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Category:food starch-modified
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Assay: | 95.00 to 100.00
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 1.64500 @ 25.00 °C.
|
| Boiling Point: | 105.00 to 106.00 °C. @ 760.00 mm Hg (est)
|
| Vapor Pressure: | 34.570999 mmHg @ 25.00 °C. (est) |
| Flash Point: | 32.00 °F. TCC ( 0.00 °C. ) (est)
|
| logP (o/w): | 0.357 (est) |
| Soluble in: |
| | water, 6.197e+004 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 36 mg/kg
LIVER: OTHER CHANGES
GASTROINTESTINAL: OTHER CHANGES
National Technical Information Service. Vol. OTS0534840
oral-mouse LD50 327 mg/kg
Weisheng Dulixue Zazhi. Journal of Health Toxicology. Vol. 6, Pg. 98, 1992.
|
| Dermal Toxicity: |
skin-rabbit LDLo 1000 mg/kg
BEHAVIORAL: MUSCLE WEAKNESS
LIVER: OTHER CHANGES
National Technical Information Service. Vol. OTS0534840
|
| Inhalation Toxicity: |
inhalation-rat LC50 32 ppm/4H
"Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 17, 1972.
inhalation-mouse LC50 404 mg/m3/2H
Weisheng Dulixue Zazhi. Journal of Health Toxicology. Vol. 6, Pg. 98, 1992.
inhalation-guinea pig LC50 53 ppm/4H
BEHAVIORAL: IRRITABILITY
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
American Industrial Hygiene Association Journal. Vol. 25, Pg. 470, 1964.
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Safety in Use Information:
| Category: | | food starch-modified |
| Recommendation for phosphorus oxychloride usage levels up to: | | | not for fragrance use.
|
| |
| Recommendation for phosphorus oxychloride flavor usage levels up to: |
| | not for flavor use.
|
Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | phosphoric chloride | | | phosphoric trichloride | | | phosphoroxychloride | | | phosphoroyl trichloride | | | phosphorus oxide trichloride | | | phosphorus oxytrichloride | | | phosphorus(V) oxychloride | | | phosphorusoxychloride | | | phosphoryl chloride | | | trichloridooxidophosphorus | | | trichlorophosphorus oxide |
Articles:
| PubMed:[Toxicity and treatment strategies of phosphorus oxychloride]. |
| PubMed:A modular phosphate tether-mediated divergent strategy to complex polyols. |
| PubMed:[Analysis of eight cases of acute phosphorus oxychloride poisoning]. |
| PubMed:Synthesis of the allelochemical alliarinoside present in garlic mustard (Alliaria petiolata), an invasive plant species in North America. |
| PubMed:Synthesis and Properties of Heavy Chalcogen Analogues of the Texas Reds and Related Rhodamines. |
| PubMed:Synthesis and characterization of symmetric cyclooctatetraindoles: exploring the potential as electron-rich skeletons with extended π-systems. |
| PubMed:Synthesis of α-d-glucosyl substituted methyl glycosides of 3-deoxy-α-d-manno- and d-glycero-α-d-talo-oct-2-ulosonic acid (Kdo/Ko) corresponding to inner core fragments of Acinetobacter lipopolysaccharide. |
| PubMed:Perfluoroalkyl-substituted thiophenes and pyrroles from donor-acceptor cyclopropanes and heterocumulenes: synthesis and exploration of their reactivity. |
| PubMed:Synthesis of new 2,5-di-substituted 1,3,4-oxadiazoles bearing 2,6-di-tert-butylphenol moieties and evaluation of their antioxidant activity. |
| PubMed:Preparation of 2-aminopyridoimidazoles and 2-aminobenzimidazoles via phosphorus oxychloride-mediated cyclization of aminoureas. |
| PubMed:Synthesis and biological evaluation of 2,5-di(7-indolyl)-1,3,4-oxadiazoles, and 2- and 7-indolyl 2-(1,3,4-thiadiazolyl)ketones as antimicrobials. |
| PubMed:Synthesis and antiproliferative assay of norcantharidin derivatives in cancer cells. |
| PubMed:Effects of the order of addition of reagents and catalyst on modification of maize starches. |
| PubMed:Rapid self-healable poly(ethylene glycol) hydrogels formed by selective metal-phosphate interactions. |
