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ammonium formate
formic acid, ammonium salt (1:1)

Supplier Sponsors

Name:azane; formic acid
CAS Number: 540-69-2Picture of molecule3D/inchi
Other(deleted CASRN):2787-68-0
ECHA EINECS - REACH Pre-Reg:208-753-9
FDA UNII: 3801F9644E
Beilstein Number:3625095
MDL:MFCD00013103
Molecular Weight:63.05625000
Formula:C H5 N O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 116.00 °C. @ 760.00 mm Hg
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
Soluble in:
 water, 1e+006 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Ammonium formate ≥98% (Titration)
Charkit Chemical
AMMONIUM FORMATE
ECSA Chemicals
AMMONIUM FORMATE RPE-FOR ANALYSIS, G 250
ECSA TRADE THE MOST UPDATED FINANCIAL PUBLICATION ON THE WORLD OF CHEMISTRY
Glentham Life Sciences
Ammonium formate, 98%
Sigma-Aldrich: Aldrich
For experimental / research use only.
Ammonium Formate ≥99.995% trace metals basis
sds
Viachem
Ammonium Formate
Odor: bland
Use: Ammonium formate, NH4HCO2, is the ammonium salt of formic acid. It is a colorless, hygroscopic, crystalline solid. Pure ammonium formate decomposes into formamide and water when heated, and this is its primary use in industry. Formic acid can also be obtained by reacting ammonium formate with a dilute acid, and since ammonium formate is also produced from formic acid, it can serve as a way of storing formic acid.
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-mouse LD50 2250 mg/kg
Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969.

intravenous-mouse LD50 410 mg/kg
Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
information only not used for fragrances or flavors
Recommendation for ammonium formate usage levels up to:
 not for fragrance use.
 
Recommendation for ammonium formate flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Scientific Opinion on the safety and efficacy of ammonium formate, calcium formate and sodium formate when used as a technological additive for all animal species
View page or View pdf

Scientific Opinion on the safety and efficacy of formic acid, ammonium formate and sodium formate as feed hygiene agents for all animal species
View page or View pdf

Safety of ammonium formate (E 295) for all animal species
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):540-69-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :10904
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
azane; formic acid
Chemidplus:0000540692
EPA/NOAA CAMEO:hazardous materials
RTECS:BQ6650000 for cas# 540-69-2
 
References:
 azane; formic acid
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:540-69-2
Pubchem (cid):10904
Pubchem (sid):134975739
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2915.12.0000
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 ammoniumformate
 azane; formic acid
 formic acid amine
 formic acid ammonium salt
 formic acid ammonium salt (1:1)
 formic acid, ammonium salt
 formic acid, ammonium salt (1:1)
 formic acid, ammonium salt (4:1)
 

Articles:

PubMed:Use of ammonium formate in QuEChERS for high-throughput analysis of pesticides in food by fast, low-pressure gas chromatography and liquid chromatography tandem mass spectrometry.
PubMed:Development and validation of a generic method for quantification of collagen in food supplement tablets using liquid chromatography coupled with time-of-flight mass spectrometry.
PubMed:A LC-MS/MS method for the determination of BADGE-related and BFDGE-related compounds in canned fish food samples based on the formation of [M+NH(4)](+) aducts.
PubMed:Determination of phosphatidylethanolamine molecular species in various food matrices by liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS2).
PubMed:Simultaneous determination of praziquantel, pyrantel embonate, febantel and its active metabolites, oxfendazole and fenbendazole, in dog plasma by liquid chromatography/mass spectrometry.
PubMed:Enrichment and quantification of monoacylglycerols and free fatty acids by solid phase extraction and liquid chromatography-mass spectrometry.
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PubMed:A simple extraction method for the simultaneous detection of tetramisole and diethylcarbamazine in milk, eggs, and porcine muscle using gradient liquid chromatography-tandem mass spectrometry.
PubMed:[Simultaneous determination of six synthetic sweeteners in food by high performance liquid chromatography-tandem mass spectrometry].
PubMed:Capillary liquid chromatography with diode array and mass spectrometry detection for heterocyclic aromatic amine determination in ready-to-eat food treated with electron-beam irradiation.
PubMed:Analysis of UV ink photoinitiators in packaged food by fast liquid chromatography at sub-ambient temperature coupled to tandem mass spectrometry.
PubMed:A rapid and underivatized method for the determination of glutamine in human serum with ultra performance liquid chromatography-tandem mass spectrometry and its application.
PubMed:Simple and sensitive analysis of histamine and tyramine in Japanese soy sauces and their intermediates using the stable isotope dilution HILIC-MS/MS method.
PubMed:Development and validation of a sensitive LC-MS/MS assay for the quantification of nizatidine in human plasma and urine and its application to pharmacokinetic study.
PubMed:A Simple LC/MS/MS Method for the Determination of Moxifloxacin N-Sulfate in Rat Plasma and Its Application in a Pharmacokinetic Study.
PubMed:Novel dispersive micro-solid-phase extraction combined with ultrahigh-performance liquid chromatography-high-resolution mass spectrometry to determine morpholine residues in citrus and apples.
PubMed:[High-sensitivity analysis of purines in alcoholic beverages using hydrophilic interaction chromatography coupled with tandem mass spectrometry].
PubMed:Development, optimization and validation of a multimethod for the determination of 36 mycotoxins in wines by liquid chromatography-tandem mass spectrometry.
PubMed:A rapid LC-MS/MS method for quantification of CSUOH0901, a novel antitumor agent, in rat plasma.
PubMed:Development and validation of a bioanalytical method by LC-MS/MS for the quantification of the LAFIS 10 - an antimalarial candidate - and its pharmacokinetics first evaluation.
PubMed:Beta-D-glucosyl and alpha-D-galactosyl Yariv reagents: syntheses from p-nitrophenyl-D-glycosides by transfer reduction using ammonium formate.
PubMed:Forced degradation and impurity profiling: recent trends in analytical perspectives.
PubMed:A novel dispersive micro solid phase extraction using PCX as the sorbent for the determination of melamine and cyromazine in milk and milk powder by UHPLC-HRMS/MS.
PubMed:Sensitive LC-MS/MS-ESI method for simultaneous determination of montelukast and fexofenadine in human plasma: application to a bioequivalence study.
PubMed:[Simultaneous determination of 23 sedative drugs in health foods by high performance liquid chromatography-tandem mass spectrometry].
PubMed:Determination of plant growth regulators in pears by microwave-assisted extraction and liquid chromatography with electrospray ionization mass spectrometry.
PubMed:Development and validation of an HPLC method to determine metabolites of 5-hydroxymethylfurfural (5-HMF).
PubMed:Determination of Triazine Herbicides in Drinking Water by Dispersive Micro Solid Phase Extraction with Ultrahigh-Performance Liquid Chromatography-High-Resolution Mass Spectrometric Detection.
