems: effect of heat and compromised skin.
PubMed:Macroporous poly(vinyl alcohol) microspheres bearing phosphate groups as a new adsorbent for low-density lipoprotein apheresis.
PubMed:[Study of relationship between consumption of potassium permanganate and total organic carbon on plastic kitchen utensils, food packages and toys].
PubMed:Pulsed light inactivation of Listeria monocytogenes through different plastic films.
PubMed:[Model for the functional instruction of swallowing].
PubMed:[Stability investigation of total parenteral nutrition admixture prepared in a hospital pharmacy].
PubMed:Odour investigation of granular polyolefins for flexible food packaging using a sensory panel and an electronic nose.
PubMed:New insights on poly(vinyl acetate)-based coated floating tablets: characterisation of hydration and CO2 generation by benchtop MRI and its relation to drug release and floating strength.
PubMed:Contraceptive vaginal ring.
PubMed:Effectiveness and stability of plastic films coated with nisin for inhibition of Listeria monocytogenes.
PubMed:Typical diffusion behaviour in packaging polymers - application to functional barriers.
PubMed:Influence of polymer matrix and adsorption onto silica materials on the migration of alpha-tocopherol into 95% ethanol from active packaging.
PubMed:Investigation of fungal deterioration of synthetic paint binders using vibrational spectroscopic techniques.
PubMed:Controlled release of tebuconazole from a polymer matrix microparticle: release kinetics and length of efficacy.
PubMed:Migration of volatile degradation products into ozonated water from plastic packaging materials.
PubMed:Effect of ionizing radiation on the physicochemical and mechanical properties of commercial monolayer flexible plastics packaging materials.
PubMed:Determination of toxicokinetic parameters for bioconcentration of water-soluble fraction of petroleum hydrocarbon associated with no. 0 diesel in Changjiang estuary and Jiaozhou bay: model versus mesocosm experiments.
PubMed:Thin-film solid-phase extraction to measure fugacities of organic chemicals with low volatility in biological samples.
PubMed:Local delivery of tetracycline: from concept to clinical application.
PubMed:Mathematical modelling of microbial growth in packaged refrigerated beef stored at different temperatures.
PubMed:Life on a string: development of the tetracycline fiber delivery system.
PubMed:Behaviour of Chimassorb 81 in the recycling process of agricultural films used as soil covers.
PubMed:Contraceptive implants.
PubMed:Chronic toxicity and oncogenicity study with vinyl acetate in the rat: in utero exposure in drinking water.
PubMed:Development and implementation of a safety evaluation program for chemical fibers.
PubMed:Availability of insulin from total parenteral nutrition solutions.
PubMed:Migration of Irganox 1010 from ethylene-vinyl acetate films to foods and food-simulating liquids.
PubMed:[Hygienic evaluation of tea-bag paper].
PubMed:[Sanitary chemical evaluation of TK-2P brand thermal glue based on an ethylene copolymer with vinyl acetate].
 
Notes:
Esterification agent for modification of food starch
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