| PubMed:Unusual formation of 21-oxacorrole from 21-oxaporphyrin induced by phosphoryl chloride. |
| PubMed:Syntheses and anti-allergic activity of 2-((bis(trimethylsilyl)methylthio/methylsulfonyl)methyl)-5-aryl-1,3,4-oxadiazoles. |
| PubMed:Ungeremine and Its hemisynthesized analogues as bactericides against Flavobacterium columnare. |
| PubMed:Synthesis and in vitro antiproliferative activity of new 11-aminoalkylamino-substituted chromeno[2,3-b]indoles. |
| PubMed:A study of the reaction of perfluoroalkyl Grignard reagents with phosphoryl chloride and phenylphosphonic dichloride. |
| PubMed:Uses of 2-ethoxy-4(3H) quinazolinone in synthesis of quinazoline and quinazolinone derivatives of antimicrobial activity: the solvent effect. |
| PubMed:Synthesis of a new series of pyridine and fused pyridine derivatives. |
| PubMed:Study on the characteristics of amorphous low-K thin film for solar cells. |
| PubMed:Straightforward acid-catalyzed synthesis of pyrrolyldipyrromethenes. |
| PubMed:Hydrolysis studies of phosphodichloridate and thiophosphodichloridate ions. |
| PubMed:Efficient synthesis of exo-N-carbamoyl nucleosides: application to the synthesis of phosphoramidate prodrugs. |
| PubMed:Large-scale solvent-free chlorination of hydroxy-pyrimidines, -pyridines, -pyrazines and -amides using equimolar POCl₃. |
| PubMed:Facile synthesis, characterization and pharmacological activities of 3,6-disubstituted 1,2,4-triazolo[3,4-b][1,3,4]thiadiazoles and 5,6-dihydro-3,6-disubstituted-1,2,4-triazolo[3,4-b][1,3,4]thiadiazoles. |
| PubMed:Synthesis and evaluation of substituted diphenyl-1,3,4-oxadiazole derivatives for central nervous system depressant activity. |
| PubMed:A facile iodine(III)-mediated synthesis of 3-(3-aryl-1-phenyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[4,3-a]pyridines via oxidation of 2-((3-aryl-1-phenyl-1H-pyrazol-4-yl)methylene)-1-(pyridin-2-yl)hydrazines and their antimicrobial evaluations. |
| PubMed:One-pot Synthesis, Molecular Modeling and In Vitro Antibacterial Activity of Novel 3-(1,3,4-Oxadiazol-2-yl) Quinoxaline 1,4-Dioxide and Pyrazolyl Analogs. |
| PubMed:Synthesis and antibacterial activities of novel 2,5-diphenylindolo[2,3-e] pyrazolo[1',5':3",4"]pyrimido[2",1"-c] [1,2,4]triazines. |
| PubMed:Direct, metal-free amination of heterocyclic amides/ureas with NH-heterocycles and N-substituted anilines in POCl3. |
| PubMed:One-pot multimolecular macrocyclization for the expedient synthesis of macrocyclic aromatic pentamers by a chain growth mechanism. |
| PubMed:Synthesis and antimicrobial activity of some novel 5-alkyl-6-substituted uracils and related derivatives. |
| PubMed:[Determination of phosphorus oxychloride in the air of workplace by ion chromatography]. |
| PubMed:Synthesis and detection of oxygen-18 labeled phosphate. |
| PubMed:Formation of the Vilsmeier-Haack complex: the performance of different levels of theory. |
| PubMed:Synthesis of new visnagen and khellin furochromone pyrimidine derivatives and their anti-inflammatory and analgesic activity. |
| PubMed:Wettability, surface microstructure and mechanical properties of films based on phosphorus oxychloride-treated zein. |
| PubMed:POCl3 chlorination of 4-quinazolones. |
| PubMed:On the existence of the chair conformation in six-membered ring phosphates bearing an aryl group axially oriented at the C4 position: cyclic nucleotides as model compounds for cyclic phosph(on)ate and phosphoramide prodrugs. |
| PubMed:Facile small scale synthesis of nucleoside 5'-phosphate mixtures. |
| PubMed:Cadmium sorption characteristics of phosphorylated sago starch-extraction residue. |
| PubMed:Diastereoselective synthesis of P-stereogenic heterocycles via enyne ring-closing metathesis. |
