methyl acrylate, 96-33-3

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CODE125955 CODE125955
Product(s):
13-26775 METHYL ACRYLATE

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CODE125955 CODE125955
Product(s):
A0145 Methyl Acrylate (stabilized with MEHQ) >99.0%(GC)
SDS

CAS Number:	96-33-3	3D/inchi
ECHA EINECS - REACH Pre-Reg:	202-500-6
FDA UNII:	WC487PR91H
Nikkaji Web:	J3.967E
Beilstein Number:	0605396
MDL:	MFCD00008627
CoE Number:	10759
XlogP3:	0.80 (est)
Molecular Weight:	86.09022000
Formula:	C4 H6 O2
BioActivity Summary:	listing
NMR Predictor:	Predict (works with chrome, Edge or firefox)

Category:food contact substances for use only as components of articles intended for repeated use

US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:

Google Scholar:	Search
Google Books:	Search
Google Scholar: with word "volatile"	Search
Google Scholar: with word "flavor"	Search
Google Scholar: with word "odor"	Search
Google Patents:	Search
US Patents:	Search
EU Patents:	Search
Pubchem Patents:	Search
PubMed:	Search
NCBI:	Search
	FDA/DG SANTE Petitions, Reviews, Notices:
1977	Monomeric methyl acrylate (packaging) View - review
181.30	Polymeric methyl acrylate (packaging) View - review
DG SANTE Food Contact Materials:	acrylic acid, methyl ester
FDA Mainterm (SATF):	96-33-3 ; METHYL ACRYLATE
FDA Regulation:
FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart B--Substances for Use Only as Components of Adhesives Sec. 175.105 Adhesives. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.300 Resinous and polymeric coatings. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.320 Resinous and polymeric coatings for polyolefin films. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.360 Vinylidene chloride copolymer coatings for nylon film. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.365 Vinylidene chloride copolymer coatings for polycarbonate film. FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Subpart B--Substances for Use Only as Components of Paper and Paperboard Sec. 176.170 Components of paper and paperboard in contact with aqueous and fatty foods. FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Subpart B--Substances for Use Only as Components of Paper and Paperboard Sec. 176.180 Components of paper and paperboard in contact with dry food. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1010 Acrylic and modified acrylic plastics, semirigid and rigid. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1200 Cellophane. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Surfaces Sec. 177.1340 Ethylene-methyl acrylate copolymer resins. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Surfaces Sec. 177.1480 Nitrile rubber modified acrylonitrile-methyl acrylate copolymers. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1630 Polyethylene phthalate polymers. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1650 Polysulfide polymer-polyepoxy resins. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Surfaces Sec. 177.1990 Vinylidene chloride/methyl acrylate copolymers. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Surfaces Sec. 177.2000 Vinylidene chloride/methyl acrylate/methyl methacrylate polymers. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart C--Substances for Use Only as Components of Articles Intended for Repeated Use Sec. 177.2420 Polyester resins, cross-linked.

Physical Properties:

Assay:	98.00 to 100.00
Food Chemicals Codex Listed:	No
Specific Gravity:	0.95600 to 0.95800 @ 20.00 °C.
Pounds per Gallon - (est).:	7.964 to 7.981
Refractive Index:	1.40100 to 1.40400 @ 20.00 °C.
Boiling Point:	80.00 to 81.00 °C. @ 760.00 mm Hg
Vapor Pressure:	86.280998 mmHg @ 25.00 °C. (est)
Flash Point:	44.00 °F. TCC ( 6.67 °C. )
logP (o/w):	0.800
Soluble in:
	water, 49400 mg/L @ 25 °C (exp)

Organoleptic Properties:

Odor and/or flavor descriptions from others (if found).

Cosmetic Information:

None found

Suppliers:

Arkema

Methylacrylate

Odor: characteristic

Use: It can be polymerized with each other and copolymerized with other monomers to produce polymers having the optimal properties for your application.

Shiva Chemicals and Pharmaceuticals

Methyl Acrylate

Sigma-Aldrich: Aldrich

For experimental / research use only.

Methyl acrylate 99%, contains =100 ppm monomethyl ether hydroquinone as inhibitor

sds

Silver Fern Chemical

Methyl Acrylate (MA)

Odor: characteristic

Use: MA is commonly used to make acrylic polymers, amphoteric surfactants, vitamin B1, and as a chemical intermediate.

TCI AMERICA

For experimental / research use only.

