butylated hydroxyanisole, 25013-16-5

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Butylated Hydroxy Anisole

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Product(s):
25013-16-5 Butylhydroxyanisole 95%

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BUTYLATED HYDROXYANISOLE BHA

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GK0616 Butylated hydroxyanisole

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BHA

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464050 BHA,

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Butylated Hydroxy Anisole (BHA)

Penta International Corporation

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Product(s):
02-52000 BUTYLATED HYDROXYANISOLE (BHA) NF
02-52001 BUTYLATED HYDROXYANISOLE (BHA) FCC
02-52002 BUTYLATED HYDROXY ANISOLE EP GRADE
02-52003 BUTYLATED HYDROXYANISOLE (BHA) NF/FCC POWDER (40 MESH)
02-52005 BUTYLATED HYDROXYANISOLE (BHA) EP / NF GRADE
02-52006 BUTYLATED HYDROXY ANISOLE (BHA) EP/NF POWDER (40 MESH)
02-52008 BUTYLATED HYDROXYANISOLE (BHA) EP / IP GRADE
02-52020 BUTYLATED HYDROXY ANISOLE (BHA) NF / FCC GRADE
02-52035 BUTYLATED HYDROXYANISOLE (BHA) NF GRADE (80 MESH)

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0ZP03359 BHT Butylated Hydroxy Anisole - anti-oxidant

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Product(s):
W218308 Butylated hydroxyanisole, 99%, FCC, FG
SDS

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Product(s):
500563 BHA

Name:	2-tert-butyl-4-methoxyphenol;3-tert-butyl-4-methoxyphenol
CAS Number:	25013-16-5	3D/inchi
Other(deleted CASRN):	1336-31-8
ECHA EINECS - REACH Pre-Reg:	246-563-8
FDA UNII:	REK4960K2U
Beilstein Number:	1867499
MDL:	MFCD01779059
XlogP3:	3.20 (est)
Molecular Weight:	360.49384000
Formula:	C22 H32 O4
BioActivity Summary:	listing
NMR Predictor:	Predict (works with chrome, Edge or firefox)

Category:antioxidants and preservatives for fragrance and flavor

US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:

Google Scholar:	Search
Google Books:	Search
Google Scholar: with word "volatile"	Search
Google Scholar: with word "flavor"	Search
Google Scholar: with word "odor"	Search
Perfumer and Flavorist:	Search
Google Patents:	Search
US Patents:	Search
EU Patents:	Search
Pubchem Patents:	Search
PubMed:	Search
NCBI:	Search
	FDA/DG SANTE Petitions, Reviews, Notices:
182.3169	Butylated Hydroxyanisole (BHA) View - review
EU SANCO	Gallates, TBHQ and BHA View - review
EU SANCO	Butylated hydroxyanisole View - review
JECFA Food Additive:	Butylated Hydroxyanisole
GSFA Codex:	Butylated hydroxyanisole (320)
DG SANTE Food Additives:	BHA
DG SANTE Food Contact Materials:	BHA
FEMA Number:	2183 butylated hydroxyanisole
FDA:	No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):	25013-16-5 ; BUTYLATED HYDROXYANISOLE
FDA Regulation:
FDA PART 166 -- MARGARINE Subpart B--Requirements for Specific Standardized Margarine Sec. 166.110 Margarine. FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Subpart B--Food Preservatives Sec. 172.110 BHA. FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Subpart B--Food Preservatives Sec. 172.115 BHT. FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Subpart B--Food Preservatives Sec. 172.185 TBHQ. FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Subpart F--Flavoring Agents and Related Substances Sec. 172.515 Synthetic flavoring substances and adjuvants. FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Subpart G--Gums, Chewing Gum Bases and Related Substances Sec. 172.615 Chewing gum base. FDA PART 173 -- SECONDARY DIRECT FOOD ADDITIVES PERMITTED IN FOOD FOR HUMAN CONSUMPTION Subpart D--Specific Usage Additives Sec. 173.340 Defoaming agents. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart B--Substances for Use Only as Components of Adhesives Sec. 175.105 Adhesives. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart B--Substances for Use Only as Components of Adhesives Sec. 175.125 Pressure-sensitive adhesives. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.300 Resinous and polymeric coatings. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.380 Xylene-formaldehyde resins condensed with 4,4'-isopropylidenediphenol-epichlorohydrin epoxy resins. FDA PART 175 -- INDIRECT FOOD ADDITIVES: ADHESIVES AND COMPONENTS OF COATINGS Subpart C--Substances for Use as Components of Coatings Sec. 175.390 Zinc-silicon dioxide matrix coatings. FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Subpart B--Substances for Use Only as Components of Paper and Paperboard Sec. 176.170 Components of paper and paperboard in contact with aqueous and fatty foods. FDA PART 176 -- INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Subpart B--Substances for Use Only as Components of Paper and Paperboard Sec. 176.210 Defoaming agents used in the manufacture of paper and paperboard. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1010 Acrylic and modified acrylic plastics, semirigid and rigid. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1210 Closures with sealing gaskets for food containers. FDA PART 177 -- INDIRECT FOOD ADDITIVES: POLYMERS Subpart B--Substances for Use as Basic Components of Single and Repeated Use Food Contact Sec. 177.1350 Ethylene-vinyl acetate copolymers. FDA PART 178 -- INDIRECT FOOD ADDITIVES: ADJUVANTS, PRODUCTION AIDS, AND SANITIZERS Subpart D--Certain Adjuvants and Production Aids Sec. 178.3570 Lubricants with incidental food contact. FDA PART 179 -- IRRADIATION IN THE PRODUCTION, PROCESSING AND HANDLING OF FOOD Subpart C--Packaging Materials for Irradiated Foods Sec. 179.45 Packaging materials for use during the irradiation of prepackaged foods. FDA PART 181 -- PRIOR-SANCTIONED FOOD INGREDIENTS Subpart B--Specific Prior-Sanctioned Food Ingredients Sec. 181.24 Antioxidants. FDA PART 182 -- SUBSTANCES GENERALLY RECOGNIZED AS SAFE Subpart D--Chemical Preservatives Sec. 182.3169 Butylated hydroxyanisole.