| PubMed:Synthesis, crystal structure, and biological activity of 4-methyl-1,2,3-thiadiazole-containing 1,2,4-triazolo[3,4-b][1,3,4]thiadiazoles. |
| PubMed:Synthesis of new 2-naphthyl ethers and their protective activities against DNA damage induced by bleomycin-iron. |
| PubMed:Macroporous poly(vinyl alcohol) microspheres bearing phosphate groups as a new adsorbent for low-density lipoprotein apheresis. |
| PubMed:Identification of benzofuro[2,3-b]quinoline derivatives as a new class of antituberculosis agents. |
| PubMed:Synthesis, characterization and evaluation of 1,2-bis(2,4,6-trinitrophenyl) hydrazine: a key precursor for the synthesis of high performance energetic materials. |
| PubMed:Synthesis and antimicrobial activities of novel quinoline derivatives carrying 1,2,4-triazole moiety. |
| PubMed:Synthesis of uracil nucleotide analogs with a modified, acyclic ribose moiety as P2Y(2) receptor antagonists. |
| PubMed:Synthesis, physicochemical properties and antimicrobial activity of some new benzimidazole derivatives. |
| PubMed:Synthesis and antiviral activities of chiral thiourea derivatives containing an alpha-aminophosphonate moiety. |
| PubMed:Synthesis, antimicrobial and cytotoxic activities of 1,3,4-oxadiazoles, 1,3,4-thiadiazoles and 1,2,4-triazoles. |
| PubMed:Synthesis and structural characterization of the 5-(2-haloethyl)pyrimidines--hydrogen-bonded chains in alpha-(1-carbamyliminomethylene)-gamma-butyrolactone. |
| PubMed:[Synthesis and application of novel dental adhesive materials of 10-methacryloyloxydecyl dihydrogen phosphate]. |
| PubMed:2,6,7-Trioxa-1-phosphabicyclo-[2.2.2]octan-4-ylmethanol 1-sulfide. |
| PubMed:Synthesis, Antimicrobial and Antiinflammatory Activity of 2,5-Disubstituted-1,3,4-oxadiazoles. |
| PubMed:Synthesis of a quaternary polyprenyl ammonium salt. |
| PubMed:One-pot synthesis of benzothiazolines and napthathiazolines via cascade ortho-lithiation, cyclisation and elimination of N-arylsulfonyl lactams. |
| PubMed:Tubular cationized pullulan hydrogels as local reservoirs for plasmid DNA. |
| PubMed:Multistep, microwave assisted, solvent free synthesis and antibacterial activity of 6-substituted-2,3,4-trihydropyrimido[1,2-c]9,10,11,12-tetrahydrobenzo[b]thieno[3,2-e]pyrimidines. |
| PubMed:A microwave-assisted synthesis of julolidine-9-carboxamide derivatives and their conversion to chalcogenoxanthones via directed metalation. |
| PubMed:Cationized pullulan 3D matrices as new materials for gene transfer. |
| PubMed:Synthesis and antimicrobial activities of some novel 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazoles and 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazines carrying thioalkyl and sulphonyl phenoxy moieties. |
| PubMed:Synthesis, antimicrobial, and anti-inflammatory activities of novel 2-(1-adamantyl)-5-substituted-1,3,4-oxadiazoles and 2-(1-adamantylamino)-5-substituted-1,3,4-thiadiazoles. |
| PubMed:PLCgamma2 regulates osteoclastogenesis via its interaction with ITAM proteins and GAB2. |
| PubMed:Synthesis of compounds with antiproliferative activity as analogues of prenylated natural products existing in Brazilian propolis. |
| PubMed:Electrospray ionization mass spectrometry study on dipeptide 4-chlorobutyl ester produced from refluxing of amino acid with phosphoryl chloride in tetrahydrofuran. |
| PubMed:Electrospray ionization-tandem mass spectrometry investigation of polymerization of tetrahydrofuran initiated by phosphorus oxychloride. |
| PubMed:Synthesis of some new 2-(6-methoxy-2-naphthyl)- 5-aryl-1,3,4-oxadiazoles as possible non-steroidal anti-inflammatory and analgesic agents. |
| PubMed:Synthesis of some new biologically active 1,3,4-oxadiazolyl nitroindoles and a modified Fischer indole synthesis of ethyl nitro indole-2-carboxylates. |