PubMed:[Determination of N-methyl carbamate pesticides in diet samples by high performance liquid chromatography-linear ion trap mass spectrometry with gel permeation chromatography cleanup].
PubMed:Quantitative mass spectrometry independence from matrix effects and detector saturation achieved by flow injection analysis with real-time infinite dilution.
PubMed:Comparison of different extraction methods for simultaneous determination of B complex vitamins in nutritional yeast using LC/MS-TOF and stable isotope dilution assay.
PubMed:Development and validation of a sensitive and high-throughput LC-MS/MS method for the simultaneous determination of esomeprazole and naproxen in human plasma.
PubMed:Development of a sensitive and rapid method for rifampicin impurity analysis using supercritical fluid chromatography.
PubMed:Determination of purine contents in different parts of pork and beef by high performance liquid chromatography.
PubMed:Development and validation of a LC-MS/MS method to determine sulforaphane in honey.
PubMed:Rapid method for the determination of metamizole residues in bovine muscle by LC-MS/MS.
PubMed:Quantitation of sunitinib, an oral multitarget tyrosine kinase inhibitor, and its metabolite in urine samples by nonaqueous capillary electrophoresis time of flight mass spectrometry.
PubMed:Imatinib assay by high-performance liquid chromatography in tandem mass spectrometry with solid-phase extraction in human plasma.
PubMed:Buprenorphine and norbuprenorphine quantification in human plasma by simple protein precipitation and ultra-high performance liquid chromatography tandem mass spectrometry.
PubMed:Determination of Levocetirizine in Human Plasma by LC-MS-MS: Validation and Application in a Pharmacokinetic Study.
PubMed:Development of LC-MS/MS methodology for the detection/determination and confirmation of chloramphenicol, chloramphenicol 3-O-β-d-glucuronide, florfenicol, florfenicol amine and thiamphenicol residues in bovine, equine and porcine liver.
PubMed:Mass spectral studies towards more reliable measurement of perfluorooctanesulfonic acid and other perfluorinated chemicals (PFCs) in food matrices using liquid chromatography/tandem mass spectrometry.
PubMed:Analysis of metronidazole in equine plasma using liquid chromatography/tandem mass spectrometry and high-resolution accurate mass spectrometry.
PubMed:Determination of zolpidem in human plasma by liquid chromatography-tandem mass spectrometry for clinical application.
PubMed:Determination of metabolites of 5-hydroxymethylfurfural in human urine after oral application.
PubMed:[Determination of acetyl coenzyme A in grape berries by high performance liquid chromatography-tandem mass spectrometry].
PubMed:Simultaneous screening and determination of 18 illegal adulterants in herbal medicines and health foods for male sexual potency by ultra-fast liquid chromatography-electrospray ionization tandem mass spectrometry.
PubMed:Analysis of chlormequat and mepiquat by hydrophilic interaction chromatography coupled to tandem mass spectrometry in food samples.
PubMed:A novel cation exchange polymer as a reversed-dispersive solid phase extraction sorbent for the rapid determination of rhodamine B residue in chili powder and chili oil.
PubMed:Rapid determination of disulfoton and its oxidative metabolites in human whole blood and urine using QuEChERS extraction and liquid chromatography-tandem mass spectrometry.
PubMed:[UPLC-MS/MS method for the determination of icaritin in rat plasma].
PubMed:Determination of aflatoxins in food samples by automated on-line in-tube solid-phase microextraction coupled with liquid chromatography-mass spectrometry.
PubMed:The challenges of developing a generic extraction procedure to analyze multi-class veterinary drug residues in milk and honey using ultra-high pressure liquid chromatography quadrupole time-of-flight mass spectrometry.
PubMed:[Determination of 14 heterocyclic aromatic amines in wine by liquid chromatography-ion trap-time of flight tandem mass spectrometry].
PubMed:Simultaneous determination of a p38 MAP kinase inhibitor and its amide hydrolyzed metabolite in Cynomolgus monkey plasma by LC-MS/MS, and its application to a toxicokinetic study.
PubMed:Occurrence of acidic pharmaceuticals and personal care products in Turia River Basin: from waste to drinking water.
PubMed:[Simultaneous identification and detection of 16 anabolic steroid hormones in muscle using liquid chromatography oupled to quadrupole/linear ion trap mass spectrometry].