Physical Properties:

Appearance:	white to pale yellow solid (est)
Assay:	98.00 to 100.00
Food Chemicals Codex Listed:	Yes
Melting Point:	58.00 to 60.00 °C. @ 760.00 mm Hg
Boiling Point:	268.00 to 269.00 °C. @ 760.00 mm Hg
Vapor Pressure:	0.004000 mmHg @ 25.00 °C. (est)
Vapor Density:	6.2 ( Air = 1 )
Flash Point:	235.00 °F. TCC ( 112.78 °C. )
logP (o/w):	3.087 (est)
Shelf Life:	24.00 month(s) or longer if stored properly.
Storage:	store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
	alcohol
	water, 212.8 mg/L @ 25 °C (est)
Insoluble in:
	water

Organoleptic Properties:

Odor Strength:low

Odor Description:at 100.00 %. mild rubbery

Odor and/or flavor descriptions from others (if found).

Cosmetic Information:

CosIng:	cosmetic data
Cosmetic Uses:	antioxidants fragrance

Suppliers:

Anhui Haibei

BHA

Augustus Oils

Butylated Hydroxy Anisole

Services

BOC Sciences

For experimental / research use only.

Butylhydroxyanisole 95%

Charkit Chemical

BUTYLATED HYDROXYANISOLE BHA

Eastman Chemical

Eastman Tenox™ BHA Food Grade Antioxidant, Flake, Kosher

sds

Glentham Life Sciences

Butylated hydroxyanisole

Graham Chemical

BHA

Indenta Group

BHA

Indis NV

For experimental / research use only.

BHA - Butylated Hydroxyanisole

BHA

BHA

Butylated Hydroxy Anisole (BHA)

Penta International

BUTYLATED HYDROXY ANISOLE (BHA) EP/NF POWDER (40 MESH)

Penta International

BUTYLATED HYDROXY ANISOLE (BHA) NF / FCC GRADE

Penta International

BUTYLATED HYDROXY ANISOLE EP GRADE

Penta International

BUTYLATED HYDROXYANISOLE (BHA) FCC

Penta International

BUTYLATED HYDROXYANISOLE (BHA) NF

Penta International

BUTYLATED HYDROXYANISOLE (BHA) EP / IP GRADE

Penta International

BUTYLATED HYDROXYANISOLE (BHA) EP / NF GRADE

Penta International

BUTYLATED HYDROXYANISOLE (BHA) NF GRADE (80 MESH)

Penta International

BUTYLATED HYDROXYANISOLE (BHA) NF/FCC POWDER (40 MESH)

PerfumersWorld

BHT Butylated Hydroxy Anisole - anti-oxidant

Perfumery Laboratory

BHT ANTIOXIDATOR (Butylated Hydroxy Anisole)

Prinova

BHA

R C Treatt & Co Ltd

B.H.A.