| PubMed:One pot conjugation of the polypeptides directed by phosphorus oxychloride. |
| PubMed:Electrospray ionization mass spectrometry: a powerful tool to investigate the oligomerization mechanism of tetrahydrofuran by phosphoryl chloride. |
| PubMed:Synthesis and topoisomerase I inhibitory properties of luotonin A analogues. |
| PubMed:Simple coupling reaction between amino acids and weakly nucleophilic heteroaromatic amines. |
| PubMed:Efficient synthesis of phosphorylated prodrugs with bis(POM)-phosphoryl chloride. |
| PubMed:[Benzo[c][2,7]naphthyridines from 2,6-dinor-nifedipine and its dimethyl 2,5-dicarboxylate isomer]. |
| PubMed:Antitumour polycyclic acridines. Palladium(0) mediated syntheses of quino[4,3,2-kl]acridines bearing peripheral substituents as potential telomere maintenance inhibitors. |
| PubMed:Synthesis and estrogenic activity of bisphenol a mono- and di-beta-D-glucopyranosides, plant metabolites of bisphenol A. |
| PubMed:Differentiation between acetylcholinesterase and the organophosphate-inhibited form using antibodies and the correlation of antibody recognition with reactivation mechanism and rate. |
| PubMed:Control of synaptic strength, a novel function of Akt. |
| PubMed:Major intermediates in organophosphate synthesis (PCl3, POCl3, PSCl3, and their diethyl esters) are anticholinesterase agents directly or on activation. |
| PubMed:Synthesis and anticancer activity of 2-amino-8-chloro-5,5-dioxo[1,2,4]triazolo[2,3-b][1,4,2]benzodithiazine derivatives. |
| PubMed:Parkinsonian mimetics induce aspects of unfolded protein response in death of dopaminergic neurons. |
| PubMed:Synthesis of some novel quinoline-3-carboxylic acids and pyrimidoquinoline derivatives as potential antimicrobial agents. |
| PubMed:A general approach toward the synthesis of C-nucleoside pyrazolo[1,5-a]-1,3,5-triazines and their 3',5'-bisphosphate C-nucleotide analogues as the first reported in vivo stable P2Y(1)-receptor antagonists. |
| PubMed:Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source. |
| PubMed:Elemental composition (C, N, P) and cell volume of exponentially growing and nutrient-limited bacterioplankton. |
| PubMed:Electrospray ionization mass spectrometric studies of phosphorus oxychloride directed synthesis of homo-oligopeptide ester libraries. |
| PubMed:Alkaline phosphatase revisited: hydrolysis of alkyl phosphates. |
| PubMed:Efficient synthesis of phospholipids from glycidyl phosphates. |
| PubMed:[Synthesis of carbonyl chlorides substituted with aromatic dense-ring]. |
| PubMed:Preparation and novel reduction reactions of vinamidinium salts. |
| PubMed:Vilsmeier formylation of praziquantel: synthesis and application for polarographic assay. |
| PubMed:Synthesis and in-vitro anticancer evaluation of bis-tacrine congeners. |
| PubMed:Amino acids and peptides. XXXV. Facile preparation of p-nitroanilide analogs by the solid-phase method. |
| PubMed:[Synthesis and transformations of ethyl 1,4-dihydro-4-oxo(1)benzofuro(3,2-b)pyridine-3-carboxylic acid esters: new antibacterial agents]. |
| PubMed:[Potential antiallergics. 3. Synthesis and transformations of 1,4-dihydro-4-oxo-(1)benzothieno(3,2-b)pyridine-2-carboxylic acid esters]. |
| PubMed:[Gyrase inhibitors. 3. Synthesis and reactions of 1,4-dihydro-4-oxo-(1)benzothieno(3,2-b)pyridin-3-carboxylic acid esters]. |
| PubMed:An efficient preparation of vinamidinium hexafluorophosphate salts. |
| PubMed:Phosphoacetylcholinesterase: toxicity of phosphorus oxychloride to mammals and insects that can be attributed to selective phosphorylation of acetylcholinesterase by phosphorodichloridic acid. |
| PubMed:A convenient synthesis of a novel nucleoside analogue: 4-(alpha-diformyl-methyl)-1-(beta-D-ribofuranosyl)-2-pyrimidinone. |