Methyl Acrylate (stabilized with MEHQ) >99.0%(GC)

sds

Safety Information:

Preferred SDS: View

Hazards identification

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements

Pictogram

Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 277 mg/kg Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975. intraperitoneal-mouse LD50 254 mg/kg Journal of Dental Research. Vol. 51, Pg. 526, 1972. oral-mouse LD50 827 mg/kg Toxicology Letters. Vol. 11, Pg. 125, 1982. oral-rabbit LDLo 280 mg/kg LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: TREMOR Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 317, 1949. intraperitoneal-rat LD50 325 mg/kg Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975.
Dermal Toxicity:
skin-rabbit LD50 1243 mg/kg Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 63, 1948.
Inhalation Toxicity:
inhalation-rat LC50 1350 ppm/4H SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA Journal of Toxicology and Environmental Health. Vol. 16, Pg. 811, 1985. inhalation-human TCLo 75 ppm SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 75, 1969. inhalation-mouse LC50 12800 mg/m3 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(9), Pg. 55, 1979. inhalation-rabbit LCLo 2522 ppm/1H BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 317, 1949.

Safety in Use Information:

Category:
food contact substances for use only as components of articles intended for repeated use
Recommendation for methyl acrylate usage levels up to:
	not for fragrance use.

Recommendation for methyl acrylate flavor usage levels up to:
	not for flavor use.

Safety References:

EPI System: View

EPA-Iris:IRIS

NIOSH International Chemical Safety Cards:search

NIOSH Pocket Guide:search

Chemical Carcinogenesis Research Information System:Search

AIDS Citations:Search

Cancer Citations:Search

Toxicology Citations:Search

EPA GENetic TOXicology:Search

EPA Substance Registry Services (TSCA):96-33-3

EPA ACToR:Toxicology Data

EPA Substance Registry Services (SRS):Registry

Laboratory Chemical Safety Summary :7294

National Institute of Allergy and Infectious Diseases:Data

WGK Germany:2

methyl prop-2-enoate

Chemidplus:0000096333

EPA/NOAA CAMEO:hazardous materials

RTECS:96-33-3

References:

	methyl prop-2-enoate
NIST Chemistry WebBook:	Search Inchi
Canada Domestic Sub. List:	96-33-3
Pubchem (cid):	7294
Pubchem (sid):	134972380

Other Information:

(IUPAC):	Atomic Weights of the Elements 2011 (pdf)
Videos:	The Periodic Table of Videos
tgsc:	Atomic Weights use for this web site
(IUPAC):	Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):	View
FDA Indirect Additives used in Food Contact Substances:	View
CHEBI:	View
CHEMBL:	View
KEGG (GenomeNet):	C19443
HMDB (The Human Metabolome Database):	HMDB33977
FooDB:	FDB012209
Export Tariff Code:	2916.12.5020
ChemSpider:	View
Wikipedia:	View
Formulations/Preparations: •grades: technical (inhibited) •methyl acrylate available commercially in us has the following typical properties: purity, 98.9%; acidity (as acrylic acid), 0.0008%; water, 0.06%; inhibitor (hydroquinine monomethyl ether), 15, 200 or 1000 mgkg (ppm) ... •grades or purity: 99.9% •stabilized against polymerization with hydroquinone monomethyl ether or a similar inhibitor

Potential Blenders and core components note

None Found

Potential Uses:

None Found

Occurrence (nature, food, other):note

not found in nature

Synonyms:

	acrylic acid methyl ester
	acrylic acid, methyl ester
	methoxycarbonyl ethylene
	methoxycarbonylethylene
	methyl 2-propenoate
	methyl ester of acrylic acid
	methyl prop-2-enoate
	methyl propenate
	methyl propenoate
	methyl-2-propenoate
	methylacrylate
2-	propenoic acid methyl ester
2-	propenoic acid, methyl ester

Articles:

PubMed:Synthesis and insecticidal evaluation of novel N-pyridylpyrazolecarboxamides containing an amino acid methyl ester and their analogues.

PubMed:Graft polymerization of native chicken feathers for thermoplastic applications.

PubMed:Novel molecularly imprinted polymer using 1-(α-methyl acrylate)-3-methylimidazolium bromide as functional monomer for simultaneous extraction and determination of water-soluble acid dyes in wastewater and soft drink by solid phase extraction and high performance liquid chromatography.

PubMed:Chronic toxicity and oncogenicity of inhaled methyl acrylate and n-butyl acrylate in Sprague-Dawley rats.

PubMed:Acrylic acid, methyl acrylate, ethyl acrylate and polyacrylic acid.

Notes:

Methyl acrylate is a contact allergen present in nail lacquer.; Methyl acrylate is a volatile alpha beta unsubstituted methyl ester used in the preparation of polyamidoamine (PAMAM) dendrimers typically by Michael addition with a primary amine.

methyl acrylate 2-propenoic acid, methyl ester

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Articles:

methyl acrylate
2-propenoic acid, methyl ester