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dithianon
naphtho(2,3-b)-1,4-dithiin-2,3-dicarbonitrile, 5,10-dihydro-5,10-dioxo-

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CAS Number: 3347-22-6Picture of molecule3D/inchi
Other(deleted CASRN):11096-35-8
ECHA EINECS - REACH Pre-Reg:222-098-6
FDA UNII: 3ESS44NI1F
Nikkaji Web:J4.516K
Beilstein Number:1325563
MDL:MFCD00055492
XlogP3-AA:2.80 (est)
Molecular Weight:296.32828000
Formula:C14 H4 N2 O2 S2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 225.00 °C. @ 760.00 mm Hg
logP (o/w): 2.840
Soluble in:
 water, 0.14 mg/L @ 20 °C (exp)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
dithianon 95%
Santa Cruz Biotechnology
For experimental / research use only.
Dithianon
Sigma-Aldrich
For experimental / research use only.
Dithianon PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-guinea pig LD50 110 mg/kg
"Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 5, Pg. 86, 1976.

oral-mouse LD50 1110 mg/kg
"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A169, Pg. 1983

oral-quail LD50 280 mg/kg
Pesticide Manual. Vol. 9, Pg. 320, 1991.

oral-rat LD50 638 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C114, 1991.

unreported-rat LD50 1015 mg/kg
"Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 425, 1971.

Dermal Toxicity:
skin-rat LD50 > 2000 mg/kg
Pesticide Manual. Vol. 9, Pg. 320, 1991.

Inhalation Toxicity:
inhalation-rat LC50 3000 mg/m3/4H
Pesticide Manual. Vol. 9, Pg. 320, 1991.

 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for dithianon usage levels up to:
 not for fragrance use.
 
Recommendation for dithianon flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Peer review of the pesticide risk assessment for the active substance dithianon in light of confirmatory data submitted
View page or View pdf

Updated peer review of the pesticide risk assessment for the active substance dithianon in light of confirmatory data submitted
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :18771
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
5,10-dioxobenzo[g][1,4]benzodithiine-2,3-dicarbonitrile
Chemidplus:0003347226
RTECS:QL0700000 for cas# 3347-22-6
 
References:
 5,10-dioxobenzo[g][1,4]benzodithiine-2,3-dicarbonitrile
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):18771
Pubchem (sid):134982159
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18574
HMDB (The Human Metabolome Database):HMDB31780
FooDB:FDB008453
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 delan
 delan WP
 delan-col
2,3-dicarbonitrilo-1,4-diathiaanthrachinon
2,3-dicyano-1,4-dithia-anthraquinone
5,10-dihydro-5,10-dioxonaphtho(2,3-b)-1,4-dithiin-2,3-dicarbonitrile
5,10-dihydro-5,10-dioxonaphtho(2,3-b)-p-dithiin-2,3-dicarbonitrile
2,3-dinitrilo-1,4-dithia-9,10-anthraquinone
2,3-dinitrilo-1,4-dithia-anthraquinone
2,3-dinitrilo-1,4-dithioanthrachinon
5,10-dioxobenzo[g][1,4]benzodithiine-2,3-dicarbonitrile
1,4-dithiaanthraquinone-2,3-dicarbonitrile
1,4-dithiaanthraquinone-2,3-dinitrile
 dithianone
 HSDB 1583
 IT 931
 merkdelan
 MV 119A
 naphtho(2,3-b)-1,4-dithiin-2,3-dicarbonitrile, 5,10-dihydro-5,10-dioxo-
 naphtho(2,3-b)-p-dithiin-2,3-dicarbonitrile, 5,10-dihydro-5,10-dioxo-
 stauffer MV-119A
 thynon
 

Articles:

PubMed:Toxicity of copper hydroxide, dithianon, fluazinam, tebuconazole and pyraclostrobin to Didymella applanata isolates from Serbia.
PubMed:Structures of four polymorphs of the pesticide dithianon solved from X-ray powder diffraction data.
PubMed:Characterization of non-extractable residues of the fungicide dithianon in soil using 13C/14C-labelling techniques.
PubMed:Biomarkers of effect in evaluating dithianon cocarcinogenesis: selective induction and suppression of murine CYP3A isoform.
PubMed:A new spectrophotometric method for the determination of dithianon in commercial formulations and its residues in foodstuffs.
PubMed:In vitro cytotoxic and cell transforming activities exerted by the pesticides cyanazine, dithianon, diflubenzuron, procymidone, and vinclozolin on BALB/c 3T3 cells.
PubMed:Influence of the amendment of corn straw on the degradation behaviour of the fungicide dithianon in soil.
PubMed:Characterisation of soil-bound residue fractions of the fungicide dithianon by gel permeation chromatography and polyacrylamide gel electrophoresis.
PubMed:Induction and suppression of murine CYP-mediated biotransformation by dithianon: organ- and sex-related differences.
PubMed:[Determination and disintegration of dithianon, pyridinitril and flurenol in soils and waters].
PubMed:Determination of residues of dithianon in apples by high-performance liquid chromatography.
PubMed:Spectrophotometric determination of the fungicide dithianon in aqueous formulation Delan-Col with 2,4-dinitrophenylhydrazine.
PubMed:Production of apple-based baby food: changes in pesticide residues.
PubMed:Toxicity of mancozeb, chlorothalonil, captan, fluopyram, boscalid, and difenoconazole to Didymella applanata isolates from Serbia.
PubMed:Interactions between yeasts, fungicides and apple fruit russeting.
PubMed:A novel ABC transporter gene, PMR5, is involved in multidrug resistance in the phytopathogenic fungus Penicillium digitatum.
PubMed:Evaluation of the field dissipation of fungicides and insecticides used on fruit bearing trees in northern Italy.
PubMed:Developing an ecotoxicological testing standard for predatory mites in Australia: acute and sublethal effects of fungicides on Euseius victoriensis and Galendromus occidentalis (Acarina: Phytoseiidae).
PubMed:Management of apple scab (Venturia inaequalis) in Romania based on electronic warnings.
PubMed:Structural and functional approach to studying pesticide side-effects on specific soil functions.
 
Notes:
Agricultural and horticultural fungicide
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