| PubMed:Electrocyclic ring-opening/pi-allyl cation cyclization reaction sequences involving gem-dihalocyclopropanes as substrates: application to syntheses of (+/-)-, (+)-, and (-)-gamma-lycorane. |
| PubMed:Phosphatase-triggered guest release from a cyclodextrin complex. |
| PubMed:Formation and reactivity of 2,4-ditriazolyl pyrimidine C-nucleoside derived from pseudouridine. |
| PubMed:The Diode-Laser Spectrum of Phosphoryl Chloride (ClPO). |
| PubMed:Water-soluble phosphate prodrugs of 1-propargyl-8-styrylxanthine derivatives, A(2A)-selective adenosine receptor antagonists. |
| PubMed:Synthesis of some new biologically active thiadiazolotriazinones--Part II. |
| PubMed:Synthesis and reaction of cyanopyridone derivatives and their potential biological activities. |
| PubMed:Synthesis of some new biologically active thiadiazolotriazinones. |
| PubMed:A definitive example of aluminum-27 chemical shielding anisotropy |
| PubMed:Bicyclic [b]-heteroannelated pyridazine derivatives. Part 6. Aromatization of some tetrahydrotriazolo[4,3-b]pyridazine derivatives with potential activity as benzodiazepine receptor ligands. |
| PubMed:Synthesis and biological activity studies of 1,3,4-thiadiazolo[2,3-c]-as-triazines. |
| PubMed:Studies on arylfuran derivatives-Part VI. Synthesis, characterization and antibacterial activities of some 6-(5-aryl-2-furyl)-1,2,4-triazolo [3,4-b]-1,3,4-thiadiazoles and 6-(5-nitro-2-furyl)-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazoles. |
| PubMed:Neighboring group catalysis in the design of nucleotide prodrugs. |
| PubMed:N(omega)-phosphoarginine phosphatase (17 kDa) and alkaline phosphatase as protein arginine phosphatases. |
| PubMed:Synthesis of N alpha-protected aminoacyl 7-amino-4-methyl-coumarin amide by phosphorous oxychloride and preparation of specific fluorogenic substrates for papain. |
| PubMed:Amino acid grafting of beta-lactoglobulin mediated by phosphorus oxychloride. |
| PubMed:Phosphorylation of beta-lactoglobulin using amino acids as the sole base and nucleophile of the reaction. |
| PubMed:Acute inhalation toxicology of oxalyl chloride. |
| PubMed:Synthesis and biological evaluation of phosphate triester alkyl lysophospholipids (ALPs) as novel potential anti-neoplastic agents. |
| PubMed:[Synthesis of quinazolino-1,3-benzothiazine derivatives]. |
| PubMed:Synthesis and evaluation of 4-amino-substituted 7-methoxy (and 7-hydroxy)- 11-methyl (and 5,11-dimethyl)-10H-pyrido [2,3-b] carbazoles and 4-amino- substituted 11-methyl (and 5,11-dimethyl)-10H-pyrido[3',4':4,5] pyrrolo [3,2-g] quinolines, two new series related to antitumor ellipticine derivatives. |
| PubMed:Steroids 49. Investigations on the dehydration of 17 alpha-ethynyl-17 beta-hydroxysteroids. |
| PubMed:Rapid synthesis of 2-desoxy-2-amino-3-phosphocholine-glycerinic-acid- alkylester, 1-alkyl-1-desoxy- and 1-O-alkyl-2-desoxy-2-amino-sn-glycero-3- phosphocholines, -3-phospho-N,N'-dimethylethanolamine and -3-phospho-Fmoc- serine-methylester. |
| PubMed:Chemical modification of an antitumor alkaloid, 20(S)-camptothecin: glycosides, phosphates and sulfates of 7-ethyl-10-hydroxycamptothecin. |
| PubMed:[5-Fluoro (3H) pyrimidine-4-ones: synthesis, reactivity and pharmacological properties]. |
| PubMed:Graphical description of health threat defeats parent company opinion. |
| PubMed:In vitro and in vivo activities of monoclonal antibody-alkaline phosphatase conjugates in combination with phenol mustard phosphate. |
| PubMed:[Studies on synthesis and anticonvulsant activity of 3-GABA derivatives of 6-(substituted-phenyl) pyridazines]. |
| PubMed:Synthesis and antitumor activity of 1-[[(dialkylamino)alkyl]amino]-4-methyl-5H-pyrido[4,3-b]benzo[e]- and -benzo[g])indoles. A new class of antineoplastic agents. |