Santa Cruz Biotechnology

For experimental / research use only.

butylated Hydroxyanisole

Sigma-Aldrich

Butylated hydroxyanisole, 99%, FCC, FG

sds

Certified Food Grade Products

Silver Fern Chemical

Butylated Hydroxyanisole (BHA)

Odor: characteristic

Use: Butylated hydroxyanisole (BHA) is a white or slightly yellow, waxy solid with a faint characteristic odor. It is not naturally water soluble, but can be treated to be so. It is freely soluble in alcohol and propylene glycol.

Vigon International

BHA

Safety Information:

Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 22 - Harmful if swallowed. R 40 - Possible risks of irreversable effects. S 02 - Keep out of the reach of children. S 22 - Do not breath dust. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.

Hazards identification

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements

Pictogram

Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 2000 mg/kg BEHAVIORAL: ATAXIA BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho. Annual Report of Tokyo Metropolitan Research Laboratory of Public Health. Vol. 22, Pg. 231, 1970. intraperitoneal-rat LD50 881 mg/kg BLOOD: HEMORRHAGE Toxicology Letters. Vol. 27, Pg. 15, 1985. oral-mouse LD50 1100 mg/kg LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION BEHAVIORAL: ATAXIA BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho. Annual Report of Tokyo Metropolitan Research Laboratory of Public Health. Vol. 22, Pg. 231, 1970.
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in Use Information:

Category:
antioxidants and preservatives for fragrance and flavor
Recommendation for butylated hydroxyanisole usage levels up to:
	not for fragrance use.

Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
		average usual ppm	average maximum ppm
baked goods:		-	2.80000
beverages(nonalcoholic):		-	0.82000
beverages(alcoholic):		-	-
breakfast cereal:		-	-
cheese:		-	-
chewing gum:		-	13.00000
condiments / relishes:		-	-
confectionery froastings:		-	-
egg products:		-	-
fats / oils:		-	230.00000
fish products:		-	-
frozen dairy:		-	0.81000
fruit ices:		-	0.81000
gelatins / puddings:		-	0.54000
granulated sugar:		-	-
gravies:		-	-
hard candy:		-	9.60000
imitation dairy:		-	-
instant coffee / tea:		-	-
jams / jellies:		-	-
meat products:		-	-
milk products:		-	-
nut products:		-	-
other grains:		-	-
poultry:		-	-
processed fruits:		-	-
processed vegetables:		-	5.00000
reconstituted vegetables:		-	-
seasonings / flavors:		-	-
snack foods:		-	-
soft candy:		-	-
soups:		-	-
sugar substitutes:		-	-
sweet sauces:		-	-

Safety References:

European Food Safety Authority (EFSA) reference(s):

Scientific Opinion on the re-evaluation of butylated hydroxyanisole � BHA (E 320) as a food additive
View page or View pdf

Statement on the safety assessment of the exposure to butylated hydroxyanisole E 320 (BHA) by applying a new exposure assessment methodology
View page or View pdf

Safety and efficacy of butylated hydroxyanisole (BHA) as a feed additive for all animal species
View page or View pdf

Safety of butylated hydroxy anisole (BHA) for all animal species
View page or View pdf

Safety and efficacy of a feed additive consisting of butylated hydroxyanisole (BHA) for use in cats (FEDIAF)
View page or View pdf

EPI System: View

Chemical Carcinogenesis Research Information System:Search

AIDS Citations:Search

Cancer Citations:Search

Toxicology Citations:Search

Carcinogenic Potency Database:Search

EPA GENetic TOXicology:Search

EPA Substance Registry Services (TSCA):25013-16-5

EPA ACToR:Toxicology Data

EPA Substance Registry Services (SRS):Registry

Laboratory Chemical Safety Summary :24667

National Institute of Allergy and Infectious Diseases:Data

WGK Germany:2

2-tert-butyl-4-methoxyphenol;3-tert-butyl-4-methoxyphenol

Chemidplus:0025013165

EPA/NOAA CAMEO:hazardous materials

RTECS:SL1945000 for cas# 25013-16-5

References:

	2-tert-butyl-4-methoxyphenol;3-tert-butyl-4-methoxyphenol
NIST Chemistry WebBook:	Search Inchi
Canada Domestic Sub. List:	25013-16-5
Pubchem (cid):	24667
Pubchem (sid):	134996929

Other Information:

(IUPAC):	Atomic Weights of the Elements 2011 (pdf)
Videos:	The Periodic Table of Videos
tgsc:	Atomic Weights use for this web site
(IUPAC):	Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):	View
FDA Indirect Additives used in Food Contact Substances:	View
CHEBI:	View
CHEMBL:	View
KEGG (GenomeNet):	C15469
HMDB (The Human Metabolome Database):	HMDB31848
FooDB:	FDB008532
FDA Listing of Food Additive Status:	View
ChemSpider:	View
Wikipedia:	View
Formulations/Preparations: •the commercial prepn of bha sold under name of tenox bha (eastman chem inc) contains about 85% of 3-tert-butyl-4-hydroxyanisole & 15% of 2-tert-butyl-4-hydroxyanisole. •food grade, 98.5+%.

Potential Blenders and core components note

None Found

Potential Uses:

	antioxidants
	preservatives

Occurrence (nature, food, other):note

not found in nature

Synonyms:

	antioxyne B
	B.H.A.
	BHA
	BHA food grade NF
	butyl hydroxyanisole
tert-	butyl hydroxyanisole
2(3)-t-	butyl-4-hydroxyanisole
2(3)-tert-	butyl-4-hydroxyanisole
tert-	butyl-4-hydroxyanisole
2(3)-tert-	butyl-4-methoxyphenol
tert-	butyl-4-methoxyphenol
2-tert-	butyl-4-methoxyphenol;3-tert-butyl-4-methoxyphenol
3-tert-	butyl-4-methoxyphenyl and 2tert-butyl-4-methoxyphenol
2-tert-	butyl-4-methoxyphenyl and 3-tert-butyl-4-methoxyphenol
2(3)-(tert-	butyl)-4-methoxyphenol
tert-	butylhydroxyanisole
(1,1-	dimethyl ethyl)-4-methoxyphenol
2(3)-(1,1-	dimethylethyl)-4-(methyloxy)phenol
2(3)-(1,1-	dimethylethyl)-4-methoxy-phenol
2(or 3)-(1,1-	dimethylethyl)-4-methoxyphenol
	embanox
butylated	hydroxy anisole (BHA) EP/NF powder (40 mesh)
butylated	hydroxy anisole (BHA) NF / FCC grade
butylated	hydroxy anisole EP grade
4-	hydroxy-2(3)-tert-butylanisole
butylated	hydroxyanisole (BHA) EP / IP grade
butylated	hydroxyanisole (BHA) EP / NF grade
butylated	hydroxyanisole (BHA) FCC
butylated	hydroxyanisole (BHA) N.F.
butylated	hydroxyanisole (BHA) NF/FCC powder (40 mesh)
4-	methoxy-2(3)-tert-butylphenol
	phenol, (1,1-dimethylethyl)-4-methoxy-
	phenol, 2(3)-(1,1-dimethylethyl)-4-methoxy-
	phenol, 2(3)-t-butyl-4-methoxy-
	phenol, 2(3)-tert-butyl-4-methoxy-
	phenol, t-butyl-4-methoxy-
	tenox BHA food grade antioxidant, flake

Articles:

Info:EVALUATION OF CERTAIN FOOD ADDITIVES AND CONTAMINANTS

PubMed:Oxidative stability of cooked, frozen, reheated beef patties: effect of antioxidants.

PubMed:Effects of sodium lactate and acetic acid derivatives on the quality and sensory characteristics of hot-boned pork sausage patties.

PubMed:Evaluation of antioxidant activity of green tea extract and its effect on the biscuits lipid fraction oxidative stability.

PubMed:Antioxidants in bakery products: a review.

PubMed:Antioxidant properties of dried plum ingredients in raw and precooked pork sausage.

PubMed:Antioxidant and antimicrobial effects of garlic in chicken sausage.

PubMed:Effect of enrobing and antioxidants on quality characteristics of precooked pork patties under chilled and frozen storage conditions.

PubMed:Effect of antioxidants on the flavor characteristics and the gas chromatography/olfactometry profiles of champagne extracts.

Notes:

mixture of 2- and 3-tert-butyl-4-methoxyphenols that is used as an antioxidant in foods, cosmetics, and pharmaceuticals. Antioxidant. Used in foods Butylated hydroxyanisole (BHA) is an antioxidant consisting of a mixture of two isomeric organic compounds, 2-tert-butyl-4-hydroxyanisole and 3-tert-butyl-4-hydroxyanisole. It is prepared from 4-methoxyphenol and isobutylene. It is a waxy solid used in certain amounts as a food additive with the E number E320.

butylated hydroxyanisole BHA

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