PubMed:Development of a liquid chromatography tandem mass spectrometry method for simultaneous determination of eight adulterants in slimming functional foods.
PubMed:Liquid chromatography-tandem mass spectrometry method for the determination of anthelmintics in alfalfa plants.
PubMed:Analysis of abietic acid and dehydroabietic acid in food samples by in-tube solid-phase microextraction coupled with liquid chromatography-mass spectrometry.
PubMed:Planar chromatography mediated screening of tetracycline and fluoroquinolone antibiotics in milk by fluorescence and mass selective detection.
PubMed:[Fingerprint analysis of Fritillaria thunbergii using rapid resolution liquid chromatography coupled with electrospray ionization quadrupole time-of-flight tandem mass spectrometry].
PubMed:Simultaneous determination of 38 phosphodiestrase-5 inhibitors in illicit erectile dysfunction products by liquid chromatography-electrospray ionization-tandem mass spectrometry.
PubMed:Quantification of nicotine, cotinine, trans-3'-hydroxycotinine and varenicline in human plasma by a sensitive and specific UPLC-tandem mass-spectrometry procedure for a clinical study on smoking cessation.
PubMed:Liquid chromatography/tandem mass spectrometry (highly selective selected reaction monitoring) for the analysis of isopropylthioxanthone in packaged food.
PubMed:Simultaneous quantification of eight biogenic amine compounds in tuna by matrix solid-phase dispersion followed by HPLC-orbitrap mass spectrometry.
PubMed:Direct determination of pregabalin in human urine by nonaqueous CE-TOF-MS.
PubMed:Fast and sensitive high performance liquid chromatography analysis of cosmetic creams for hydroquinone, phenol and six preservatives.
PubMed:Sample stacking microemulsion electrokinetic capillary chromatography induced by reverse migrating pseudostationary phase for the quantification of phenobarbital and its p-hydroxyphenobarbital metabolite in rat urine.
PubMed:Rapid determination of chloramphenicol and its glucuronide in food products by liquid chromatography-electrospray negative ionization tandem mass spectrometry.
PubMed:Development and validation of a liquid chromatography method with electrospray ionization tandem mass spectrometry for the determination of brotizolam residues in beef and commercial whole milk.
PubMed:[Analytical method of cereulide in processed cereal-based foods and milk powder by LC-MS/MS].
PubMed:Application of ion-exchange cartridge clean-up in food analysis. V. Simultaneous determination of sulphonamide antibacterials in animal liver and kidney using high-performance liquid chromatography with ultraviolet and mass spectrometric detection.
PubMed:Rapid determination of fumagillin residues in honey by liquid chromatography-tandem mass spectrometry using the QuEChERS method.
PubMed:Optimization of a solid phase extraction and hydrophilic interaction liquid chromatography-tandem mass spectrometry method for the determination of metformin in dietary supplements and herbal medicines.
PubMed:Analysis of amprolium by hydrophilic interaction liquid chromatography-tandem mass spectrometry.
PubMed:Analysis of 18 perfluorinated compounds in river waters: comparison of high performance liquid chromatography-tandem mass spectrometry, ultra-high-performance liquid chromatography-tandem mass spectrometry and capillary liquid chromatography-mass spectrometry.
PubMed:Ultrasensitive determination of jasmonic acid in plant tissues using high-performance liquid chromatography with fluorescence detection.
PubMed:Validation of an analytical method for the quantification of pyrethrins on lemons and apricots using high-performance liquid chromatography/mass spectrometry.
PubMed:Development and validation of a liquid chromatography/mass spectrometry method for pharmacokinetic studies of OZ78, a fasciocidal drug candidate.
PubMed:Development and application of an HILIC-MS/MS method for the quantitation of nucleotides in infant formula.
PubMed:Liquid chromatography-tandem mass spectrometry for the determination of sphingomyelin species from calf brain, ox liver, egg yolk, and krill oil.
PubMed:[LC/ESI-MS/MS method for the simultaneous determination of macrocyclic lactone parasiticides in livestock products and fish].
PubMed:Simultaneous determination of six non-polar heterocyclic amines in meat samples by supercritical fluid extraction-capillary electrophoresis under fluorimetric detection.