| PubMed:Preparation of triazolo[1,5-c]pyrimidines as potential antiasthma agents. |
| PubMed:[Synthesis and preliminary pharmacological screening of 2,4-disubstituted N,N-dialkyl-1,8-naphthyridine-3-carboxamides]. |
| PubMed:Synthesis of novel 2-chloro-1,4-dihydropyridines by chlorination of 2-hydroxy-1,4-dihydropyridines with phosphorus oxychloride. |
| PubMed:[Synthesis of thieno[2,3-d]pyrimidine derivatives and their antifungal activities]. |
| PubMed:Recent results of carcinogenicity bioassays of fibres and other particulate materials. |
| PubMed:[Derivatives of pyrimidine 1,2-condensate. IV. Synthesis and pharmacological properties of the N,N-disubstituted 4-amino-2H-pyrido(1,2-a)pyrimidin- 2-ones and 2-amino-4H-pyrido(1,2-a)pyrmidin-4-ones]. |
| PubMed:Synthesis of 4-methoxy-2,3,5-trimethylpyridine: a specific building block for compounds with gastric-acid inhibiting activity. |
| PubMed:Synthesis of a tripeptide with a C-terminal nitrile moiety and the inhibition of proteinases. |
| PubMed:Synthesis and antiviral properties of (E)-5-(2-bromovinyl)-2'-deoxycytidine-related compounds. |
| PubMed:[3-Dialkylamino-substituted 2H-1,4-benzoxazines]. |
| PubMed:Phosphorylation of yeast protein: Reduction of ribonucleic acid and isolation of yeast protein concentrate. |
| PubMed:The adsorption of polyaromatic hydrocarbons on natural and chemically modified asbestos fibers. |
| PubMed:Stereospecific analysis of fatty acid esters of chloropropanediol isolated from fresh goat milk. |
| PubMed:Synthesis of 5-chloroformycin A, 5-chloro-2'-deoxyformycin A and certain related 5,7-disubstituted 3-beta-D-ribofuranosylpyrazolo[4,3-d] pyrimidines from formycin A. |
| PubMed:Cyclic platelet-activating factor analogues derived from 2-deoxy-D-erythro-pentose. |
| PubMed:[Chemistry and pharmacology of pyran derivatives. 16. Derivatives of 2-(dialkylamino)-7-methoxychromone with antiallergic activity]. |
| PubMed:Synthesis and biological evaluation of 9-[5'-(2-oxo-1,3,2-oxazaphosphorinan-2-yl)-beta-D-arabinosyl]ade nine and 9-[5'-(2-oxo-1,3,2-dioxaphosphorinan-2-yl)-beta-D-arabinosyl]ade nine: potential neutral precursors of 9-[beta-D-arabinofuranosyl]adenine 5'-monophosphate. |
| PubMed:Synthesis of homoursodeoxycholic acid and [11,12-3H]homoursodeoxycholic acid. |
| PubMed:Inhibition of plaque-forming cells with anti-idiotope or hapten: variation due to hapten density on indicator red cells. |
| PubMed:Synthesis of polar head group homologs of all-trans-cyclopentano-phosphatidylcholine, phosphatidyl-N,N-dimethylethanolamine, and phosphatidylethanolamine. |
| PubMed:Synthesis and characterization of N2-(p-n-butylphenyl)-2'-deoxyguanosine and its 5'-triphosphate and their inhibition of HeLa DNA polymerase alpha. |
| PubMed:Synthesis and properties of N-, O-, and S-phospho derivatives of amino acids, peptides, and proteins. |
| PubMed:N2-1H-benzimidazol-2-yl-N4-phenyl-2,4-pyrimidinediamines and N2-1H-benzimidazol-2-yl-5,6,7,8-tetrahydro-N4-phenyl-2,4-quinazolinediamines as potential antifilarial agents. |
| PubMed:Synthesis and biological evaluation of neutral derivatives of 5-fluoro-2'-deoxyuridine 5'-phosphate. |
| PubMed:Phosphorylation of casein and lysozyme by phosphorus oxychloride. |
| PubMed:Synthesis of [32P]dolichyl phosphate, utilizing a general procedure for [32P]phosphorus oxychloride preparation. |
| PubMed:[Chemical and pharmacological research on pyran derivatives. XV. Phenyl-substituted 2-(dialkylamino)chromones]. |
| PubMed:Chemical phosphorylation of bovine beta-lactoglobulin. |
| PubMed:Synthesis of 5'-thymidinyl bis(1-aziridinyl)phosphinates as antineoplastic agents. |
| PubMed:Synthesis and antimalarial effects of N2-aryl-N4-[(dialkylamino)alkyl]- and N4-aryl-N2-[(dialkylamino)alkyl]-2,4-quinazolinediamines. |
| PubMed:p-Isothiocyanatophenyl 6-phospho-alpha-D-mannopyranoside coupled to albumin. A model compound recognized by the fibroblast lysosomal enzyme uptake system. 1. Chemical synthesis and characterization. |
| PubMed:A simple preparation of N-phosphorylated lysine and arginine. |
| PubMed:[Chemical and pharmacological research on pyran derivatives. XIV. 3-alkylaminoaphtho/2,1-b/pyran-1-ones and derivatives]. |
| PubMed:[Chemical and pharmacological research on pyran derivatives. XIII. Derivatives of 2H-pyrano/3,2-c/quinoline]. |
| PubMed:Chemistry of 8-chloroberberine. |
| PubMed:Synthesis and chemical properties of N- and O-phosphorylated derivatives of creatinol. |
| PubMed:[Chemical and pharmacological research on pyran derivatives. XII. Bis-(beta-chloroethyl)amino-substituted chromones and benzochromones]. |
| PubMed:[Chemical and pharmaceutical research on pyran derivatives. XI. Synthesis of 2-dialkylamino-4-oxo-10-methyl-4H-naphtho[2,3b]pyrans]. |
| PubMed:[Chemical and pharmaceutical research on pyran derivatives. X. Synthesis of 1-oxo-2-alkyl-3-dialkylamino-1H-naphtho[2,1b]pyrans]. |
| PubMed:Synthesis of some 2-styrylquinazoline derivatives structurally related to certain chemotherapeutic agents. |
| PubMed:Poisoning caused by inhalation of hydrogen chloride, phosphorus oxychloride, phosphorus pentachloride, oxalyl chloride, and oxalic acid. |
| PubMed:Synthesis and biological activity of N6-(n-alkylureido)purine ribonucleosides and their 5'-phosphates. |
| PubMed:Synthesis and metabolism of 5beta-[11,12-3H]cholestane-3alpha, 7alpha-diol. |
| PubMed:Quantitative ion-exchange separation of submicrogram amounts of iron from phosphate medium. |
| PubMed:The cyclodesulphurization of thio-compounds. Part 15: Synthesis of 6-substituted aminophenanthridines from some thiourea derivatives. |
| PubMed:[Chemical and pharmacologic study on pyran derivatives. IX. Synthesis of 2-dialkylaminochromones]. |
| PubMed:[Study of 1,5-benzodiazepines. II. Synthesis of 2,4-di-(N-alkyl,N-phenyl)amino-3H-1,5-benzodiazepine]. |
| PubMed:[Chemical and pharmacological research on pyran derivatives. VIII. Synthesis of 2-dialkylamino-7-methoxychromones and derivatives]. |
| PubMed:[Studies on 1,5-benzodiazepine. I. Derivatives of 4-amino-1,5-benzodiazepine]. |
| PubMed:[Chemical and pharmacological research on pyran derivatives. VII. Derivatives of naphto/1',2':5,6/pyran/2,3-c/pyrazole and of 12H-naphto/1',2':5,6/pyran/2,3-d/pyrimidine]. |
| PubMed:Chloro compounds of phosphorus as industrial hazards. |
| PubMed:Polynucleotides. XLII1. Limited addition of 2'O-onitrobenzyl nucleotides to the 3'-end of ribooligonucleotide with polynucleotide phosphorylase. |
| PubMed:Phosphorus-containing heterocycles as fungicides: synthesis of 2,2'-diphenylene chlorophosphonate and 2,2'-diphenylene chlorothiophosphonate. |
| PubMed:The cyclodesulphurization of thio-compounds. Part 12: A new simple method for the synthesis of N-alpha-substituted benzimidazoles from thiourea derivatives. |
| PubMed:[Chemical and pharmacological research on derivatives of 1H-naphto/2,1-b/pyran. IV. Substituted 1-oxo-3-dialkylamino-1H-naphto/2,1-b/pyrans]. |
| PubMed:Synthesis of tritium- and deuterium-labeled 9-beta-D-arabinofuranosyladenine and the tritium-labeled 5'-monophosphate ester with increased metabolic stability. |
| PubMed:Use of phosphorus oxychloride in synthesizing nucleotides and oligonucleotides. |
| PubMed:Aliphatic analogues of nucleotides: synthesis and affinity towards nucleases. |
| PubMed:Preparation and progestational activity of 6-cyano-16-methylene-17 -hydroxy-4,6-pregnadiene-3,20-dione 17-acetate and related compounds. |
| PubMed:[Reaction of 1-substituted 2-piperidones with phosphoryl chloride. IV. Interconversion of the beta-keto-amide and the quaternary salt]. |