PubMed:Detection of adulteration of anti-hypertension dietary supplements and traditional Chinese medicines with synthetic drugs using LC/MS.
PubMed:Characteristics and origins of common chemical noise ions in negative ESI LC-MS.
PubMed:Optimization and validation of a SPE-HPLC-PDA-fluorescence method for the simultaneous determination of drugs used in combined cardiovascular therapy in human plasma.
PubMed:Multiresidue analysis of pesticides with hydrolyzable functionality in cooked vegetables by liquid chromatography tandem mass spectrometry.
PubMed:Validation of an ion-pair liquid chromatography-electrospray-tandem mass spectrometry method for the determination of heterocyclic aromatic amines in meat-based infant foods.
PubMed:Acrylamide in foods: occurrence, sources, and modeling.
PubMed:[Determination of five synthetic sweeteners in wines using high performance liquid chromatography-tandem mass spectrometry].
PubMed:Multiresidue analysis of 47 pesticides in cooked wheat flour and polished rice by liquid chromatography with tandem mass spectrometry.
PubMed:Semicarbazide formation in azodicarbonamide-treated flour: a model study.
PubMed:Liquid chromatographic determination of paralytic shellfish poisons in shellfish after prechromatographic oxidation.
PubMed:Field amplified sample injection-capillary electrophoresis-tandem mass spectrometry for the analysis of acrylamide in foodstuffs.
PubMed:Effect of Lactobacillus buchneri, Lactobacillus fermentum, Leuconostoc mesenteroides inoculants, or a chemical additive on the fermentation, aerobic stability, and nutritive value of crimped wheat grains.
PubMed:Supercritical fluid extraction (SFE) of 4(5)-methylimidazole (4-MeI) and 2-acetyl-4(5)-(1,2,3,4)-tetrahydroxybutyl-imidazole (THI) from ground-coffee with high-performance liquid chromatographic-electrospray mass spectrometric quantification (HPLC/ESI-MS).
PubMed:Liquid chromatography analysis of erythromycin A in salmon tissue by electrochemical detection with confirmation by electrospray ionization mass spectrometry.
PubMed:A sensitive confirmatory method for aflatoxins in maize based on liquid chromatography/electrospray ionization tandem mass spectrometry.
PubMed:Quantitative analysis of delta9-tetrahydrocannabinol in preserved oral fluid by liquid chromatography-tandem mass spectrometry.
PubMed:Determination of residues of the plant growth regulator chlormequat in pears by ion-exchange high performance liquid chromatography-electrospray mass spectrometry.
PubMed:[Analytical method for carbamate pesticides in processed foods by LC/MS/MS].
PubMed:A new hydrophilic interaction liquid chromatography tandem mass spectrometry method for the simultaneous determination of seven biogenic amines in cheese.
PubMed:Off-line solid-phase microextraction and capillary electrophoresis mass spectrometry to determine acidic pesticides in fruits.
PubMed:High-performance liquid chromatographic analysis of the antituberculosis drugs aconiazide and isoniazid.
PubMed:Analysis of six synthetic adulterants in herbal weight-reducing dietary supplements by LC electrospray ionization-MS.
PubMed:Determination of peptide hormones of brain and intestine by CE with ESI-MS detection.
PubMed:A new method for screening and determination of diuretics by on-line CE-ESI-MS.
PubMed:Positive and negative electrospray LC-MS-MS methods for quantitation of the antiparasitic endectocide drugs, abamectin, doramectin, emamectin, eprinomectin, ivermectin, moxidectin and selamectin in milk.
PubMed:A rapid separation method for inositol phosphates and their isomers.
PubMed:Determination of chloramphenicol residues in bee pollen by liquid chromatography/tandem mass spectrometry.
PubMed:[A rapid capillary zone electrophoresis method for simultaneous determination of several kinds of doping agents].
PubMed:Simultaneous determination of residues of dipyrone and its major metabolites in milk, bovine muscle, and porcine muscle by liquid chromatography/mass spectrometry.
PubMed:Determination of phenolic compounds in dietary supplements and tea blends containing Echinacea by liquid chromatography with coulometric electrochemical detection.
PubMed:High-performance liquid chromatographic separation and on-line mass spectrometric detection of saturated and unsaturated oligogalacturonic acids.
 
Notes:
None found
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