| PubMed:[Reaction of 1-substituted 2-piperidones with phosphoryl chloride. 3. Structures of reaction products. 3. Reduction of quaternary salts]. |
| PubMed:[Reaction of 1-substituted 2-piperidones with phosphoryl chloride. II. Structures of reaction products. 2. Quaternary salts]. |
| PubMed:[Reaction of 1-substituted 2-piperidones with phosphoryl chloride. I. Structures of reaction products. 1. Beta-keto-amides]. |
| PubMed:The total synthesis of phosphatidyl(Dioleoyl)hydroxy-l-proline and its activity in blood-clotting systems. |
| PubMed:Studies of phosphorylation. II. Reaction of 2',3'-O-isopropylideneinosine and -guanosine with phosphoryl chloride. |
| PubMed:Studies of phosphorylation. I. Phosphorylation of 2',3'-o-isopropylidene nucleoside by phosphoryl chloride. |
| PubMed:An improved synthesis of isopentenyl pyrophosphate. |
| PubMed:[Synthesis of nucleotides. 3. Selective phosphorylation of ribonucleoside with phosphorus oxychloride]. |
| PubMed:[Clinical contribution to the knowledge of acute poisoning by phosphorus oxychloride]. |
| PubMed:Chromatographic studies of phosphorus compounds. XI. The reaction of sodium hydroxide with phosphoryl chloride. |
| PubMed:THE FORMYLATION OF STEROIDAL KETONES WITH PHOSPHORUS OXYCHLORIDE AND DIMETHYLFORMAMIDE. |
| PubMed:ACUTE VAPOR TOXICITY OF PHOSPHORUS OXYCHLORIDE, PHOSPHORUS TRICHLORIDE AND METHYL PHOSPHONIC DICHLORIDE. |
| PubMed:Analysis of reaction of phosphoryl chloride with tissue components. |
| PubMed:[Phosphoryl chloride as esterification catalyst]. |
| PubMed:[Condensation products between dicyandiamide and alkyl fatty acids in presence of phosphorus oxychloride]. |
| PubMed:[Demonstration of some ketones with phosphorus oxychloride]. |
| PubMed:[Preparation of ketones of antipyrine series with the aid of phosphorus oxychloride]. |
| PubMed:[Simple method for the preparation of ketones of 4-hydroxycoumarin with the aid of phosphorus oxychloride]. |
| PubMed:[The content of hydrated phosphorus oxychloride and polyphosphoric esters and amides of thiamine in polyphosphoric compounds]. |
| PubMed:[Occupational poisoning from phosphorus oxychloride]. |
| PubMed:[Use of aerosol therapy in certain acute poisoning with gases; acute poisoning with cadmium monoxide and with phosphorus oxychloride]. |
| PubMed:[On the acetylation of certain aromatic amines in the presence of phosphorus oxychloride]. |
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Etherification and esterification agent for modification of food starch
Like phosphate, phosphoryl chloride is tetrahedral in shape. It features three P-Cl bonds and one very strong P=O double bond, with an estimated bond dissociation energy of 533.5 kJ/mol. On the basis of bond length and electronegativity, the Schomaker-Stevenson rule suggests that the double bond form is very dominant (in contrast with POF3). The P=O bond does not resemble the ? bond in a carbonyl group as in a ketone. The appropriate description of the P-O interaction is a matter of long discussion. Older textbooks favor a description that invokes participation of the d-orbitals on phosphorus. Some of these d-orbitals project toward the O atom, overlapping with p-orbitals on oxygen. More modern texts seem to favor a description where the P-O ? bonding involves the ?* components of the P-Cl bonds. These descriptions do not consider a role for d-orbitals.; Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. It hydrolyses in moist air to phosphoric acid to release choking fumes of hydrogen chloride. It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide. It is mainly used to make phosphate esters such as tricresyl phosphate.
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3D/inchi